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4-Fluoro-3-nitrobenzyl bromide

4-Fluoro-3-nitrobenzyl bromide structure

CAS No.: 15017-52-4

Chemical Name:: 4-Fluoro-3-nitrobenzyl bromide

Synonyms: 3-NITRO-4-FLUOROBENZYLBROMIDE;4-FLUORO-3-NITROBENZYL BROMIDE;4-Fluoro-3-NitrobenzylBromide96%;4-(BROMOMETHYL)-1-FLUORO-2-NITROBENZENE;Benzene, 4-(bromomethyl)-1-fluoro-2-nitro-;4-Fluoro-3-nitrobenzyl bromide ISO 9001：2015 REACH

CBNumber:: CB7357020

Molecular Formula:: C7H5BrFNO2

Molecular Weight:: 234.02

MDL Number:: MFCD03412241

MOL File:: 15017-52-4.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-04-24 14:58:24

Product description	Number	Pack Size	Price
4-Fluoro-3-nitrobenzylBromide	F401628	100mg	$60
4-Fluoro-3-nitrobenzylBromide	F401628	500mg	$75
4-(Bromomethyl)-1-fluoro-2-nitrobenzene 95+%	119408	5g	$108
4-(Bromomethyl)-1-fluoro-2-nitrobenzene 95+%	119408	10g	$162
4-FLUORO-3-NITROBENZYL BROMIDE 95.00%	HCH0023791	1G	$600.79
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4-Fluoro-3-nitrobenzyl bromide Properties

Melting point	84-86°C
Boiling point	317.4±27.0 °C(Predicted)
Density	1.733±0.06 g/cm3(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	solid
color	Pale yellow
CAS DataBase Reference	15017-52-4(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS05
Signal word	Danger
Hazard statements	H314
Precautionary statements	P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P405-P501
Hazard Codes	C,Xn
Risk Statements	34-36/37/38-22
Safety Statements	26-36/37/39
RIDADR	1759
HS Code	2904990090

4-Fluoro-3-nitrobenzyl bromide price More Price(17)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TRC	F401628	4-Fluoro-3-nitrobenzylBromide	15017-52-4	100mg	$60	2021-12-16	Buy
TRC	F401628	4-Fluoro-3-nitrobenzylBromide	15017-52-4	500mg	$75	2021-12-16	Buy
Matrix Scientific	119408	4-(Bromomethyl)-1-fluoro-2-nitrobenzene 95+%	15017-52-4	5g	$108	2021-12-16	Buy
Matrix Scientific	119408	4-(Bromomethyl)-1-fluoro-2-nitrobenzene 95+%	15017-52-4	10g	$162	2021-12-16	Buy
American Custom Chemicals Corporation	HCH0023791	4-FLUORO-3-NITROBENZYL BROMIDE 95.00%	15017-52-4	1G	$600.79	2021-12-16	Buy

Product number	Packaging	Price	Buy
F401628	100mg	$60	Buy
F401628	500mg	$75	Buy
119408	5g	$108	Buy
119408	10g	$162	Buy
HCH0023791	1G	$600.79	Buy

