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VANADIUM (IV) CHLORIDE

CAS No.
7632-51-1
Chemical Name:
VANADIUM (IV) CHLORIDE
Synonyms
VCl4;VANADIUM CHLORIDE;Vanadium tetrachloride;Tetrachlorovanadium;vanadiumchloride(vcl4);VANADIUM (IV) CHLORIDE;Tetrachlorovanadium(IV);Vanadium(IV) tetrachloride;VANADIUM (IV) CHLORIDE 99+%;(t-4)-vanadiumchloride(vcl4
CBNumber:
CB7328482
Molecular Formula:
Cl4V
Molecular Weight:
192.75
MDL Number:
MFCD00061343
MOL File:
7632-51-1.mol
MSDS File:
SDS
Last updated:2026-05-28 04:49:48
Product description Number Pack Size Price
VANADIUM(IV) CHLORIDE 95.00% ING0007344 1G $758.57
VANADIUM(IV) CHLORIDE 95.00% ING0007344 100G $2591.04
More product size

VANADIUM (IV) CHLORIDE Properties

Melting point −28 °C(lit.)
Boiling point 154 °C(lit.)
Density 1.816 g/mL at 25 °C(lit.)
vapor pressure 10.173hPa at 25℃
Flash point 148.5°C/755mm
storage temp. water-free area
solubility diethyl ether: slightly soluble(lit.)
form Liquid
color Opaque reddish-brown
Water Solubility soluble alcohol, ether [HAW93]
Sensitive Moisture Sensitive
Dielectric constant 3.1(Ambient)
Major Application battery manufacturing
InChI InChI=1S/4ClH.V/h4*1H;/q;;;;+4/p-4
InChIKey JTJFQBNJBPPZRI-UHFFFAOYSA-J
SMILES [V](Cl)(Cl)(Cl)Cl
LogP 0 at 20℃
EWG's Food Scores 1
FDA UNII 2I17MGM5YJ
EPA Substance Registry System Vanadium chloride (VCl4), (T-4)- (7632-51-1)
UNSPSC Code 12352302

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314-H412
Precautionary statements  P260-P264-P280-P273-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P305+P351+P338-P405-P501
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  T
Risk Statements  14-23/24/25-34
Safety Statements  26-27-36/37/39-45
RIDADR  UN 2444
WGK Germany  3
RTECS  YW2625000
TSCA  TSCA listed
HazardClass  8
PackingGroup  I
HS Code  28273990
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Oral
Aquatic Chronic 3
Eye Dam. 1
Skin Corr. 1C
Hazardous Substances Data 7632-51-1(Hazardous Substances Data)
REACH Registrations Active
NFPA 704
0
3 2
W

VANADIUM (IV) CHLORIDE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
American Custom Chemicals Corporation ING0007344 VANADIUM(IV) CHLORIDE 95.00% 7632-51-1 1G $758.57 2021-12-16 Buy
American Custom Chemicals Corporation ING0007344 VANADIUM(IV) CHLORIDE 95.00% 7632-51-1 100G $2591.04 2021-12-16 Buy
Product number Packaging Price Buy
ING0007344 1G $758.57 Buy
ING0007344 100G $2591.04 Buy

VANADIUM (IV) CHLORIDE Chemical Properties,Uses,Production

Chemical Properties

Red liquid. Decomposes slowly to vanadium trichloride and chlorine below63C. Soluble in absolute alcohol and ether. Nonflammable.

Chemical Properties

Vanadium tetrachloride is a thick, reddishbrown liquid that gives off fumes on exposure to moist air.

Uses

Preparation of vanadium trichloride, vanadium dichloride, and organovanadium compounds.

Preparation

Disproportionate of VCl3 to VCl2 and VCl4 by heating in a N2 stream at 900°C in a porcelain tube.

Air & Water Reactions

Forms acid mists in moist air. Reacts with water to form corrosive fumes of HCl. Handling Chemicals Safely 1980. p. 952).

Reactivity Profile

VANADIUM (IV) CHLORIDE decomposes by the action of light with the formation of Cl2 gas. Reacts as an acid to neutralize bases. These neutralizations generate heat. Usually does not react as either oxidizing agents or reducing agents but such behavior is not impossible. May catalyze organic reactions.

Health Hazard

CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may burn, but none ignite readily. May ignite combustibles (wood, paper, oil, clothing, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. Substance may be transported in a molten form.

Flammability and Explosibility

Not classified

reaction suitability

reagent type: catalyst
core: vanadium

Safety Profile

Poison by ingestion. A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of VOx and Cl-. See also VANADIUM COMPOUNDS and HYDROCHLORIC ACID.

Potential Exposure

Vanadium tetrachloride is used as a fixative in textile dyeing and in the manufacture of other vanadium compounds.

Shipping

UN2444 Vanadium tetrachloride, Hazard class: 8; Labels: 8-Corrosive material.

Incompatibilities

Vanadium tetrachloride is chemically unstable, highly reactive with all forms of moisture, including humidity, releasing corrosive hydrogen chloride and/or chloride fumes. Keep away from light, UV, water, steam, lithium, chlorine, trifluoride, alcohols, organic, and combustible materials. Vanadium tetrachloride is a reactive chemical and is an explosion hazard. See storage and handling section. Corrosive to metals and may release flammable hydrogen gas. Vanadium tetrachloride decomposes by the action of light with the formation of Cl2 gas. Reacts as an acid to neutralize bases. These neutralizations generate heat. Usually does not react as either oxidizing agents or reducing agents but such behavior is not impossible. May catalyze organic reactions.

VANADIUM (IV) CHLORIDE Preparation Products And Raw materials

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VANADIUM (IV) CHLORIDE VANADIUM (IV) CHLORIDE, 99+%, 99.99% (METALS BASIS) VANADIUM (IV) CHLORIDE 99+% Vanadium(IV)chloride,99.99%(metalsbasis) (beta-4)-vanadiumchloride(vcl4 (t-4)-vanadiumchloride(vcl4 Tetrachlorovanadium Vanadium chloride (VCl4), (t-4)- vanadiumchloride(vcl4) Tetrachlorovanadium(IV) Vanadium(IV) tetrachloride VanadiuM(IV) chloride, 99+% 100GR VANADIUM CHLORIDE Vanadium tetrachloride VCl4 7632-51-1 Cl4V Vanadium Catalysis and Inorganic Chemistry Catalysis and Inorganic Chemistry Chemical Synthesis Salts Vanadium Salts VanadiumMetal and Ceramic Science Catalysis and Inorganic Chemistry Chemical Synthesis Materials Science Metal and Ceramic Science Vanadium Vanadium Salts