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2-Bromo-1-bromomethyl-5-chlorobenzene

2-Bromo-1-bromomethyl-5-chlorobenzene Structure
2-Bromo-1-bromomethyl-5-chlorobenzene structure
CAS No.
66192-24-3
Chemical Name:
2-Bromo-1-bromomethyl-5-chlorobenzene
Synonyms
2-Bromo-1-bromomethyl-5-chlorobenzene;Benzene, 1-bromo-2-(bromomethyl)-4-chloro-
CBNumber:
CB82502904
Molecular Formula:
C7H5Br2Cl
Molecular Weight:
284.38
MDL Number:
MFCD09743743
MOL File:
66192-24-3.mol
MSDS File:
SDS
Last updated:2026-05-28 04:34:33
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2-Bromo-1-bromomethyl-5-chlorobenzene Properties

Melting point 63-64°C
Boiling point 281.5±25.0 °C(Predicted)
Density 1.933
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Solid
color White
InChI InChI=1S/C7H5Br2Cl/c8-4-5-3-6(10)1-2-7(5)9/h1-3H,4H2
InChIKey UTKGZXVMMFBCJC-UHFFFAOYSA-N
SMILES C1(Br)=CC=C(Cl)C=C1CBr

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

2-Bromo-1-bromomethyl-5-chlorobenzene price More Price(44)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC TRC-B680600-25G 2-Bromo-1-bromomethyl-5-chlorobenzene 66192-24-3 25g $139 2026-06-03 Buy
TRC TRC-B680600-1G 2-Bromo-1-bromomethyl-5-chlorobenzene 66192-24-3 1g $109 2026-06-03 Buy
TRC TRC-B680600-10G 2-Bromo-1-bromomethyl-5-chlorobenzene 66192-24-3 10g $129 2026-06-03 Buy
Biosynth FB19053 2-Bromo-1-bromomethyl-5-chlorobenzene 66192-24-3 0.05kg $150 2026-06-04 Buy
Biosynth FB19053 2-Bromo-1-bromomethyl-5-chlorobenzene 66192-24-3 0.025kg $150 2026-06-04 Buy
Product number Packaging Price Buy
TRC-B680600-25G 25g $139 Buy
TRC-B680600-1G 1g $109 Buy
TRC-B680600-10G 10g $129 Buy
FB19053 0.05kg $150 Buy
FB19053 0.025kg $150 Buy

2-Bromo-1-bromomethyl-5-chlorobenzene Chemical Properties, Uses, Production

Chemical Properties

Colourless Oil

Synthesis

1-Bromo-4-chloro-2-methylbenzene

14495-51-3

2-Bromo-1-bromomethyl-5-chlorobenzene

66192-24-3

The general procedure for the synthesis of 2-bromo-5-chlorobenzyl bromide from 2-bromo-5-chlorotoluene was as follows: 20.5 g (100 mmol) of 2-bromo-5-chlorotoluene was dissolved in 200 mL of carbon tetrachloride, followed by the addition of 0.2 g (1 mmol) of AIBN (azobisisobutyronitrile) and 19.6 g (110 mmol) of N-bromosuccinimide (NBS). The resulting mixture was refluxed for 2 h and then cooled to room temperature. The reaction mixture was sequentially washed twice with 50 mL of water, then with 50 mL of brine solution and finally dried with anhydrous magnesium sulfate. The solvent was removed by distillation under reduced pressure to give an oil containing a small amount of unreacted material. The oily substance was dissolved in 20 mL of hexane and recrystallized at room temperature to give 22.7 g (80% yield) of 2-bromo-1-bromomethyl-5-chlorobenzene. The product was characterized by 1H NMR (300 MHz, CDCl3): δ 7.50 (d, 1H, J = 8.7 Hz), 7.45 (d, 1H, J = 2.4 Hz), 7.15 (dd, 1H, J = 8.7 Hz, 2.4 Hz), 4.53 (s, 2H).

References

[1] Organic and Biomolecular Chemistry, 2012, vol. 10, # 31, p. 6404 - 6409
[2] Patent: WO2005/123054, 2005, A1. Location in patent: Page/Page column 25
[3] Patent: WO2006/46030, 2006, A2. Location in patent: Page/Page column 28
[4] Organic Letters, 2015, vol. 17, # 19, p. 4654 - 4657
[5] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 19, p. 2903 - 2909

2-Bromo-1-bromomethyl-5-chlorobenzene synthesis

14495-51-3
66192-24-3
Synthesis of 2-Bromo-1-bromomethyl-5-chlorobenzene from 1-Bromo-4-chloro-2-methylbenzene

2-Bromo-1-bromomethyl-5-chlorobenzene Preparation Products And Raw materials

Raw materials

1-Bromo-4-chloro-2-methylbenzene N-Bromosuccinimide AIBN Carbon tetrachloride

Preparation Products

2-Bromo-5-chlorobenzaldehyde

2-Bromo-1-bromomethyl-5-chlorobenzene Suppliers

Global Suppliers ( 145)
Supplier Tel Email Country ProdList Advantage
Xi'an Pure&True New Materials Co., Ltd. 18991218082 13572462239 hongyan.zhao@xianpt.com China 120 58
Henan Evonik Biotechnology Co. LTD 15672878902 hnyingchuang@163.com China 4047 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
PharmaBlock Sciences (Nanjing),Inc. 025-86918202 4000255188 sales@pharmablock.com China 5000 55
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Jia Xing Isenchem Co.,Ltd 0573-85285100 18627885956 isenchem@163.com China 9389 66
Nanjing Chemlin Chemical Co., Ltd 025-83697070 13770331960 info@chemlin.com.cn China 16305 64
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Chemsky（shanghai）International Co.,Ltd. 021-50135380 shchemsky@sina.com China 32273 50
Tianjin Jinyuda Chemical Co., Ltd. 022-58013646 13011382049 sales@jinyudachem.com China 1976 55
Supplier Advantage
Xi'an Pure&True New Materials Co., Ltd. 58
Henan Evonik Biotechnology Co. LTD 58
J & K SCIENTIFIC LTD. 76
PharmaBlock Sciences (Nanjing),Inc. 55
Energy Chemical 61
Jia Xing Isenchem Co.,Ltd 66
Nanjing Chemlin Chemical Co., Ltd 64
Shanghai Hanhong Scientific Co.,Ltd. 64
Chemsky（shanghai）International Co.,Ltd. 50
Tianjin Jinyuda Chemical Co., Ltd. 55

View Latest Price from 2-Bromo-1-bromomethyl-5-chlorobenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromo-1-bromomethyl-5-chlorobenzene pictures 2026-09-02 2-Bromo-1-bromomethyl-5-chlorobenzene
66192-24-3
 $1.00-80.00 1KG 99% Henan Fengda Chemical Co., Ltd
1-Bromo-2-(bromomethyl)-4-chlorobenzene pictures 2026-05-18 1-Bromo-2-(bromomethyl)-4-chlorobenzene
66192-24-3
 1kg 98% Hefei Lbao Physical & Chemical Science Co.,Ltd
2-Bromo-1-bromomethyl-5-chlorobenzene pictures 2025-04-04 2-Bromo-1-bromomethyl-5-chlorobenzene
66192-24-3
 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.

2-Bromo-1-bromomethyl-5-chlorobenzene Spectrum

2-Bromo-1-bromomethyl-5-chlorobenzene(66192-24-3)1HNMR

66192-24-3 (2-Bromo-1-bromomethyl-5-chlorobenzene) Related Search:

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