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1,4-Dibromobenzene

CAS No.
106-37-6
Chemical Name:
1,4-Dibromobenzene
Synonyms
dibromobenzene;P-DIBROMOBENZENE;NSC 33942;1.4-DibroMoben;dibromobenzene.;p-dibromo-benzen;1,4-Dibrombenzol;4-DibroMobenzene;Of DibroMobenzene;1,4-DIBROMOBENZENE
CBNumber:
CB8676250
Molecular Formula:
C6H4Br2
Molecular Weight:
235.9
MDL Number:
MFCD00000089
MOL File:
106-37-6.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-24 14:58:31
Product description Number Pack Size Price
1,4-Dibromobenzene 98% D39029 100g $36.5
1,4-Dibromobenzene 98% D39029 2kg $467
1,4-Dibromobenzene >99.0%(GC) D0170 25g $23
1,4-Dibromobenzene >99.0%(GC) D0170 100g $27
1,4-Dibromobenzene 98% D39029 500g $130
More product size

1,4-Dibromobenzene Properties

Melting point 83-87 °C (lit.)
Boiling point 219 °C (lit.)
Density 1.841 g/mL at 25 °C (lit.)
vapor pressure 0.134 at 35 °C (Hine et al., 1963)
refractive index 1.5742
Flash point 219-220°C
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in alcohol, benzene, chloroform, toluene and carbon tetrachloride. Insoluble in ether.
form Crystals
color Colorless to almost white
Water Solubility practically insoluble
λmax 282nm(EtOH)(lit.)
Merck 14,3019
BRN 1904543
Henry's Law Constant 5.0 x 10-4 atmm3/mol at 25 °C (Hine and Mookerjee, 1975)
Dielectric constant 8.8(20℃)
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
InChI 1S/C6H4Br2/c7-5-1-2-6(8)4-3-5/h1-4H
InChIKey SWJPEBQEEAHIGZ-UHFFFAOYSA-N
SMILES Brc1ccc(Br)cc1
CAS DataBase Reference 106-37-6(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 9991W3M5HZ
NIST Chemistry Reference Benzene, 1,4-dibromo-(106-37-6)
EPA Substance Registry System p-Dibromobenzene (106-37-6)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09
Signal word  Warning
Hazard statements  H315-H319-H335-H411
Precautionary statements  P273-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  24/25-36-26
RIDADR  UN 2711
WGK Germany  2
RTECS  CZ1791000
TSCA  TSCA listed
HazardClass  9
PackingGroup  III
HS Code  29036990
Storage Class 11 - Combustible Solids
Hazard Classifications Aquatic Chronic 2
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazardous Substances Data 106-37-6(Hazardous Substances Data)
Toxicity Acute oral LD50 for mice 120 mg/kg (quoted, RTECS, 1985).
NFPA 704
0
2 0

1,4-Dibromobenzene price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich D39029 1,4-Dibromobenzene 98% 106-37-6 100g $36.5 2026-03-19 Buy
Sigma-Aldrich D39029 1,4-Dibromobenzene 98% 106-37-6 2kg $467 2026-03-19 Buy
TCI Chemical D0170 1,4-Dibromobenzene >99.0%(GC) 106-37-6 25g $23 2026-03-19 Buy
TCI Chemical D0170 1,4-Dibromobenzene >99.0%(GC) 106-37-6 100g $27 2026-03-19 Buy
Sigma-Aldrich D39029 1,4-Dibromobenzene 98% 106-37-6 500g $130 2026-03-19 Buy
Product number Packaging Price Buy
D39029 100g $36.5 Buy
D39029 2kg $467 Buy
D0170 25g $23 Buy
D0170 100g $27 Buy
D39029 500g $130 Buy

1,4-Dibromobenzene Chemical Properties,Uses,Production

Chemical Properties

1,4-dibromobenzene is a dibromobenzene. It is a white or off-white powder. freely soluble in hot ethanol, acetone, ether and hot benzene, soluble in ethanol and benzene, insoluble in water. It has a strong smell similar to that of the lighter chlorine analogue. It can be used as a precursor to the dye 6,6-Dibromoindigo.

