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2-Benzothiazolol

CAS No.
934-34-9
Chemical Name:
2-Benzothiazolol
Synonyms
2-HYDROXYBENZOTHIAZOLE;2(3H)-BENZOTHIAZOLONE;Benzo[d]thiazol-2(3H)-one;BENZOTHIAZOLONE;2-BENZOTHIAZOLINONE;benzo[d]thiazol-2-ol;HYDROXYBENZOTHIAZOLE;2-BENZOTHIAZOL;2-BENZOTHIAZOLOL;Compound Fr16664
CBNumber:
CB7854675
Molecular Formula:
C7H5NOS
Molecular Weight:
151.19
MDL Number:
MFCD00792539
MOL File:
934-34-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-27 19:03:18
Product description Number Pack Size Price
2-Hydroxybenzothiazole 98% 407607 5g $48.9
2-Hydroxybenzothiazole 98% 407607 25g $182
2(3H)-Benzothiazolone >98.0%(GC) B2344 5g $36
2(3H)-Benzothiazolone >98.0%(GC) B2344 25g $105
2(3H)-Benzothiazolone B206660 25g $275
More product size

2-Benzothiazolol Properties

Melting point 137-140 °C (lit.)
Boiling point 360°C (rough estimate)
Density 1.2170 (rough estimate)
refractive index 1.5500 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform (Slightly, Sonicated), DMSO (Slightly)
pka 10.41±0.20(Predicted)
form Solid
color White to Off-White
InChI 1S/C7H5NOS/c9-7-8-5-3-1-2-4-6(5)10-7/h1-4H,(H,8,9)
InChIKey YEDUAINPPJYDJZ-UHFFFAOYSA-N
SMILES Oc1nc2ccccc2s1
LogP 1.760
CAS DataBase Reference 934-34-9(CAS DataBase Reference)
FDA UNII 7T26K7NG46
NIST Chemistry Reference 2-Benzothiazolol (keto form)(934-34-9)
EPA Substance Registry System 2(3H)-Benzothiazolone (934-34-9)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332
Precautionary statements  P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn
Risk Statements  20/21/22
Safety Statements  36
WGK Germany  3
TSCA  TSCA listed
HS Code  29061990
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
NFPA 704
1
0 0

2-Benzothiazolol price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 407607 2-Hydroxybenzothiazole 98% 934-34-9 5g $48.9 2026-04-30 Buy
Sigma-Aldrich 407607 2-Hydroxybenzothiazole 98% 934-34-9 25g $182 2026-04-30 Buy
TCI Chemical B2344 2(3H)-Benzothiazolone >98.0%(GC) 934-34-9 5g $36 2026-04-30 Buy
TCI Chemical B2344 2(3H)-Benzothiazolone >98.0%(GC) 934-34-9 25g $105 2026-04-30 Buy
TRC B206660 2(3H)-Benzothiazolone 934-34-9 25g $275 2021-12-16 Buy
Product number Packaging Price Buy
407607 5g $48.9 Buy
407607 25g $182 Buy
B2344 5g $36 Buy
B2344 25g $105 Buy
B206660 25g $275 Buy

2-Benzothiazolol Chemical Properties,Uses,Production

Chemical Properties

off-white to light brown crystalline powder

Uses

2-Hydroxybenzothiazole may be employed as carbon, nitrogen and energy supplement in the bacterial cultures. It may be used in the preparation of insulating thin polymer (<0.1μm), via electropolymerization.

Definition

ChEBI: Benzothiazole substituted with a hydroxy group at the 2-position.

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 4890, 1950 DOI: 10.1021/ja01167a011

General Description

2-Hydroxybenzothiazole (2-OHBT) is a 2-substituted benzothiazole. It is a tautomer of 2-benzothiazolinone. Its enthalpy of formation in the gas phase has been determined using high-level ab initio molecular orbital calculations at the G3(MP2)//B3LYP level of theory. Polarized IR spectra of the hydrogen-bonded molecular crystals of 2-OHBT have been studied. Oxidation of 2-OHBT using H2O2/UV and iron(III) photoassisted Fenton techniques have been reported. 2-OHBT is released into wastewaters during the industrial production of 2-mercaptobenzothiazole, a rubber vulcanization accelerator. The anodic oxidation of 2-OHBT on copper, iron and platinum in alcohol and alcohol-water solutions by cyclic polarization and chronoamperometry has been reported.

Purification Methods

Crystallise it from aqueous EtOH or water. [Hoggarth J Chem Soc 3314 1949, Hunter J Chem Soc 135 1930, Beilstein 27 H 182, 27 I 270, 27 II 225, 27 III/IV 2693.]

137-07-5
934-34-9
Synthesis of 2-Benzothiazolol from 2-Aminobenzenethiol
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View Lastest Price from 2-Benzothiazolol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Benzothiazolone pictures 2026-04-27 Benzothiazolone
934-34-9
US $0.00 / removed ≥98% 10g TargetMol Chemicals Inc.
Benzothiazolone pictures 2026-04-27 Benzothiazolone
934-34-9
US $0.00 / removed ≥98% 10g TargetMol Chemicals Inc.
Benzothiazolone pictures 2025-07-21 Benzothiazolone
934-34-9
US $30.00 / mg ≥98% 10g TargetMol Chemicals Inc.
2(3H)-Benzothiazolone(9CI) 2-Hydroxybenzothiazole, HPLC 97% 2-BENZOTHIAZOL 2-hydroxy benzothiazo1e Benzo[d]thiazol-2(3H)-one 2-Hydroxy-1,3-benzothiazole 98% 2-Oxobenzothiazole 3H-1,3-Benzothiazol-2-one 2,3-Dihydrobenzothiazole-2-one Benzothiazol-2-ol 2-Benzothiazolol,95% 2-Hydroxy-1,3-benzothiazole 2,3-dihydro-1,3-benzothiazol-2-one 2-Benzothiazolol 2-Hydroxybenzothiazole benzo[d]thiazol-2-ol 2-Hydroxybenzthiazole 2(3H)-Benzothiazolone 3H-BENZOTHIAZOL-2-ONE 1,3-BENZOTHIAZOL-2-OL 2(3H)-BENZOTHIAZOLONE 2-HYDROXYBENZOTHIAZOL 2-HYDROXYBENZOTHIAZOLE 2-BENZOTHIAZOLINONE 2-BENZOTHIAZOLOL IFLAB-BB F0918-5160 BENZOTHIAZOLONE 1,3-Benzothiazol-2(3H)-one 2-Benzothiazolone Benzothiazol, 2-hydroxy- Carbamothioic acid, (2-mercatophenyl)-, gamma-lactone TIMTEC-BB SBB005792 benzothiazol-2(3H)-one 2-Hydroxybenzothiazole,98% HYDROXYBENZOTHIAZOLE 2(3H)-Benzothiazolone > Benziothiazolinone-d4 Rosuvastatin Impurity 141 Compound Fr16664 benzothiazolinone 2(3H)-Benzothiazolone in methanol 2-hydroxybenzenebenzothiazole Dotinurad Impurity 138 934-34-9 Thiazoles Heterocyclic Building Blocks Building Blocks pharmacetical BENZOTHIAZOLE