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Methyl 2-bromomethylbenzoate

CAS No.
2417-73-4
Chemical Name:
Methyl 2-bromomethylbenzoate
Synonyms
METHYL 2-BROMOMETHYL BENZOATE;RARECHEM AL BO 0035;ART-CHEM-BB B019566;2-BROMOMETHYL-1-BENZOIC ACID;2-BroMoMethylbenzoic Methylester;2-(BROMOMETHYL)BENZOIC ACID METHYL ESTER;o-(Bromomethyl)benzoic acid methyl ester;Benzoic acid, 2-(bromomethyl)-, methyl ester
CBNumber:
CB7308451
Molecular Formula:
C9H9BrO2
Molecular Weight:
229.07
MDL Number:
MFCD03425900
MOL File:
2417-73-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 03:18:48
Product description Number Pack Size Price
Methyl 2-(Bromomethyl)benzoate min. 98.0 % M2122 1G $49
Methyl 2-(Bromomethyl)benzoate min. 98.0 % M2122 5G $147
Methyl 2-Bromomethylbenzoate TRC-M295180-5G 5g $109
Methyl 2-Bromomethylbenzoate TRC-M295180-25G 25g $306
Methyl 2-Bromomethylbenzoate TRC-M295180-100G 100g $917
More product size

Methyl 2-bromomethylbenzoate Properties

Melting point 32-32.5 °C
Boiling point 114 °C(Press: 0.44 Torr)
Density 1.460±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Chloroform (Sparingly), Hexane (Slightly)
form Solid
color White Low Melting
InChI InChI=1S/C9H9BrO2/c1-12-9(11)8-5-3-2-4-7(8)6-10/h2-5H,6H2,1H3
InChIKey QKASDIPENBEWBU-UHFFFAOYSA-N
SMILES C(OC)(=O)C1=CC=CC=C1CBr
CAS DataBase Reference 2417-73-4(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302+H332-H315-H319-H335-H412
Precautionary statements  P260-P280
HS Code  2916310090

Methyl 2-bromomethylbenzoate price More Price(61)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical M2122 Methyl 2-(Bromomethyl)benzoate min. 98.0 % 2417-73-4 1G $49 2026-04-30 Buy
TCI Chemical M2122 Methyl 2-(Bromomethyl)benzoate min. 98.0 % 2417-73-4 5G $147 2026-04-30 Buy
TRC TRC-M295180-5G Methyl 2-Bromomethylbenzoate 2417-73-4 5g $109 2026-06-03 Buy
TRC TRC-M295180-25G Methyl 2-Bromomethylbenzoate 2417-73-4 25g $306 2026-06-03 Buy
TRC TRC-M295180-100G Methyl 2-Bromomethylbenzoate 2417-73-4 100g $917 2026-06-03 Buy
Product number Packaging Price Buy
M2122 1G $49 Buy
M2122 5G $147 Buy
TRC-M295180-5G 5g $109 Buy
TRC-M295180-25G 25g $306 Buy
TRC-M295180-100G 100g $917 Buy

Methyl 2-bromomethylbenzoate Chemical Properties,Uses,Production

Uses

Methyl 2-Bromomethylbenzoate is a reactant in the preparation of Methyl 2-((4-(2-(2-methylphenoxy)acetyl)piperazin-1-yl)methyl)benzoate with neuroprotective activity.

Synthesis

Methyl o-toluate

89-71-4

Methyl 2-bromomethylbenzoate

2417-73-4

General procedure for the synthesis of methyl 2-bromomethylbenzoate from methyl o-toluate: (2) 1.50 g (10 mmol) of methyl o-toluate was added to a 250 mL round-bottom flask and dissolved in 80 mL of carbon tetrachloride. Subsequently 1.98 g (11 mmol) of N-bromosuccinimide (NBS) and 48 mg (0.2 mmol) of benzoyl peroxide (BPO) were added. The mixture was heated to reflux for 1.5 h to ensure complete reaction. Upon completion of the reaction, insoluble material was removed by filtration and the solvent was subsequently evaporated to give methyl 2-bromomethylbenzoate. The reaction was quantitative.

References

[1] Journal of Medicinal Chemistry, 2000, vol. 43, # 24, p. 4667 - 4677
[2] Chemical Communications, 2010, vol. 46, # 13, p. 2227 - 2229
[3] Patent: US2011/237786, 2011, A1. Location in patent: Page/Page column 7
[4] Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1989, vol. 44, # 9, p. 1132 - 1148
[5] Journal of Heterocyclic Chemistry, 1980, vol. 17, # 9, p. 1359 - 1360

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View Lastest Price from Methyl 2-bromomethylbenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 2-bromomethylbenzoate pictures 2020-01-05 Methyl 2-bromomethylbenzoate
2417-73-4
$9.80 1g ≥99% 100kg Career Henan Chemical Co

Methyl 2-bromomethylbenzoate Spectrum

2-(BROMOMETHYL)BENZOIC ACID METHYL ESTER 2-BROMOMETHYL-1-BENZOIC ACID METHYL 2-BROMOMETHYL BENZOATE ART-CHEM-BB B019566 RARECHEM AL BO 0035 2-BroMoMethylbenzoic Methylester o-(Bromomethyl)benzoic acid methyl ester Benzoic acid, 2-(bromomethyl)-, methyl ester 2417-73-4 7116-89-1 Aromatic Esters Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts