2-Fluorotoluene
- CAS No.
- 95-52-3
- Chemical Name:
- 2-Fluorotoluene
- Synonyms
- O-FLUOROTOLUENE;1-Fluoro-2-methylbenzene;FC6H4CH3;o-Fluortoluol;2-Fluortoluol;o-fluoro-toluen;2-FLUOROTOLUENE;2-fulorotoluene;o-Flouorotoluene;2-FLUOROTOLOUENE
- CBNumber:
- CB8664172
- Molecular Formula:
- C7H7F
- Molecular Weight:
- 110.13
- MDL Number:
- MFCD00000322
- MOL File:
- 95-52-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2-Fluorotoluene ≥99% | F15323 | 100g | $60.1 |
| 2-Fluorotoluene ≥99% | F15323 | 500g | $146 |
| 2-Fluorotoluene >99.0%(GC) | F0039 | 25mL | $16 |
| 2-Fluorotoluene >99.0%(GC) | F0039 | 500mL | $86 |
| o-Fluorotoluene, 99% | 09-4310 | 50g | $31 |
| More product size | |||
| Melting point | -62 °C (lit.) |
|---|---|
| Boiling point | 113-114 °C (lit.) |
| Density | 1.001 g/mL at 25 °C (lit.) |
| vapor density | 3.8 (vs air) |
| vapor pressure | 21 mm Hg ( 20 °C) |
| refractive index |
n |
| Flash point | 55 °F |
| storage temp. | Store below +30°C. |
| form | Liquid |
| color | Clear colorless to slightly yellow |
| Specific Gravity | 1.001 |
| explosive limit | 1.3%(V) |
| Water Solubility | immiscible |
| Merck | 14,4180 |
| BRN | 1853362 |
| Dielectric constant | 4.2199999999999998 |
| InChI | 1S/C7H7F/c1-6-4-2-3-5-7(6)8/h2-5H,1H3 |
| InChIKey | MMZYCBHLNZVROM-UHFFFAOYSA-N |
| SMILES | Cc1ccccc1F |
| LogP | 2.73-2.74 |
| CAS DataBase Reference | 95-52-3(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | L55XKB3K7H |
| NIST Chemistry Reference | Benzene, 1-fluoro-2-methyl-(95-52-3) |
| EPA Substance Registry System | o-Fluorotoluene (95-52-3) |
| UNSPSC Code | 12352101 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H335 | |||||||||
| Precautionary statements | P210-P233-P240-P241-P242-P243 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | F,Xi | |||||||||
| Risk Statements | 11-36/37/38 | |||||||||
| Safety Statements | 16-26-33-36-37/39 | |||||||||
| RIDADR | UN 2388 3/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | XT2579000 | |||||||||
| Hazard Note | Flammable/Irritant | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29036990 | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Flam. Liq. 2 STOT SE 3 |
|||||||||
| Toxicity | LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg | |||||||||
| Limited Quantities | 1.0 L (0.3 gallon) (liquid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
2-Fluorotoluene price More Price(23)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | F15323 | 2-Fluorotoluene ≥99% | 95-52-3 | 100g | $60.1 | 2025-07-31 | Buy |
| Sigma-Aldrich | F15323 | 2-Fluorotoluene ≥99% | 95-52-3 | 500g | $146 | 2025-07-31 | Buy |
| TCI Chemical | F0039 | 2-Fluorotoluene >99.0%(GC) | 95-52-3 | 25mL | $16 | 2025-07-31 | Buy |
| TCI Chemical | F0039 | 2-Fluorotoluene >99.0%(GC) | 95-52-3 | 500mL | $86 | 2025-07-31 | Buy |
| Strem Chemicals | 09-4310 | o-Fluorotoluene, 99% | 95-52-3 | 50g | $31 | 2024-03-01 | Buy |
2-Fluorotoluene Chemical Properties,Uses,Production
Chemical Properties
clear colorless to slightly yellow liquid
Uses
It is employed in organic synthesis.
