2-(2-METHOXY-2-OXOETHYL)BENZOIC ACID
- CAS No.
- 14736-50-6
- Chemical Name:
- 2-(2-METHOXY-2-OXOETHYL)BENZOIC ACID
- Synonyms
- Verazobone impurity 1;2-(2-Methoxy-2-oxoethyl);2-(2-METHOXY-2-OXOETHYL)BENZOIC ACID;Benzeneacetic acid, 2-carboxy-, 1-methyl ester;Benzeneacetic acid, 2-carboxy-, a-Methyl ester
- CBNumber:
- CB7466227
- Molecular Formula:
- C10H10O4
- Molecular Weight:
- 194.18
- MDL Number:
- MFCD00661540
- MOL File:
- 14736-50-6.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2-(2-methoxy-2-oxoethyl)benzoic acid | PAA73650 | 5g | $531 |
| 2-(2-Methoxy-2-oxoethyl)benzoic acid 98% | AS47323 | 1g | $124 |
| 2-(2-Methoxy-2-oxoethyl)benzoic acid 98% | AS47323 | 5g | $360 |
| 2-(2-Methoxy-2-oxoethyl)benzoic acid | 121300 | 1.00g | $106 |
| 2-(2-Methoxy-2-oxoethyl)benzoic acid | 121300 | 5.00g | $227 |
| Melting point | 98-100 °C(Solv: ethyl ether (60-29-7); hexane (110-54-3)) |
|---|---|
| Boiling point | 320.9±17.0 °C(Predicted) |
| Density | 1.254±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| pka | 3.69±0.36(Predicted) |
| Appearance | Light yellow to yellow Solid |
| InChI | InChI=1S/C10H10O4/c1-14-9(11)6-7-4-2-3-5-8(7)10(12)13/h2-5H,6H2,1H3,(H,12,13) |
| InChIKey | UKPMFGARCZOXDI-UHFFFAOYSA-N |
| SMILES | C(O)(=O)C1=CC=CC=C1CC(=O)OC |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H335-H319-H315 |
| Precautionary statements | P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P |
2-(2-METHOXY-2-OXOETHYL)BENZOIC ACID price More Price(38)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | PAA73650 | 2-(2-methoxy-2-oxoethyl)benzoic acid | 14736-50-6 | 5g | $531 | 2026-06-04 | Buy |
| Activate Scientific | AS47323 | 2-(2-Methoxy-2-oxoethyl)benzoic acid 98% | 14736-50-6 | 1g | $124 | 2026-06-04 | Buy |
| Activate Scientific | AS47323 | 2-(2-Methoxy-2-oxoethyl)benzoic acid 98% | 14736-50-6 | 5g | $360 | 2026-06-04 | Buy |
| Matrix Scientific | 121300 | 2-(2-Methoxy-2-oxoethyl)benzoic acid | 14736-50-6 | 1.00g | $106 | 2026-05-18 | Buy |
| Matrix Scientific | 121300 | 2-(2-Methoxy-2-oxoethyl)benzoic acid | 14736-50-6 | 5.00g | $227 | 2026-05-18 | Buy |
2-(2-METHOXY-2-OXOETHYL)BENZOIC ACID Chemical Properties,Uses,Production
Synthesis
67-56-1
89-51-0
716-43-8
14736-50-6
The general procedure for the synthesis of methyl 2-(2-methoxy-2-oxoethyl)benzoate and 2-(2-methoxy-2-oxoethyl)benzoic acid from methanol and o-carboxybenzeneacetic acid was as follows: o-carboxybenzeneacetic acid (2.01 g, 10.0 mmol) was dissolved in methanol (10 mL), and the resultant solution was transferred to a syringe and mounted on a syringe pump. This methanol solution was pumped at a flow rate of 0.177 mL/min into a stainless steel column (4.0 mm ID x 50 mm length, 0.53 mL internal volume) filled with HO-SAS (334 mg). The column was immersed in an oil bath preheated to 110 °C and a back pressure regulator was connected to maintain the system pressure at 75 psi.The reaction effluent was discarded during the initial 10 min of the reaction, followed by the collection of the reaction mixture over 3 min and the addition of n-decane as an internal standard for the gas chromatographic analysis. The reaction effluent was continued to be collected in a glass flask for 30 min, after which the solvent was removed by rotary evaporation. The crude product was purified by silica gel fast column chromatography (eluent ratio hexane/ethyl acetate = 5/1) to give the final target product methyl 2-(2-methoxy-2-oxoethyl)benzoate (1.13 g, 99% yield).
References
[1] Journal of Chemical Research - Part S, 2000, # 6, p. 282 - 283
[2] Bulletin of the Chemical Society of Japan, 2017, vol. 90, # 5, p. 607 - 612
[3] Tetrahedron Letters, 2003, vol. 44, # 51, p. 9205 - 9208
[4] Journal of the Indian Chemical Society, 1987, vol. 64, # 1, p. 34 - 37
2-(2-METHOXY-2-OXOETHYL)BENZOIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
2-(2-METHOXY-2-OXOETHYL)BENZOIC ACID Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-15225627621 +86-13213167925 | jiuyitime@fdachem.com | China | 16511 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Dideu Industries Group Limited | +86-29-89586680 +86-15129568250 | 1059@dideu.com | China | 29093 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| Suzhou ARTK Medchem Co., Ltd. | +8618118463618 | sales1@artkmedchem.com | China | 39021 | 58 |
| DAYANG CHEM (HANGZHOU) CO.,LTD | +86-88938639 +86-17705817739 | info@dycnchem.com | China | 53803 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131956 | 58 |
| Wuhan Brin Technology Co., Ltd. | 3456065315 13260619011 | 3456065315@qq.com | China | 2418 | 58 |
| PharmaBlock Sciences (Nanjing),Inc. | 025-86918202 4000255188 | sales@pharmablock.com | China | 5000 | 55 |
| Baiyin Chengze Chemical Technology Co., Ltd. | +86 943-8535351 13389336721 | sales@chengzechem.com | China | 300 | 58 |
View Lastest Price from 2-(2-METHOXY-2-OXOETHYL)BENZOIC ACID manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-07-02 | 2-(2-Methoxy-2-oxoEthyl)benzoic acid
14736-50-6
|
$2.20-8.80 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD |
-
- 2-(2-Methoxy-2-oxoEthyl)benzoic acid
14736-50-6
- $2.20-8.80
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
