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(S)-(+)-Benzyl glycidyl ether

CAS No.
16495-13-9
Chemical Name:
(S)-(+)-Benzyl glycidyl ether
Synonyms
(S)-BENZYL GLYCIDYL ETHER;BENZYL (S)-(+)-GLYCIDYL ETHER;(2S)-2-[(Benzyloxy)methyl]oxirane;(s)-o-benzylglycidol;(S)-Benzylglycidyether;(S)-Glycidylbenzyl ether;(+)-Benzyl glycidyl ether;(S)-BENZYLOXYMETHYL-OXIRANE;(+)-BENZYL (S)-GLYCIDYL ETHER;(S)-(+)-BENZYL GLYCIDYL ETHER
CBNumber:
CB8164324
Molecular Formula:
C10H12O2
Molecular Weight:
164.2
MDL Number:
MFCD00054428
MOL File:
16495-13-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 03:28:28
Product description Number Pack Size Price
(S)-(+)-Glycidyl benzyl ether 99% 363537 1g $26.4
Benzyl (S)-(+)-Glycidyl Ether >98.0%(GC) B2239 1g $35
Benzyl (S)-(+)-Glycidyl Ether >98.0%(GC) B2239 5g $49
(S)-(+)-Benzyl Glycidyl Ether TRC-B278300-5G 5g $165
(S)-(+)-Benzyl Glycidyl Ether TRC-B278300-25G 25g $536
More product size

(S)-(+)-Benzyl glycidyl ether Properties

Boiling point 130 °C (0.1 mmHg)
alpha 5.1 º (c=5 in toluene)
Density 1.072 g/mL at 20 °C(lit.)
refractive index n20/D 1.517
Flash point >110°C
storage temp. 2-8°C
solubility Chloroform, Ethanol
form Oil
color Colourless
Specific Gravity 1.077
optical activity [α]20/D +5.1°, c = 5 in toluene
BRN 5246495
InChI InChI=1S/C10H12O2/c1-2-4-9(5-3-1)6-11-7-10-8-12-10/h1-5,10H,6-8H2/t10-/m1/s1
InChIKey QNYBOILAKBSWFG-SNVBAGLBSA-N
SMILES O1C[C@H]1COCC1=CC=CC=C1
CAS DataBase Reference 16495-13-9(CAS DataBase Reference)
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
RTECS  TX2860030
HS Code  29109000
Storage Class 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Toxicity mic-sat 660 nmol/plate MUREAV 298,197,1993
NFPA 704
0
2 0

(S)-(+)-Benzyl glycidyl ether price More Price(100)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 363537 (S)-(+)-Glycidyl benzyl ether 99% 16495-13-9 1g $26.4 2026-04-30 Buy
TCI Chemical B2239 Benzyl (S)-(+)-Glycidyl Ether >98.0%(GC) 16495-13-9 1g $35 2026-04-30 Buy
TCI Chemical B2239 Benzyl (S)-(+)-Glycidyl Ether >98.0%(GC) 16495-13-9 5g $49 2026-04-30 Buy
TRC TRC-B278300-5G (S)-(+)-Benzyl Glycidyl Ether 16495-13-9 5g $165 2026-06-03 Buy
TRC TRC-B278300-25G (S)-(+)-Benzyl Glycidyl Ether 16495-13-9 25g $536 2026-06-03 Buy
Product number Packaging Price Buy
363537 1g $26.4 Buy
B2239 1g $35 Buy
B2239 5g $49 Buy
TRC-B278300-5G 5g $165 Buy
TRC-B278300-25G 25g $536 Buy

(S)-(+)-Benzyl glycidyl ether Chemical Properties,Uses,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(S)-(+)-Benzyl Glycidyl Ether is used as a reactant in the synthesis of (+)-Discodermolide.

Uses

(S)-(+)-Glycidyl benzyl ether may be employed for the total asymmetric synthesis of (+)-gigantecin.

General Description

(S)-(+)-Glycidyl benzyl ether is aryl glycidyl ether. Enantiomerically pure aryl and benzyl glycidyl ethers have been reported to undergo stereospecific cyclizations, affording 3-chromanols or tetrahydrobenzo[c]oxepin-4-ols. (S)-benzyl glycidyl ether has been produced with 30%ee along with (R)-3-benzyloxypropane-1,2-diol with 40%ee, via its resolution using whole cells of Bacillus alcalophilus.

Safety Profile

Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.

