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4-Methoxyphenylmagnesium bromide

4-Methoxyphenylmagnesium bromide structure

CAS No.: 13139-86-1

Chemical Name:: 4-Methoxyphenylmagnesium bromide

Synonyms: p-Anisylbromomagnesium;4-ANISYLMAGNESIUM BROMIDE;P-ANISYLMAGNESIUM BROMIDE;4-Methoxyphenylbromomagnesium;(4-Methoxyphenyl)bromomagnesium;4-METHOXYPHENYLMAGNESIUM BROMIDE;4-anisylmagnesium bromide, 0.5m in thf;4-Methoxyphenylmagnesium bromide solution;4-METHOXY PHENYL MAGENSIUM BROMIDE IN THF;4-Methoxyphenylmagnesium bromide, 1M in THF

CBNumber:: CB8405643

Molecular Formula:: C7H7BrMgO

Molecular Weight:: 211.34

MDL Number:: MFCD00013515

MOL File:: 13139-86-1.mol

MSDS File:: SDS

Last updated:2026-01-13 11:27:06

Product description	Number	Pack Size	Price
4-Methoxyphenylmagnesium bromide solution 0.5 M in THF	470260	100ml	$115
4-Methoxyphenylmagnesium bromide solution 0.5 M in THF	470260	1l	$354
4-Methoxyphenylmagnesium bromide, 0.5M in THF	M350295	50g	$175
4-Methoxyphenylmagnesium bromide, 0.5M in THF	M350295	5g	$45
4-Methoxyphenylmagnesiumbromide	3261	50mL	$226
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4-Methoxyphenylmagnesium bromide Properties

Boiling point	65-67 °C
Density	0.955 g/mL at 25 °C
Flash point	−4 °F
storage temp.	Flammables + water-Freezer (-20°C)e area
form	Liquid
color	Yellow to brown
Water Solubility	Severe reaction
Sensitive	Air & Moisture Sensitive
Exposure limits	ACGIH: TWA 50 ppm; STEL 100 ppm (Skin) OSHA: TWA 200 ppm(590 mg/m3) NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
InChI	1S/C7H7O.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1
InChIKey	JKXAZEXIOPFJSC-UHFFFAOYSA-M
SMILES	COc1ccc([Mg]Br)cc1
UNSPSC Code	12352103
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS05,GHS07,GHS08

Signal word

Danger

Hazard statements

H225-H302-H314-H335-H351-H318-H333

Precautionary statements

P260h-P303+P361+P353-P405-P501a-P210-P260-P280-P305+P351+P338-P370+P378-P403+P235

target organs

Central nervous system, Respiratory system

Hazard Codes

F,C

Risk Statements

11-14-19-22-34-14/15-40-37

Safety Statements

16-26-33-36/37/39-45-6A-43B

RIDADR

UN 2924 3/PG 2

WGK Germany

HazardClass

4.3

PackingGroup

HS Code

29319090

Storage Class

3 - Flammable liquids

Hazard Classifications

Acute Tox. 4 Oral
Carc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3

NFPA 704

	3
3		2
	W

4-Methoxyphenylmagnesium bromide price More Price(13)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	470260	4-Methoxyphenylmagnesium bromide solution 0.5 M in THF	13139-86-1	100ml	$115	2026-03-19	Buy
Sigma-Aldrich	470260	4-Methoxyphenylmagnesium bromide solution 0.5 M in THF	13139-86-1	1l	$354	2026-03-19	Buy
TRC	M350295	4-Methoxyphenylmagnesium bromide, 0.5M in THF	13139-86-1	50g	$175	2021-12-16	Buy
TRC	M350295	4-Methoxyphenylmagnesium bromide, 0.5M in THF	13139-86-1	5g	$45	2021-12-16	Buy
Rieke Metals	3261	4-Methoxyphenylmagnesiumbromide	13139-86-1	50mL	$226	2021-12-16	Buy

Product number	Packaging	Price	Buy
470260	100ml	$115	Buy
470260	1l	$354	Buy
M350295	50g	$175	Buy
M350295	5g	$45	Buy
3261	50mL	$226	Buy

4-Methoxyphenylmagnesium bromide Chemical Properties,Uses,Production

Chemical Properties

Clear to brown solution when properly stored

Uses

4-Methoxyphenylmagnesium bromide is applied in Grignard-reactions as a reagent for the introduction of the 4-methoxyphenyl group.

reaction suitability

reaction type: Grignard Reaction

Synthesis

A mixture of Mg (13.49 g, 554.99 mmol) and I2 (50.00 mg, 197.00 mol) in THF (260 mL) was degassed and purged 3 times with N 2 , and then compound 1A (86.50 g, 462.49 mmol in THF (200 mL)) was added to the mixture. The mixture was stirred at 25 C for 1 h under N2 atmosphere. The color of the mixture changed. The crude product compound 4-methoxyphenylmagnesium bromide was used in the next step without further purification (97.74 g, crude).

4-Methoxyphenylmagnesium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

(4-METHOXYPHENYL)DIPHENYLSULFONIUM TRIFLATE 4-METHOXYPHENETHYL BROMIDE 4,4'-DIMETHOXYBENZHYDROL 4-Methoxybiphenyl 4'-METHOXY-2,2,2-TRIFLUOROACETOPHENONE

4-METHOXYAZOBENZENE Bis(4-methoxyphenyl)phosphine oxide 4-Methoxytriphenylmethyl chloride

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4-Methoxyphenylmagnesium bromide Suppliers

Global( 167)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29830	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5600	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58
Dayang Chem (Hangzhou) Co.,Ltd.	+86-0571-88938639 +8617705817739	info@dycnchem.com	China	52705	58
Bio Connect Life Sciences		info@bio-connect.nl	United States	261	58
changzhou huayang technology co., ltd	+8615250961469	2571773637@qq.com	China	9653	58
sgtlifesciences pvt ltd	+8617013299288	dj@sgtlifesciences.com	China	12373	58
Alfa Chemistry	+1-5166625404;	Info@alfa-chemistry.com	United States	20405	58
GLR Innovations	+91 9891111994	info@glrgroup.in	India	4535	58

Supplier	Advantage
career henan chemical co	58
CONIER CHEM AND PHARMA LIMITED	58
Richest Group Ltd	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
Bio Connect Life Sciences	58
changzhou huayang technology co., ltd	58
sgtlifesciences pvt ltd	58
Alfa Chemistry	58
GLR Innovations	58

View Lastest Price from 4-Methoxyphenylmagnesium bromide manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2021-07-02	4-Methoxyphenylmagnesium bromide 13139-86-1	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
	2019-07-06	4-Methoxyphenylmagnesium bromide 13139-86-1	US $1.00 / kg	1kg	98%	100KG	Career Henan Chemical Co

4-Methoxyphenylmagnesium bromide
13139-86-1
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

4-Methoxyphenylmagnesium bromide
13139-86-1
US $1.00 / kg
98%
Career Henan Chemical Co

13139-86-1(4-Methoxyphenylmagnesium bromide)Related Search:

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4-PHENOXYPHENYLMAGNESIUM BROMIDE 3,4-DIMETHOXYPHENYLMAGNESIUM BROMIDE 3-FLUORO-4-METHOXYPHENYLMAGNESIUM BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN,3-FLUORO-4-METHOXYPHENYLMAGNESIUM BROMIDE

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