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Propiolic Acid

CAS No.
471-25-0
Chemical Name:
Propiolic Acid
Synonyms
PROPYNOIC ACID;propiolic;Propynoate;Propinoic acid;PROPARGYLIC ACID;2-PROPYNIOC ACID;HCequivCCOOH;PROPIOLIC ACID;Propiolic acidd;2-PROPYNOIC ACID
CBNumber:
CB8195906
Molecular Formula:
C3H2O2
Molecular Weight:
70.05
MDL Number:
MFCD00004360
MOL File:
471-25-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-24 14:58:11
Product description Number Pack Size Price
Propiolic acid 95% P51400 5g $48.8
Propiolic acid 95% P51400 25g $143
Propiolic Acid >97.0%(GC)(T) P0497 5g $60
Propiolic Acid >97.0%(GC)(T) P0497 25g $264
Propiolic acid 95% P51400 100g $291
More product size

Propiolic Acid Properties

Melting point 16-18 °C (lit.)
Boiling point 102 °C/200 mmHg (lit.)
Density 1.138 g/mL at 25 °C (lit.)
refractive index n20/D 1.431(lit.)
Flash point 138 °F
storage temp. 2-8°C
solubility Chloroform (Soluble), Methanol (Soluble)
pka 1.84(at 25℃)
form Liquid After Melting
color Clear colorless to light brown
Specific Gravity 1.138
Water Solubility miscible
Merck 14,7821
BRN 878176
Stability Stable. Incompatible with bases, oxidizing agents, reducing agents. Combustible.
InChI 1S/C3H2O2/c1-2-3(4)5/h1H,(H,4,5)
InChIKey UORVCLMRJXCDCP-UHFFFAOYSA-N
SMILES OC(=O)C#C
CAS DataBase Reference 471-25-0(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII P2QW39G9LZ
NIST Chemistry Reference Propiolic acid(471-25-0)
EPA Substance Registry System 2-Propynoic acid (471-25-0)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H226-H301-H310-H314
Precautionary statements  P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  T
Risk Statements  24/25-34-25-23/24/25
Safety Statements  26-36/37/39-45-24/25-7/9
RIDADR  UN 2920 8/PG 2
WGK Germany  3
RTECS  UD9300000
3-8
TSCA  TSCA listed
HazardClass  8
PackingGroup  II
HS Code  29161980
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 2 Dermal
Acute Tox. 3 Oral
Eye Dam. 1
Flam. Liq. 3
Skin Corr. 1B
Hazardous Substances Data 471-25-0(Hazardous Substances Data)
Toxicity guinea pig,LD50,skin,100mg/kg (100mg/kg),"Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2n rev. ed. in 1985.Vol. 2C, Pg. 4953, 1982.
Limited Quantities 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
2
3 0

Propiolic Acid price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich P51400 Propiolic acid 95% 471-25-0 5g $48.8 2026-03-19 Buy
Sigma-Aldrich P51400 Propiolic acid 95% 471-25-0 25g $143 2026-03-19 Buy
TCI Chemical P0497 Propiolic Acid >97.0%(GC)(T) 471-25-0 5g $60 2026-03-19 Buy
TCI Chemical P0497 Propiolic Acid >97.0%(GC)(T) 471-25-0 25g $264 2026-03-19 Buy
Sigma-Aldrich P51400 Propiolic acid 95% 471-25-0 100g $291 2026-03-19 Buy
Product number Packaging Price Buy
P51400 5g $48.8 Buy
P51400 25g $143 Buy
P0497 5g $60 Buy
P0497 25g $264 Buy
P51400 100g $291 Buy

Propiolic Acid Chemical Properties,Uses,Production

Chemical Properties

viscous yellow liquid

Uses

Propiolic acid is an intermediate in monohalogenated acetylene synthesis and a corrosion inhibitor for steel.

Uses

Propiolic acid is a reagent used in the preparation of transition metal complexes, haloalkyl propiolates and halopropenoates.

Uses

Reagent employed in the synthesis of transition metal complexes, haloalkyl propiolates, and halopropenoates.

Definition

ChEBI: A terminal acetylenic compound that is a 3-carbon, straight-chain, monounsaturated fatty acid having one acetylenic bond.

References

[1] Elmer Raunio, Louis Remsberg and Jr. “Notes- Potassium Hydroxide as a Catalyst for the Condensation of Propiolic Acid or Propiolic Esters with Ketones.” The Journal of Organic Chemistry 25 8 (1960): 1436–1437.
[2] K. Okuma, Toshiyuki Shigetomi, M. Koda. “Reaction of Selenoketones with Propiolic Acid.” Phosphorus Sulfur and Silicon and The Related Elements 9 5 1 (2008): 1057–1060.
[3] Dirk Hollenwger* and Andreas J. Kornath. “Synthesis and Structure of Protonated Propiolic Acid.” The Journal of Organic Chemistry 89 16 (2024): 11421-11428 11421-11428.

Global( 257)Suppliers
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View Lastest Price from Propiolic Acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Propiolic Acid pictures 2026-03-20 Propiolic Acid
471-25-0
US $1.00 / kg 1kg 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
Propiolic Acid pictures 2019-07-06 Propiolic Acid
471-25-0
US $1.00 / KG 1KG 97% 200KG Career Henan Chemical Co
  • Propiolic Acid pictures
  • Propiolic Acid
    471-25-0
  • US $1.00 / kg
  • 99%
  • Hebei Chuanghai Biotechnology Co., Ltd
ACETYLENECARBOXYLIC ACID 2-PROPYNIOC ACID 2-PROPYNOIC ACID PROPYNOIC ACID PROPIOLIC ACID Propiolic acidd PROPARGYLIC ACID Propiolic acid, 98+% Carboxyacetylene HCequivCCOOH Propinoic acid propiolic Acetylenecarboxylic acid~Propargylic acid~Propynoic acid Acetylene monocarboxylic acid PROPIOLIC ACID, 80% SOLUTION in THF 2-Propyne-1-carboxylic acid Propynoate PROPIOLIC ACID: 80% (CONTAINS 20% THF) Acetylenecarboxylic Acid 〔Propargylic Acid〕 Acetylenecarboxylic acid for synthesis Propiolic acid ,97.5% Propiolic acid, Acetylenecarboxylic acid Propiolic acid, 98% 10ML Propiolic acid, 98% 25ML Acetylenecarboxylic acid, Propynoic acid Propiolic acid 95% PropiolicAcid> propiolic-2,3-14C2 acid Propiolic acidd 471-25-0 Propiolic acid, 90% 2-PROPYNIOC ACID Rufinamide 471-25-0 HCCCO2H CHCCOOH HCCCOOH C3H2O2 HC8801CCOOH C3HO2 Organic Building Blocks Carboxylic Acids Carbonyl Compounds C1 to C5 Building Blocks Diyne Compounds (LB Films) Acetylenic Carboxylic Acids & Their Derivatives LB Films Acetylenes fine chemicals Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts Acetylenes Acetylenic Carboxylic Acids & Their Derivatives Diyne Compounds (LB Films) Functional Materials LB Films