Purification Methods

This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]

(S)-(+)-Benzyl glycidyl ether Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 270)Suppliers
Supplier Tel Email Country ProdList Advantage
Allfluoro pharmaceutical co. ltd.
+86-400-0216110 +86-15958047586 sales@allfluoro.com China 11385 58
Nantong Provichem Biotech Co., Ltd.
+8617505220108 sales@provichem.cn China 34 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-86-13131129325 +8613131129325 sales1@chuanghaibio.com China 5228 58
Shaanxi Didu New Materials Co. Ltd
+86-86-17392712697 +8617792793228 1069@dideu.com China 8609 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29640 60
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070 product@chemlin.com.cn CHINA 3009 60
Shanghai Arbor Chemical Co., Ltd.
021-60451682 act@arborchemical.com CHINA 904 58
Jinan Carbotang Biotech Co.,Ltd.
+8615866703830 figo.gao@foxmail.com China 8497 58
Changzhou Ditong Chemical Co.,Ltd
+86-0519-88298848 info@edengenechem.com China 2165 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58

View Lastest Price from (S)-(+)-Benzyl glycidyl ether manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S)-(+)-Benzyl glycidyl ether pictures 2026-06-03 (S)-(+)-Benzyl glycidyl ether
16495-13-9
$10.00 1kg ≥98.0% 20 tons Nantong Provichem Biotech Co., Ltd.
(S)-(+)-Benzyl glycidyl ether pictures 2026-05-28 (S)-(+)-Benzyl glycidyl ether
16495-13-9
$10.70 10KG 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
(S)-(+)-Benzyl glycidyl ether pictures 2026-05-15 (S)-(+)-Benzyl glycidyl ether
16495-13-9
$1.50 1g 99.0% Min 10 Tons Shaanxi Didu New Materials Co. Ltd
(S)-(+)-2-(BENZYLOXYMETHYL)OXIRANE (S)-(+)-1-BENZYLOXY-2,3-EPOXYPROPANE (S)-1-BENZYLOXY-2,3-EPOXYPROPANE (S)-(+)-BENZYL GLYCIDYL ETHER (S)-BENZYLOXYMETHYL-OXIRANE (s)-o-benzylglycidol (S)-(+)-Glycidyl benzyl ether puriss., >=99.0% (sum of enantiomers, GC) (S)-Benzyl Glycidyl Ether,99%e.e. (+)-BENZYL (S)-GLYCIDYL ETHER BENZYL (S)-(+)-GLYCIDYL ETHER, 99+% (2S)-2β-(Benzyloxymethyl)oxirane (S)-Glycidylbenzyl ether (S)-(+)-GLYCIDYL BENZYL ETHER ((S)-(+)-2-(BENZYLOXYMETHYL)OXIRANE) Benzyl (S)-(+)-glycidyl ether, 98+% (S)-(+)-Benzyl glycidyl ether,98% Benzyl (S)-(+)-2,3-Epoxypropyl Ether (S)-(+)-1-Benzyloxy-2,3-epoxypropane (S)-(+)-2-(Benzyloxymethyl)oxirane Benzyl (S)-(+)-glycidyl ether, ee: 99% Benzyl (S)-(+)-glycidyl ether, 98%, ee: 99% (S)-Benzyl glycidyl ether 97% 4-a (S)-(+)-Benzyl glycidyl etherHYDROXYBENZENESULFONIC ACID SODIUM SALT DIHYDRATE Benzyl (S)-(+)-Glycidyl Ether > Oxirane, 2-[(phenylmethoxy)methyl]-, (2S)- (2S)-2-(phenylmethoxymethyl)oxirane (+)-Benzyl glycidyl ether (S)-Benzylglycidyether (S)-(+)-Glycidyl benzyl ether Benzyl (S)-(+)-glycidyl ether, 98%min (+)-Benzyl-(S)-glycidyl ether (2S)-2-[(Benzyloxy)methyl]oxirane (S)-BENZYL GLYCIDYL ETHER BENZYL (S)-(+)-GLYCIDYL ETHER 16495-13-9 Cd0H12O2 Asymmetric Synthesis Epoxides Organic Building Blocks Oxiranes Glycidyl Compounds, etc. (Chiral) Simple 3-Membered Ring Compounds Chiral Building Blocks Chiral Building Blocks Glycidyl Compounds, etc. (Chiral) Oxiranes Simple 3-Membered Ring Compounds Synthetic Organic Chemistry Chiral Compound chiral CHIRAL COMPOUNDS