ChemicalBook >> CAS DataBase List >>(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE structure

CAS No.: 500997-70-6

Chemical Name:: (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE

Synonyms: (S)-SIPHOS-PE;(R)-SIPHOS-PE;(S)-SIPHOS-PE 97%;(SA,R,R)-SIPHOS-PE;(S)-SIPHOS-PE;(Sa,R,R)-SIPHOS-PE（WS200893）;N-DI[(R)-1-PHENYLETHYL]-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE;N-DI[(R)-1-PHENYLETHYL]-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE;N-Di[(R)-1-phenylethyl]-[(S)-1,1'-spirobiindane-7,7'-diyl]-phosphoramidite ,98%;N,N-bis((R)-1-phenylethyl)-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine

CBNumber:: CB7471614

Molecular Formula:: C33H32NO2P

Molecular Weight:: 505.59

MDL Number:: MFCD08459342

MOL File:: 500997-70-6.mol

MSDS File:: SDS

Last updated:2026-01-13 11:25:38

Product description	Number	Pack Size	Price
(S)-SIPHOS-PE 97%	700762	250mg	$629
(S)-SIPHOS-PE 97%	700762	50mg	$155
(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (S)-SIPHOS-PE	15-5163	100mg	$160
(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (S)-SIPHOS-PE	15-5163	500mg	$632
(S)-SIPHOS-PE 95.00%	CCH0001800	250MG	$850.14
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Properties

Melting point	99-101°C
alpha	-63.5° (c 1.0, CH2Cl2)
Boiling point	617.8±65.0 °C(Predicted)
storage temp.	-20°C
form	solid
pka	0.40±0.20(Predicted)
color	white
optical activity	[α]22/D 65.0°, c = 1 in chloroform
Sensitive	moisture sensitive
InChIKey	ZXLQLIDJAURBDD-HRPAVAKOSA-N
SMILES	C[C@@H](N([C@H](C)c1ccccc1)P2Oc3cccc4CCC5(CCc6cccc(O2)c56)c34)c7ccccc7
UNSPSC Code	12352005
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P261-P305+P351+P338
PPE	dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36/37
WGK Germany	3
Storage Class	11 - Combustible Solids
Hazard Classifications	Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE price More Price(6)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	700762	(S)-SIPHOS-PE 97%	500997-70-6	250mg	$629	2025-07-31	Buy
Sigma-Aldrich	700762	(S)-SIPHOS-PE 97%	500997-70-6	50mg	$155	2023-06-20	Buy
Strem Chemicals	15-5163	(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (S)-SIPHOS-PE	500997-70-6	100mg	$160	2024-03-01	Buy
Strem Chemicals	15-5163	(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (S)-SIPHOS-PE	500997-70-6	500mg	$632	2024-03-01	Buy
American Custom Chemicals Corporation	CCH0001800	(S)-SIPHOS-PE 95.00%	500997-70-6	250MG	$850.14	2021-12-16	Buy

Product number	Packaging	Price	Buy
700762	250mg	$629	Buy
700762	50mg	$155	Buy
15-5163	100mg	$160	Buy
15-5163	500mg	$632	Buy
CCH0001800	250MG	$850.14	Buy

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Chemical Properties,Uses,Production

Reaction

Chiral ligands for copper-catalyzed asymmetric allylic alkylation with dialkylzincs.
Chiral ligands for copper-catalyzed asymmetric conjugate addition of diethylzinc to enones.
Chiral ligands for palladium-catalyzed asymmetric hydrosilylation of styrenes
Chiral ligands for copper-catalyzed asymmetric ring-opening of oxabicyclic alkenes with Grignard reagents.
Chiral ligands for nickel-catalyzed asymmetric hydrovinylation of α-alkyl vinylarenes.
Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic enamines.
Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic imines.
Chiral ligands for gold-catalyzed asymmetric [2 + 2] cycloaddition reaction.
Chiral ligands for rhodium-catalyzed asymmetric hydroacylation of salicylaldehydes to homoallylic sulfides.
Chiral ligands for palladium-catalyzed asymmetric carboamination reactions.

Uses

(S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize:

Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles.
Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et₂Zn) to cyclic enones.
Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Preparation Products And Raw materials

Raw materials

CALCIUM HYDRIDE (R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE Acetone Triethylamine Phosphorus trichloride

Tetrahydrofuran Ethyl acetate PETROLEUM ETHER (S)-1,1'-SPIROBIINDANE-7,7'-DIOL n-Butyllithium

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Preparation Products

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Suppliers

Global( 52)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	13620	58
Shanghai Arbor Chemical Co., Ltd.	021-60451682	act@arborchemical.com	CHINA	904	58
Dayang Chem (Hangzhou) Co.,Ltd.	+86-0571-88938639 +8617705817739	info@dycnchem.com	China	52846	58
Labnetwork lnc.	+86-27-50766799 +8618062016861	contact@labnetwork.com	China	19987	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	+86-057181025280; +8617767106207	sales@molcore.com	China	49734	58
GIHI CHEMICALS CO.,LIMITED	+86-571-86217390; +8618058761490	info@gihichemicals.com	China	49958	58
Aladdin Scientific		tp@aladdinsci.com	United States	57505	58
J & K SCIENTIFIC LTD.	18210857532; 18210857532	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006356688 18621169109	market03@meryer.com	China	40228	62
BeiJing Hwrk Chemicals Limted	0757-86329057 18934348241	sales4.gd@hwrkchemical.com	China	14063	55

Supplier	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	58
Shanghai Arbor Chemical Co., Ltd.	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
Labnetwork lnc.	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	58
GIHI CHEMICALS CO.,LIMITED	58
Aladdin Scientific	58
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
BeiJing Hwrk Chemicals Limted	55

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE Spectrum

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE(500997-70-6)¹HNMR

500997-70-6((11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE)Related Search:

3A,4,7,7A-TETRAHYDROINDENE Indene (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE (Ra,S)-Ph-Bn-SIPHOX (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP

(R)-SIPHOS-PE (S)-SIPHOS-PE N-DI[(R)-1-PHENYLETHYL]-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE N-DI[(R)-1-PHENYLETHYL]-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1-PHENYLETHYL]AMINE (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine,min.98%(S)-SIPHOS-PE (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ, 7μ-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, N-Di[(R)-1-phenylethyl]-[(S)-1,1μ-spirobiindane-7,7μ-diyl]-phosphoramidite N-Di[(R)-1-phenylethyl]-[(S)-1,1'-spirobiindane-7,7'-diyl]-phosphoramidite ,98% (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine (11aS)- 10,11,12,13-tetrahydro-N,N-bis[(1R)-1-phenylethyl]-Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-aMine (SA,R,R)-SIPHOS-PE (S)-SIPHOS-PE 97% (11aS)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,99%e.e. (Sa,R,R)-SIPHOS-PE（WS200893） Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-bis[(1R)-1-phenylethyl]-, (11aS)- N,N-bis((R)-1-phenylethyl)-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine (S)-SIPHOS-PE,(S,R,R)-SIPHO,(11aS)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1'',7''-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine (11aS)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine (11aS)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (S)-SIPHOS-PE (S)-N,N-bis((R)-1-phenylethyl)-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine (11aS)-N,N-Bis[(R)-1-phenylethyl]-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine 500997-70-6 C33H32NO2P Chiral Phosphine Chiral Spiro Ligand CPN