4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene
- CAS No.
- 335013-18-8
- Chemical Name:
- 4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene
- Synonyms
- 4-Bromo-2-(trifluoromethyl)benzyl bromide 95%;4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene;Benzene, 4-bromo-1-(bromomethyl)-2-(trifluoromethyl)-;4-bromo-1-(bromomethyl)-2-(trifluoromethyl)benzene, 95%min
- CBNumber:
- CB82609902
- Molecular Formula:
- C8H5Br2F3
- Molecular Weight:
- 317.93
- MDL Number:
- MFCD13185414
- MOL File:
- 335013-18-8.mol
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| HS Code | 2902900000 |
4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene price More Price(42)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | PC500538 | 4-Bromo-2-(trifluoromethyl)benzyl bromide 95% | 335013-18-8 | 1g | $41 | 2026-06-04 | Buy |
| Apolloscientific | PC500538 | 4-Bromo-2-(trifluoromethyl)benzyl bromide 95% | 335013-18-8 | 5g | $145 | 2026-06-04 | Buy |
| Apolloscientific | PC500538 | 4-Bromo-2-(trifluoromethyl)benzyl bromide 95% | 335013-18-8 | 25g | $528 | 2026-06-04 | Buy |
| Activate Scientific | AS43371 | 4-Bromo-1-(bromomethyl)-2-(trifluoromethyl)benzene 98% | 335013-18-8 | 1g | $70 | 2026-06-04 | Buy |
| Activate Scientific | AS43371 | 4-Bromo-1-(bromomethyl)-2-(trifluoromethyl)benzene 98% | 335013-18-8 | 5g | $210 | 2026-06-04 | Buy |
4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene Chemical Properties, Uses, Production
Synthesis
86845-27-4
335013-18-8
General procedure for the synthesis of 4-bromo-1-(bromomethyl)-2-(trifluoromethyl)benzene from 5-bromo-2-methyltrifluorotoluene: 5-bromo-2-methyltrifluorotoluene (25 g, 104.59 mmol), N-bromosuccinimide (18.62 g, 104.59 mmol) and benzoyl peroxide (1.27 g, 5.23 mmol) were reacted in a A mixture in carbon tetrachloride (35 mL) was heated and reacted at 90 °C for 4 hours. Upon completion of the reaction, the mixture was cooled to 0 °C and filtered through a glass sand core funnel and the solids were washed with dichloromethane. The filtrates were combined and concentrated and subsequently purified by fast column chromatography (eluent: hexane/ethyl acetate, 0% to 5% ethyl acetate gradient) to give a clear oily product, which was crystallized after standing (33.26 g, 100% yield). The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 4.57 (s, 2H), 7.46 (d, J = 8.3 Hz, 1H), 7.67 (d, J = 8.3 Hz, 1H), 7.78 (s, 1H).
References
[1] Patent: WO2006/18725, 2006, A1. Location in patent: Page/Page column 208
[2] Journal of Labelled Compounds and Radiopharmaceuticals, 2015, vol. 58, # 5, p. 188 - 195
[3] Patent: WO2008/148867, 2008, A2. Location in patent: Page/Page column 37
[4] Patent: WO2009/23964, 2009, A1. Location in patent: Page/Page column 24
[5] Patent: WO2006/46593, 2006, A1. Location in patent: Page/Page column 235
4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| T&W GROUP | 021-61551611 13296011611 | contact@trustwe.com | China | 9884 | 58 |
| Nanjing ShengSai Chemical Co., Ltd. | 025-85205967 13951876367 | shengsaichem@163.com | China | 818 | 58 |
| Mashilabs (Shanghai) Co.,Ltd. | 19916721580 | mafarm@126.com | China | 4534 | 58 |
| Hangzhou J&H Chemical Co., Ltd. | 0571-87396432 | sales@jhechem.com | China | 14905 | 59 |
| Cool Pharm, Ltd | 021-60455363 18019463053 | sales@coolpharm.com | China | 8455 | 58 |
| Changzhou Anxuan Chemical, Co., Ltd. | 13912302692 | sales@anxuanchem.com | China | 4824 | 58 |
| Yancheng KangdiSen Pharmaceutical Co., Ltd. | 13812573443;18052965989 | tongbenwan22@163.com | China | 1975 | 55 |
| Shanghai YuanYe Biotechnology Co., Ltd. | 15026964105 | 2881489226@qq.com | China | 89667 | 60 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131885 | 58 |
| Shanghai CR Corporation Limited | 13917420128 13062833949 | fred.wen@crcorporation.cn | China | 9773 | 58 |
View Latest Price from 4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-06 | 4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene
335013-18-8
|
$1.00 | 1KG | 98% | 200kg | Career Henan Chemical Co |
-
- 4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene
335013-18-8
- $1.00
- 98%
- Career Henan Chemical Co
