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Triiron tetraoxide

CAS No.
1317-61-9
Chemical Name:
Triiron tetraoxide
Synonyms
BLACK IRON OXIDE;MAGNETITE;PIGMENT BLACK 11;Black Ferric Oxide;Fe3-O4;Iron oxide (Fe3O4);IRON(II,III) OXIDE;FexOy;E 172;triiron
CBNumber:
CB7752940
Molecular Formula:
Fe3O4-2
Molecular Weight:
231.53
MDL Number:
MFCD00011010
MOL File:
1317-61-9.mol
MSDS File:
SDS
Last updated:2026-06-24 18:39:39

Triiron tetraoxide Properties

Melting point 1538 °C(lit.)
Density 4.8-5.1 g/mL at 25 °C(lit.)
bulk density 0.84g/mL
refractive index 3.0
Flash point 7 °C
storage temp. -20°C
solubility Aqueous Acid (Slightly)
form powder
color black
Specific Gravity 5.2
Odor at 100.00%. odorless
Water Solubility Insoluble in water and organic solvents. Soluble in concentrated mineral acids.
Specific Heat Capacity Cp(crystal): 0.62 J/(g·K), at 25℃
Crystal Structure Inverse spinel type
crystal system Cube
Merck 14,4040
Space group Fd3m
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.839410.839410.839419090900.5915
Stability Stable. Incompatible with strong acids, chloroformates, peroxides.
Major Application battery manufacturing
Cosmetics Ingredients Functions COLORANT
InChI 1S/3Fe.4O
InChIKey SZVJSHCCFOBDDC-UHFFFAOYSA-N
SMILES O=[Fe].O=[Fe]O[Fe]=O
FDA 21 CFR 582.80
CAS DataBase Reference 1317-61-9(CAS DataBase Reference)
FDA UNII XM0M87F357
NIST Chemistry Reference Iron(ii,iii) oxide(1317-61-9)
EPA Substance Registry System Iron oxide (Fe3O4) (1317-61-9)
UNSPSC Code 12352303
NACRES NA.25

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
GHS02,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H225-H304-H315-H336-H361d-H373-H411-H319-H335
Precautionary statements  P210-P261-P273-P281-P301+P310-P331-P280a-P304+P340-P305+P351+P338-P405-P501a
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
RIDADR  3
WGK Germany  -
TSCA  TSCA listed
HS Code  28211000
Storage Class 11 - Combustible Solids
REACH Registrations Active
NFPA 704
0
0 0

Triiron tetraoxide price More Price(113)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 310069 Iron(II,III) oxide powder, <5μm, 95% 1317-61-9 25g $53.2 2026-04-30 Buy
Sigma-Aldrich 310069 Iron(II,III) oxide powder, <5μm, 95% 1317-61-9 500g $397 2026-04-30 Buy
Sigma-Aldrich 51238 Magnetic iron oxide nanoparticles solution 0.3-0.7% Fe basis, 2.5-3.5% solids basis 1317-61-9 1ML $139 2025-07-31 Buy
Sigma-Aldrich 51238 Magnetic iron oxide nanoparticles solution 0.3-0.7% Fe basis, 2.5-3.5% solids basis 1317-61-9 5ML $480 2025-07-31 Buy
Strem Chemicals 93-2616 Iron(II,III) oxide, black (Magnetite), min. 95% min.95% 1317-61-9 500g $47 2026-04-30 Buy
Product number Packaging Price Buy
310069 25g $53.2 Buy
310069 500g $397 Buy
51238 1ML $139 Buy
51238 5ML $480 Buy
93-2616 500g $47 Buy

Triiron tetraoxide Chemical Properties,Uses,Production

Physical Properties

Black cubic crystal or amorphous powder; refractive index 2.42; density 5.17 g/cm3; Moh’s hardness 6.0; melts at 1,597°C; insoluble in water, soluble in acids.

Occurrence and Uses

Triiron tetroxide occurs in nature as the mineral magnetite, the magnetic oxide of iron. This mineral along with hematite is used as the starting material for producing iron, steel and other ferro-alloys.