Chemical Properties

Dibromobenzene is a heavy colorless liquid. Pleasant aromatic odor.

Uses

Solvent for oils; ore flotation; motor fuels; organic synthesis.

Uses

1,4-Dibromobenzene is used in the synthesis of 2,5-dibromoacetophenone, triarylamines and trans- stilbenes. It is widely used as a heavy liquid solvent as well as a motor oil additive. It finds application as an intermediate in the manufacture of organic chemicals such as dyes, pharmaceuticals and flame retardants for polymeric materials.

Definition

ChEBI: 1,4-dibromobenzene is a dibromobenzene.

Potential Exposure

Dibromobenzene is used as a solvent for oils and in organic synthesis.

Shipping

UN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required. UN2514 Bromobenzene, Hazard Class: 3; Labels: 3-Flammable liquid.

Purification Methods

Steam distil the dibromobenzene , then crystallise it from EtOH or MeOH and dry it in the dark under vacuum. Purify it by zone melting. [Beilstein 5 IV 683.]

Incompatibilities

Extremely flammable. May form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides.

Waste Disposal

Use a licensed professional waste disposal service to dispose of this material. All federal, state, and local environmental regulations must be observed. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with flue gas scrubbing.

374564-35-9
106-37-6
Synthesis of 1,4-Dibromobenzene from POTASSIUM 4-BROMOPHENYLTRIFLUOROBORATE
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View Lastest Price from 1,4-Dibromobenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,4-Dibromobenzene pictures 2026-04-29 1,4-Dibromobenzene
106-37-6
US $160.00 / KG 1KG 98% 20 tons Speranza Chemical Co., Ltd.
1,4-Dibromobenzene pictures 2026-04-29 1,4-Dibromobenzene
106-37-6
US $0.00 / KG 1KG ≥99% 50 Tons/Month Yancheng Longshen Chemical Co.,Ltd.
1,4-Dibromobenzene pictures 2026-04-29 1,4-Dibromobenzene
106-37-6
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
1,4-DIBROMOBENZENE dibromobenzene. p-Bromophenyl bromide p-bromophenylbromide p-dibromo-benzen p-Phenylenedibromide 1,4-Dibromobenzene Zone Refined (number of passes:31) 1,4-DIBROMOBENZENE pure P-DIBROMOBENZENE(1,4-DIBROMOBENZENE) 1,4- Dibromo Benzene CAS No 106-37-6 1,4-DIBROMOBENZENE, 98%1,4-DIBROMOBENZENE, 98%1,4-DIBROMOBENZENE, 98%1,4-DIBROMOBENZENE, 98% PARA-DIBROMOBENZENE P-BENZENE DIBROMIDE P-DIBROMOBENZENE 1,4-Dibromobenzene ,98% 1,4-Phenylene dibromide 1,4-Dibromobenzene,99% 1,4-Dibrombenzol 1,4-dibromo-benzen Benzene, p-dibromo- Benzene,1,4-dibromo- Benzene,p-dibromo- dibromo-1,4benzene 1,4-DibroMobenzene, 99% 250GR 1,4-DibroMobenzene, 99% 5GR 1,4-Dibromobenzene Zone Refined Of DibroMobenzene 4-DibroMobenzene 1,4-DIBROMOBENZENE FOR SYNTHESIS DIBROMOBENZENE, 1,4-(SG) Ontwo broMobenzene The second broMobenzene 1.4-DibroMoben 1, 4-Dibromobenzene Solution, 1000ppm 1,4-Dibromobenzene> 1,4-Dibromobenzene Zone Refined (number of passes:31)> 1,4-DibromobenzeneSolution,2000mg/L,5ml 1, 4-2 bromobenzene 1,4-Dibromobenzene ISO 9001:2015 REACH DIBROMOBENZENE, 1,4- NSC 33942 1,4-Dibromobenzene in isooctane Glycerol Impurity 57 dibromobenzene 106-37-6 610-37-6 06-37-6 106376 Aryl Building Blocks Organic Building Blocks Halogenated Hydrocarbons C6 Bioactive Small Molecules Building Blocks Cell Biology Chemical Synthesis D-DIF