4-Fluoro-3-nitrobenzyl bromide Chemical Properties,Uses,Production

Uses

scaffold molecule for combinatorial synthesis

Synthesis

20274-69-5

15017-52-4

General procedure for the synthesis of 4-fluoro-3-nitrobenzyl bromide from 3-nitro-4-fluorobenzyl alcohol: 1. in a dry reaction flask, phosphorus tribromide (1.13 mL) was slowly added dropwise to a solution of 4-fluoro-3-nitrobenzyl alcohol (2.1 g, 11.23 mmol) in anhydrous ether (40 mL). 2. Stir the reaction mixture at room temperature for 1 hour until the reaction is complete. 3. After the reaction is complete, carefully add water to the reaction mixture to quench the reaction. 4. The reaction mixture was extracted with ethyl acetate (3 × 20 mL) and the organic phases were combined. 5. The organic phase was washed sequentially with saturated sodium bicarbonate solution (20 mL) and saturated brine (20 mL). 6. The organic phase was dried with anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to obtain the crude product. 7. The crude product was purified by silica gel column chromatography (eluent: petroleum ether/ethyl acetate, gradient elution) to obtain 4-fluoro-3-nitrobenzyl bromide (2.50 g, 95% yield) as a light yellow solid. Product Characterization: 1H NMR (270 MHz, CDCl3) δ (ppm): 8.10 (dd, 1H, J = 7.1, 2.2 Hz), 7.67 (m, 1H), 7.29 (dd, 1H, J = 10.7, 8.6 Hz), 4.49 (s, 2H).

References

[1] Patent: EP1982982, 2008, A1. Location in patent: Page/Page column 199
[2] Patent: KR101511396, 2015, B1. Location in patent: Paragraph 2917-2921
[3] Journal of the Chemical Society - Series Chemical Communications, 1994, # 4, p. 439 - 440
[4] Heterocycles, 1999, vol. 51, # 9, p. 2041 - 2063
[5] Tetrahedron, 2011, vol. 67, # 33, p. 6073 - 6082

4-Fluoro-3-nitrobenzyl bromide Preparation Products And Raw materials

Raw materials

4-FLUORO-3-NITROBENZYL ALCOHOL 96 Diethyl ether Phosphorus tribromide

Preparation Products

4-Fluoro-3-nitrobenzyl bromide Suppliers

Global( 135)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20124	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10000	58
Antai Fine Chemical Technology Co.,Limited	18503026267	info@antaichem.com	CHINA	9636	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	+8613580539051	joe@yuhengpharm.com	CHINA	21142	58
Career Henan Chemica Co	+86-0371-86658258 +8613203830695	laboratory@coreychem.com	China	30227	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58
Win-Win chemical CO., Limited	+86-0086-577-64498589 +86-15355981851	sales@win-winchemical.com	China	14304	58
Shaanxi Dideu Medichem Co. Ltd	+86-029-89586680 +86-18192503167	1026@dideu.com	China	10000	58

Supplier	Advantage
Henan Fengda Chemical Co., Ltd	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Fuxin Pharmaceutical	58
Antai Fine Chemical Technology Co.,Limited	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	58
Career Henan Chemica Co	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Win-Win chemical CO., Limited	58
Shaanxi Dideu Medichem Co. Ltd	58

View Lastest Price from 4-Fluoro-3-nitrobenzyl bromide manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-09-25	4-Fluoro-3-nitrobenzyl bromide 15017-52-4	US $100.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2021-07-13	4-Fluoro-3-nitrobenzyl bromide 15017-52-4	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
2021-07-10	4-Fluoro-3-nitrobenzyl bromide 15017-52-4	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd

4-Fluoro-3-nitrobenzyl bromide
15017-52-4
US $100.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

4-Fluoro-3-nitrobenzyl bromide
15017-52-4
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

4-Fluoro-3-nitrobenzyl bromide
15017-52-4
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

4-Fluoro-3-nitrobenzyl bromide Spectrum

4-Fluoro-3-nitrobenzyl bromide(15017-52-4)¹HNMR

15017-52-4(4-Fluoro-3-nitrobenzyl bromide)Related Search:

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Fluorine 4-Nitrobenzyl chloride BROMOTRIFLUOROMETHANE

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4-(BROMOMETHYL)-1-FLUORO-2-NITROBENZENE 4-FLUORO-3-NITROBENZYL BROMIDE 3-NITRO-4-FLUOROBENZYLBROMIDE 4-Fluoro-3-NitrobenzylBromide96% Benzene, 4-(bromomethyl)-1-fluoro-2-nitro- 4-Fluoro-3-nitrobenzyl bromide ISO 9001：2015 REACH 15017-52-4 C7H5NO2BrF Aromatic Halides (substituted)