5-broMo-2-iodophenol
- CAS No.
- 858855-11-5
- Chemical Name:
- 5-broMo-2-iodophenol
- Synonyms
- 5-Brom-2-iodophenol;5-broMo-2-iodophenol;2-iodine-5-bromophenol;Phenol, 5-bromo-2-iodo-;5-Bromo-2-iodophenol97%;5-Bromo-2-iodophenol 97%;5-broMo-2-iodophenol ISO 9001：2015 REACH
- CBNumber:
- CB82620682
- Molecular Formula:
- C6H4BrIO
- Molecular Weight:
- 298.9
- MDL Number:
- MFCD16999931
- MOL File:
- 858855-11-5.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 5-Bromo-2-iodophenol | IJB85511 | 25g | $389.5 |
| 5-Bromo-2-iodophenol | IJB85511 | 50g | $519 |
| 5-Bromo-2-iodophenol | IJB85511 | 100g | $714 |
| 5-Bromo-2-iodophenol | IJB85511 | 250g | $1427.5 |
| 5-Bromo-2-iodophenol 98% | AS42051 | 1g | $29 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302+H312+H332-H315-H319-H335 |
| Precautionary statements | P280 |
| HS Code | 2908190090 |
5-broMo-2-iodophenol price More Price(48)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | IJB85511 | 5-Bromo-2-iodophenol | 858855-11-5 | 25g | $389.5 | 2026-06-04 | Buy |
| Biosynth | IJB85511 | 5-Bromo-2-iodophenol | 858855-11-5 | 50g | $519 | 2026-06-04 | Buy |
| Biosynth | IJB85511 | 5-Bromo-2-iodophenol | 858855-11-5 | 100g | $714 | 2026-06-04 | Buy |
| Biosynth | IJB85511 | 5-Bromo-2-iodophenol | 858855-11-5 | 250g | $1427.5 | 2026-06-04 | Buy |
| Activate Scientific | AS42051 | 5-Bromo-2-iodophenol 98% | 858855-11-5 | 1g | $29 | 2026-06-04 | Buy |
5-broMo-2-iodophenol Chemical Properties,Uses,Production
Synthesis
38191-34-3
858855-11-5
The general procedure for the synthesis of 5-bromo-2-iodophenol from 2-amino-5-bromophenol was as follows: 2-amino-5-bromophenol (2.50 g, 13.30 mmol) was dissolved in anhydrous THF (12 mL) at -30 to -40 °C and cooled in a dry ice-MeCN bath. Boron trifluoride diethyl ether compound (BF3-Et2O, 4.92 mL, 39.90 mmol) was added slowly and dropwise under nitrogen protection. After the reaction mixture was stirred at -30 °C for 10 min, tert-butyl nitrite (tBuONO, 2.39 mL, 19.94 mmol) was added dropwise. Subsequently, the reaction mixture was slowly warmed to room temperature and stirring was continued for 1.5 hours to form a suspension. Petroleum ether (50 mL) was added to promote precipitation, the supernatant was removed by decantation, and the remaining solid was washed with petroleum ether to give a white solid. The solid was dissolved in dry MeCN (20 mL) and cooled in an ice bath. Potassium iodide (KI, 11.00 g, 66.26 mmol) and iodine (I2, 6.00 g, 23.64 mmol) were added sequentially. The reaction mixture was stirred at room temperature for 4 hours before saturated sodium thiosulfate solution (50 mL) was added to terminate the reaction. The mixture was extracted three times with ethyl acetate, the organic phases were combined, washed sequentially with water and brine, dried over anhydrous sodium sulfate and filtered through a diatomaceous earth pad. The solvent was removed by concentration under reduced pressure and the resulting crude product was purified by silica gel column chromatography using a mixture of ethyl acetate and petroleum ether (v/v 1:9) as eluent to give 5-bromo-2-iodophenol as a light-colored solid in the end (2.83 g, 71% yield).1H NMR (CDCl3) δ 7.50 (d, J=8.5 Hz, 1H), 7.16 (d, J= 2.2Hz, 1H), 6.84 (dd, J=2.2,8.5Hz, 1H), 5.39 (s, 1H) ppm.
References
[1] Patent: WO2015/23355, 2015, A1. Location in patent: Page/Page column 162
[2] Journal of the Chemical Society, 1934, p. 137
5-broMo-2-iodophenol Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
5-broMo-2-iodophenol Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29766 | 58 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 +86-18019713315 | info@accelachem.com | United States | 21189 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5597 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21135 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14301 | 58 |
| Dideu Industries Group Limited | +86-29-89586680 +86-15129568250 | 1059@dideu.com | China | 29096 | 58 |
| Hefei Hirisun Pharmatech Co., Ltd | +8615056975894 | shawn@hirisunpharm.com | CHINA | 9897 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +86-18949823763 | sales@tnjchem.com | China | 25333 | 58 |
| Nanjing Doge Biomedical Technology Co., Ltd | +86-25-58227606 +86-15305155328 | sales@dogechemical.com | China | 4124 | 58 |
View Lastest Price from 5-broMo-2-iodophenol manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-12 | 5-broMo-2-iodophenol
858855-11-5
|
$1.00 | 1KG | 99% | 100kg | Career Henan Chemical Co |
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- 5-broMo-2-iodophenol
858855-11-5
- $1.00
- 99%
- Career Henan Chemical Co
