ChemicalBook >> CAS DataBase List >>2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE

2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE

CAS No.
1835-02-5
Chemical Name:
2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE
Synonyms
2-Bromo-1-(3,4-dimethoxyphenyl)ethan-1-one;NSC 112833;AKOS 90592;AKOS BBS-00003864;2-BroMoacetoveratrone;3,4-DiMethoxyphenacyl BroMide;2-BroMo-3',4'-diMethoxyacetophenone;3',4'-DiMethoxy-2-broMoacetophenone;2-Bromo-3’,4’-dimethoxyacetophenone;2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE
CBNumber:
CB8366861
Molecular Formula:
C10H11BrO3
Molecular Weight:
259.1
MDL Number:
MFCD03425186
MOL File:
1835-02-5.mol
MSDS File:
SDS
Last updated:2026-06-04 16:00:12
Product description Number Pack Size Price
2-Bromo-1-(3,4-dimethoxyphenyl)ethanone TRC-B684075-500MG 500mg $97
2-Bromo-1-(3,4-dimethoxyphenyl)ethanone TRC-B684075-2G 2g $288
2-Bromo-1-(3,4-dimethoxyphenyl)ethanone TRC-B684075-1G 1g $161
3,4-Dimethoxyphenacyl bromide ≥95% OR51867 1g $21
3,4-Dimethoxyphenacyl bromide ≥95% OR51867 5g $24
More product size

2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE Properties

Melting point 81-83°C
Boiling point 326.5±27.0 °C(Predicted)
Density 1.422±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Dichloromethane, Ether, Methanol
form Solid
color Off-White to Light Grey
InChI InChI=1S/C10H11BrO3/c1-13-9-4-3-7(8(12)6-11)5-10(9)14-2/h3-5H,6H2,1-2H3
InChIKey NUAIPKMBWNVQIM-UHFFFAOYSA-N
SMILES C(=O)(C1=CC=C(OC)C(OC)=C1)CBr
CAS DataBase Reference 1835-02-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P310-P260-P280
RIDADR  UN1759
HazardClass  IRRITANT
HS Code  2934999090
Limited Quantities 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE price More Price(53)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC TRC-B684075-500MG 2-Bromo-1-(3,4-dimethoxyphenyl)ethanone 1835-02-5 500mg $97 2026-06-03 Buy
TRC TRC-B684075-2G 2-Bromo-1-(3,4-dimethoxyphenyl)ethanone 1835-02-5 2g $288 2026-06-03 Buy
TRC TRC-B684075-1G 2-Bromo-1-(3,4-dimethoxyphenyl)ethanone 1835-02-5 1g $161 2026-06-03 Buy
Apolloscientific OR51867 3,4-Dimethoxyphenacyl bromide ≥95% 1835-02-5 1g $21 2026-06-04 Buy
Apolloscientific OR51867 3,4-Dimethoxyphenacyl bromide ≥95% 1835-02-5 5g $24 2026-06-04 Buy
Product number Packaging Price Buy
TRC-B684075-500MG 500mg $97 Buy
TRC-B684075-2G 2g $288 Buy
TRC-B684075-1G 1g $161 Buy
OR51867 1g $21 Buy
OR51867 5g $24 Buy

2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE Chemical Properties,Uses,Production

Chemical Properties

Off-White Solid

Preparation

Obtained by reaction of bromine with acetoveratrone in chloroform at r.t. (84%).

Synthesis

3,4-Dimethoxyacetophenone

1131-62-0

2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE

1835-02-5

General procedure for the synthesis of 2-bromo-1-(3,4-dimethoxyphenyl)ethanone from 3,4-dimethoxyacetophenone: Benzyltrimethylammonium tribromide (2.16 g, 5.55 mmol) was added to a stirred mixture of 1-(3,4-dimethoxyphenyl)ethanone (1.0 g, 5.55 mmol) in a mixed solution of dichloromethane (6 mL) and methanol (3 mL). The reaction mixture was stirred at room temperature for 16 hours before dilution with dichloromethane (80 mL) and water (40 mL) to separate the organic layer. The aqueous phase was extracted twice with dichloromethane (80 mL x 2). All organic phases were combined, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure to afford 2-bromo-1-(3,4-dimethoxyphenyl)ethanone (1.20 g, 4.63 mmol, 83% yield) as a brown solid. The product was characterized by 1H NMR (400 MHz, CDCl3): δ 7.63 (s, 1H), 7.57 (d, J=2.1Hz, 1H), 6.94 (d, J=8.4Hz, 1H), 4.43 (s, 2H), 3.98 (s, 6H).

References

[1] European Journal of Organic Chemistry, 2002, # 13, p. 2126 - 2135
[2] Bioorganic and Medicinal Chemistry Letters, 2007, vol. 17, # 15, p. 4223 - 4227
[3] Journal of Organic Chemistry, 2005, vol. 70, # 7, p. 2720 - 2728
[4] RSC Advances, 2014, vol. 4, # 107, p. 62308 - 62320
[5] Tetrahedron Asymmetry, 2009, vol. 20, # 10, p. 1138 - 1143

2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE Preparation Products And Raw materials

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career henan chemical co
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View Lastest Price from 2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE pictures 2025-04-04 2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE
1835-02-5
1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE pictures 2019-07-06 2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE
1835-02-5
$1.00 1KG 98% 200kg Career Henan Chemical Co
2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE pictures 2019-07-06 2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE
1835-02-5
$1.00 1KG 98% 200kg Career Henan Chemical Co

2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE Spectrum

Ethanone, 2-broMo-1-(3,4-diMethoxyphenyl)- 1-(3,4-diMethoxyphenyl)-2-broMoethanone 2-BroMo-3',4'-diMethoxyacetophenone 2-BroMoacetoveratrone 3',4'-DiMethoxy-2-broMoacetophenone 3,4-DiMethoxyphenacyl BroMide NSC 112833 2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE AKOS BBS-00003864 AKOS 90592 2-BROMO-1-(3,4-DIMETHOXYPHENYL)ETHANONE, TECH 2-Bromo-1-(3,4-di ethoxyphenyl) ethanone 2-Bromo-3’,4’-dimethoxyacetophenone 2-Bromo-1-(3,4-dimethoxyphenyl)ethan-1-one 1835-02-5 C10H11BrO3 Aromatics Miscellaneous Reagents