Preparation

Triiron tetroxide is obtained from its natural mineral magnetite. In the laboratory the compound may be prepared by adding sodium hydroxide solution to an aqueous solution of 1:2 molar mixture of ferrous and ferric salt. (i.e., 1 mol FeCl2 + 2 mol FeCl3). The resulting black precipitate of the hydroxide on heating dehydrates to gives triiron tetroxide:
Fe2+(aq) + 2Fe3+(aq) + 8OH¯(aq) → Fe3(OH)8(s)
Fe3(OH)8(s) → Fe3O4(s) + 4H2O(g)
Also, the tetroxide may be produced by partial oxidation of iron or iron(II) sulfate by heating under limited amount of air. Another method of production involves heating iron metal with steam:
3Fe + 4H2O → Fe3O4 + 4H2

Reactions

Triiron tetroxide, when heated at elevated temperatures with a reducing agent such as hydrogen or carbon monoxide in the absence of air, produces metallic iron:
Fe3O4 + 4H2 → 3Fe + 4H2O
Partial reduction gives iron(II) oxide. When treated with concentrated acids, the tetroxide dissolves in acids forming mixtures of iron(II) and iron(III) salts:
Fe3O4 + 8HCl → FeCl2 + 2FeCl3 + 4H2O
Fe3O4 + 4H2SO4 → FeSO4 + Fe2(SO4)3 + 4H2O

Chemical Properties

solid

Chemical Properties

Magnetite (Fe3O4) constitutes the richest ore of iron; it is black and magnetic, one variety being called "lodestone".

Uses

Triiron tetraoxide can be used as pigment in paints, linoleum, ceramic glazes; in coloring glass; as a polishing compound; in the textile industry; in cathodes; as catalyst.

Uses

Mostly it is used as a black- pigment -catalyst in the Haber process and in the water gas shift reaction. It is used as a contrast-agent in MRI scanning, whereas it is used as a pigment in magnetic applications, polishing compounds, cosmetics, medicines, polymer, rubber, filler, building, construction, appliances, and magnetic inks.

Uses

Iron(II,III) oxide (Fe3O4) can be used as a heterogeneous catalyst for the Fenton type oxidation of rhodamine B. It can be used as an anode material for the fabrication of lithium-ion batteries. Fe3O4 can also be utilized in the catalysis of the oxygen reduction reaction (ORR) in the anion exchange membrane fuel cell.

General Description

Concentration 5mg/ml includes total weight nanocrystals plus ligands.

Flammability and Explosibility

Non flammable

Properties and Applications

TEST ITEMS

SPECIFICATION

APPEARANCE

BLACK POWDER

CONTENT OF Fe 3 O 4

90% min

pH VALUE

5-8

DENSITY

4.5 g/ml

SHADE

CLOSE TO STANDARD

OIL ABSORPTION

10-20%

RESIDUE ON 320 MESH

0.3% max

WATER SOLUBLE

0.3% max

VOLATITE 105 °C

1.0% max

TINTING STRENGTH

98-102 %

Global( 397)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Buwei Applied Materials Technology Co. LTD 021-64112762 18930491979 1460837389@qq.com China 468 58
Shanghai Yaotian New Material Technology Co., LTD 021-64110338 18939791287 2953588414@qq.com China 181 58
yimo organism 15915870272; 15915870272 yimo_bio@163.com China 286 58
ZHEJIANG YAMEI NANO TECHNOLOGY CO., LTD. 400-8200386 13456373028 2533928531@qq.com China 320 58
BROFOS NANOTECHNOLOGY(NINGBO)CO ,LTD. 0574-62615397 17757424292 brofosnano@foxmail.com China 206 58
Yumu (Ningbo) New Materials Co., Ltd. 13116661121 yumuningbo@foxmail.com China 146 58
Zhejiang Manli Nano Technology Co., Ltd. 15356045737 15356045737 739000136@qq.com China 60 58
Tianjin Jinhui Taiya Chemical Reagent Co., Ltd 022-59582624 18622766592 2163746375@qq.com China 271 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84