General Description
A colorless liquid with an aromatic odor. May sink or float on water.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
2-Fluorotoluene is of generally low reactivity. Reacts with strong oxidizing agents and strong reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides [USCG, 1999].
Health Hazard
Inhalation of vapor may cause respiratory irritation. Prolonged and repeated vapor exposures may produce systemic toxic effects.
Synthesis
The halogen exchange method reacts aromatic compounds with alkali metal fluorides (e.g., CsF and KF, etc.) and substituent groups, allowing the fluorine atom to replace other halogen groups (e.g., chlorine). The reaction method of halogen exchange between inorganic halides and between organic halides is known as the Finkelstein method. It is one of the most widely used methods for synthesizing fluoroaromatic compounds in industrial production, and has been one of the more active areas in the synthesis of fluoroaromatic compounds in recent years. Halogen exchange method is the main method with industrialized application value, characterized by low price of raw materials, easy to obtain and good selectivity, and in the reaction process can not use fluoroboric acid, hydrogen fluoride and other highly toxic reagents, in general, relatively environmentally friendly and safe, in line with the trend of the development of pharmaceutical pesticides nowadays. The disadvantage is that its reaction conditions are relatively harsh, requiring reaction at higher temperatures and under the condition of excess potassium fluoride, and also requiring the use of non-protonic inert reagents as solvents, and need to be carried out under the condition of anhydrous.
Purification Methods
Dry o-fluorotoluene with P2O5 or CaSO4 and fractionally distil it through a silvered vacuum-jacketed glass column with 1/8th-in glass helices. A high reflux ratio is necessary because of the closeness of the boiling points of the o-, m-and p-isomers [Potter & Saylor J Am Chem Soc 37 90 1951]. [Beilstein 5 H 290, 5 III 676, 5 IV 799.]
2-Fluorotoluene Preparation Products And Raw materials
Raw materials
Preparation Products
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| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Jiangsu Nengyue New Material Technology Co.,Ltd | +undefined+86-13376001577 | robinlu.jian@foxmail.com | China | 64 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615350571055 | Sibel@chuanghaibio.com | China | 8753 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29735 | 60 |
| Dalian Richfortune Chemicals Co., Ltd | +86-86-411-84820922 +86-8613904096939 | sales@richfortunechem.com | China | 305 | 57 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21597 | 55 |
| Fluoropharm Co., Ltd. | +86-0571-85586753 +86-13336034509 | sales@fluoropharm.com | China | 1445 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29831 | 58 |
| Shanghai Worldyang Chemical Co.,Ltd. | +86-021-56795779 +8613651600618 | sales@worldyachem.com | China | 967 | 58 |
| Xiamen AmoyChem Co., Ltd | +86-86-5926051114 +8615060885618 | sales@amoychem.com | China | 6369 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
View Lastest Price from 2-Fluorotoluene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-02-02 | 2-Fluorotoluene
95-52-3
|
US $0.00-0.00 / KG | 50mg | 99%HPLC | 2000tons | Shaanxi Dideu Medichem Co. Ltd | |
 |
2026-01-30 | 2-Fluorotoluene
95-52-3
|
US $10.00 / KG | 1KG | 99% | 100 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2025-06-20 | O-fluorotoluene;C7H7F
95-52-3
|
US $30.00 / Kg/Drum | 1T | 99.5% | 1000tons/month | Hebei Yanxi Chemical Co., Ltd.
|
-
- 2-Fluorotoluene
95-52-3
- US $0.00-0.00 / KG
- 99%HPLC
- Shaanxi Dideu Medichem Co. Ltd
-
- 2-Fluorotoluene
95-52-3
- US $10.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- O-fluorotoluene;C7H7F
95-52-3
- US $30.00 / Kg/Drum
- 99.5%
- Hebei Yanxi Chemical Co., Ltd.
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