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2-(Bromomethyl)naphthalene

CAS No.
939-26-4
Chemical Name:
2-(Bromomethyl)naphthalene
Synonyms
2-(broMoMethyl)napthalene;2-Naphtylmethyl bromide;2-BMN;2-Bromomethyl naphth;naphthylmethyl bromide;BROMOMETHYLNAPTHALENE-2;2-naphthylmethyl bromide;2-(Bromomethyl)phthalene;2-(Xiu Jiaji)naphthalene;2-(brommethyl)naphthalen
CBNumber:
CB7465866
Molecular Formula:
C11H9Br
Molecular Weight:
221.09
MDL Number:
MFCD00004123
MOL File:
939-26-4.mol
MSDS File:
SDS
Last updated:2025-07-04 15:07:41

2-(Bromomethyl)naphthalene Properties

Melting point 51-54 °C(lit.)
Boiling point 213 °C100 mm Hg(lit.)
Density 1.3971 (rough estimate)
refractive index 1.6411 (estimate)
Flash point >230 °F
storage temp. 2-8°C
solubility Chloroform (Sparingly), Ethyl Acetate (Very Slightly)
form Fine Crystalline Powder
color Slightly yellow to light beige
Water Solubility Soluble in water (reacts), and chloroform.
BRN 636546
InChI InChI=1S/C11H9Br/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-7H,8H2
InChIKey RUHJZSZTSCSTCC-UHFFFAOYSA-N
SMILES C1=C2C(C=CC=C2)=CC=C1CBr
CAS DataBase Reference 939-26-4(CAS DataBase Reference)
NIST Chemistry Reference Naphthalene, 2-(bromomethyl)-(939-26-4)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07
Signal word  Danger
Hazard statements  H314-H317
Precautionary statements  P260-P272-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C,Xi
Risk Statements  34-43-36/37/38-36
Safety Statements  26-28-36/37/39-45-37-27
RIDADR  UN 3261 8/PG 2
WGK Germany  3
10-21
Hazard Note  Corrosive/Keep Cold
HazardClass  8
PackingGroup  II
HS Code  29033036
NFPA 704
1
3 0

2-(Bromomethyl)naphthalene price More Price(42)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 143677 2-(Bromomethyl)naphthalene 96% 939-26-4 5g $69.3 2025-07-31 Buy
Sigma-Aldrich 143677 2-(Bromomethyl)naphthalene 96% 939-26-4 25g $168 2025-07-31 Buy
TCI Chemical B1524 2-(Bromomethyl)naphthalene >97.0%(GC) 939-26-4 5g $92 2025-07-31 Buy
TCI Chemical B1524 2-(Bromomethyl)naphthalene >97.0%(GC) 939-26-4 25g $357 2025-07-31 Buy
Sigma-Aldrich 143677 2-(Bromomethyl)naphthalene 96% 939-26-4 100g $401.8 2025-07-31 Buy
Product number Packaging Price Buy
143677 5g $69.3 Buy
143677 25g $168 Buy
B1524 5g $92 Buy
B1524 25g $357 Buy
143677 100g $401.8 Buy

2-(Bromomethyl)naphthalene Chemical Properties,Uses,Production

Chemical Properties

White to cream solid

Uses

It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.

Uses

2-(Bromomethyl)naphthalene (2-BMN) can be employed as a starting material in the synthesis of 2-(fluoromethyl)naphthalene , 2-naphthylmethyl azide , 2-naphthalenecarboxaldehyde , diselenide, bis(2-naphthalenylmethyl) , 1H-1,2,3-triazole, 4,4′-(1,4-phenylene)bis[1-(2-naphthalenylmethyl).

Purification Methods

Dissolve the bromo compound in toluene, wash it with saturated aqueous NaHCO3, dry (Mg SO4), evaporate, fractionally distil the residue and recrystallise the solidified distillate from EtOH. [Chapman & Williams J Chem Soc 5044, 1952, Bergmann & Szmuszkovicz Bull Soc Chim Fr 20 566 1953, Beilstein 5 IV 1698.]

Global( 364)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mujin Biotechnology Co.,Ltd
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Hebei Yanxi Chemical Co., Ltd.
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View Lastest Price from 2-(Bromomethyl)naphthalene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-(Bromomethyl)naphthalene pictures 2025-08-08 2-(Bromomethyl)naphthalene
939-26-4
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mujin Biotechnology Co.,Ltd
2-(Bromomethyl)naphthalene pictures 2025-06-27 2-(Bromomethyl)naphthalene
939-26-4
US $30.00-10.00 / KG 50KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd
2-(Bromomethyl)naphthalene pictures 2025-06-20 2-(Bromomethyl)naphthalene
939-26-4
US $0.00 / kg 1kg 0.99 20tons Hebei Yanxi Chemical Co., Ltd.
2-(BROMOMETHYL)NAPHTHALENE 2-BMN BROMOMETHYLNAPTHALENE-2 2-Bromomethylnaphthalene98% 2-(Bromomethyl)naphthalene,96% (2-Naphtylmethyl) bromide Naphthalene, 2-(bromomethyl)- 2-naphthylmethyl bromide 2-(Bromomethyl)naphthalene 96% 2-(Bromomethyl)naphthalene, tech 2-Naphtylmethyl bromide 2-Bromomethyl naphth 2-(BroMoMethyl)naphthalene, 96% 5GR 2-(broMoMethyl)napthalene 2-(Bromomethyl)phthalene 2-(Xiu Jiaji)naphthalene 2-(Bromomethyl)naphthalene > 2-Bromomethyl naphthalene, 96%, for synthesis naphthylmethyl bromide 2-(Bromomethyl)naphthalene ISO 9001:2015 REACH 2-(brommethyl)naphthalen 3-(Bromomethyl)naphthalene beta-(bromomethyl)naphthalene 939-26-4 934-26-4 C10H7CH2Br C11H9Br3 C11H9Br BENZYL HALIDE Building Blocks Aryl C9 to C12 Organic Building Blocks Halogenated Hydrocarbons Naphthalene series Aryl C9 to C12 Halogenated Hydrocarbons Naphthalene derivatives