View Lastest Price from Triiron tetraoxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Triiron tetraoxide pictures 2026-09-13 Triiron tetraoxide
1317-61-9
0.99 RongNa Biotechnology Co.,Ltd
Triiron tetraoxide pictures 2025-12-24 Triiron tetraoxide
1317-61-9
1KG 99.0% 10000KG Shaanxi Dideu Medichem Co. Ltd
Triiron tetraoxide pictures 2025-06-27 Triiron tetraoxide
1317-61-9
1KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd

Triiron tetraoxide Spectrum

Iron(Ⅱ,Ⅲ) oxide TRIIRON TETRAOXIDE Ferric ferrous oxide ferrosoferricoxide Iron oxide (Fe3O4) ironoxide(fe3o4) triiron Triirontetroxide FERROSOFERRIC OXIDE BLACK FERROUS/FERRIC OXIDE FERROUS(IC) OXIDE BLACK IRON (II) OXIDE IRON PIGMENT BLACK IRON OXIDE PIGMENT BLACK IRON(II,III) OXIDE IRON (II,III) OXIDE, BLACK IRON (II,III) OXIDE MAGNETOFLUID IRON(+2,+3)OXIDE IRON(II) DIIRON(III) OXIDE IRON(II,III) OXIDE SOLUTION, NANOPARTIC& Iron(III) oxide, powder, <5 micron, 98% IRON(II,III) OXIDE, 99.999% IRON (II,III) OXIDE, NANOPOWDER, 98+% IRON OXIDE BLACK PURIFIED Iron(II,III)oxide,black(Magnetite),min.95% iron(ii,iii) oxide, puratronic FERROSOFERRICOXIDE,BLACK,POWDER IRON (II,III) OXIDE: BLACK (MAGNETITE), 95%, 0.5 MICRON Iron(II,III) oxide, Puratronic(R), 99.997% (metals basis) Iron(II,III) oxide, 98% (metals basis) Iron(II,III) oxide, 97% (metals basis) Iron(II,III) oxide, 99.95% (metals basis) Iron(II,III) oxide: (Ferrosoferric oxide: Iron(III) oxide) Iron (II, III) oxide, 99.5% min (metals basis) Iron (II,III) oxide, 96% (metals basis) Synthetic black iron oxide Iron(II,III) oxide, Puratronic, 99.997% (metals basis) Iron oxide, magnetic nanoparticles solution Magnetite, Superparamagnetic iron oxide nanoparticles Iron(II,III) oxide solution Iron(II,III) oxide, black (Magnetite) Monodispersed Magnetite Microspheres Magnetic sand concentrate Iron oxide(II,III), Magnetic nanoparticles solution 10 nM avg. part. size, 5 Mg/ML in H2O Iron oxide(II,III), Magnetic nanoparticles solution 20 nM avg. part. size, 5 Mg/ML in H2O Iron oxide(II,III), Magnetic nanoparticles solution 20 nM avg. part. size, 5 Mg/ML in toluene Iron oxide(II,III), Magnetic nanoparticles solution 5 nM avg. part. size, 5 Mg/ML in H2O Iron(II,III) oxide nanopowder, 50-100 nM particle size (TEM), 97% trace Metals basis Iron(II,III) oxide powder, <5 MuM, 95% Fe NP COOH Fe NP NH2 FexOy Iron(II,III) Oxide, Nanopowder, <50NM, 98+% Metal Basis Fe NP NHS Iron oxide(II,III) magnetic nanopowder Monodisperse hydrophilic Fe3O4 nanoparticles Iron oxide(II,III), magnetic nanoparticles solution 10 nm avg. part. size, 5 mg/mL in toluene Iron oxide(II,III), magnetic nanoparticles solution 10 nm diameter, amine functionalized, 1 mg/mL Fe, dispersion in H2O Iron oxide(II,III), magnetic nanoparticles solution 10 nm diameter, carboxylic acid functionalized, 5 mg/mL Fe, dispersion in H2O