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Lithium trifluoromethanesulfonate

CAS No.
33454-82-9
Chemical Name:
Lithium trifluoromethanesulfonate
Synonyms
LITHIUM TRIFLUOROMETHANESULFONATE;LiTf;ithium trifL;LiTFS;LiOTf;PFM-LI;LiCF3SO;LITHIUM TRIFLATE;Lithium trifluorome;Lithium Trifluoro Methylsulphate
CBNumber:
CB8719494
Molecular Formula:
CF3LiO3S
Molecular Weight:
156.01
MDL Number:
MFCD00013227
MOL File:
33454-82-9.mol
MSDS File:
SDS
Last updated:2026-01-13 11:26:39
Product description Number Pack Size Price
Lithium trifluoromethanesulfonate 96% 282669 25g $122.46
Lithium trifluoromethanesulfonate 96% 282669 100g $334.6
Lithium Trifluoromethanesulfonate >98.0%(T) T1548 25g $70
Lithium trifluoromethanesulfonate, 99% (Lithium triflate) 03-2000 10g $48
Lithium trifluoromethanesulfonate, 99% (Lithium triflate) 03-2000 50g $169
More product size

Lithium trifluoromethanesulfonate Properties

Melting point >300 °C (lit.)
Density 1,9 g/cm3
storage temp. Inert atmosphere,Room Temperature
solubility Water
form Powder
color White or colorless
Water Solubility soluble
Sensitive Moisture Sensitive
BRN 4301818
Stability hygroscopic
InChI InChI=1S/CHF3O3S.Li/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
InChIKey MCVFFRWZNYZUIJ-UHFFFAOYSA-M
SMILES C(F)(F)(F)S([O-])(=O)=O.[Li+]
LogP 0.3 at 25℃ and pH1
CAS DataBase Reference 33454-82-9(CAS DataBase Reference)
FDA UNII 1C966KV50I
EPA Substance Registry System Methanesulfonic acid, trifluoro-, lithium salt (33454-82-9)
UNSPSC Code 12352302
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
3-10
Hazard Note  Irritant
TSCA  TSCA listed
HS Code  29049020
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
0
2 1

Lithium trifluoromethanesulfonate price More Price(48)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 282669 Lithium trifluoromethanesulfonate 96% 33454-82-9 25g $122.46 2025-07-31 Buy
Sigma-Aldrich 282669 Lithium trifluoromethanesulfonate 96% 33454-82-9 100g $334.6 2025-07-31 Buy
TCI Chemical T1548 Lithium Trifluoromethanesulfonate >98.0%(T) 33454-82-9 25g $70 2025-07-31 Buy
Strem Chemicals 03-2000 Lithium trifluoromethanesulfonate, 99% (Lithium triflate) 33454-82-9 10g $48 2024-03-01 Buy
Strem Chemicals 03-2000 Lithium trifluoromethanesulfonate, 99% (Lithium triflate) 33454-82-9 50g $169 2024-03-01 Buy
Product number Packaging Price Buy
282669 25g $122.46 Buy
282669 100g $334.6 Buy
T1548 25g $70 Buy
03-2000 10g $48 Buy
03-2000 50g $169 Buy

Lithium trifluoromethanesulfonate Chemical Properties,Uses,Production

Chemical Properties

white powder

Properties and Applications

Lithium trifluoromethanesulfonate is highly soluble in water and organic solvents and shows excellent ion conductivity. It is highly soluble in polar organic solvents such as dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl acetate, and others. This compound exhibits good thermal stability and has a non-coordinating anion (triflate), which helps prevent unwanted reactions with other components in electrochemical systems.

Uses

Lithium trifluoromethanesulfonate is mixed with ceramic filler to prepare polyethylene oxide films in order to improve the electrochemical and mechanical characteristics of the membrane, which is used in the lithium batteries. It acts as a doping salt used in the preparation of nano manganese-composite polymer electrolytes.

General Description

This product has been enhanced for energy efficiency.

Synthesis

A 316L stainless steel autoclave was charged with 1678 g of a 10.0% aqueous solution of lithium hydroxide and 424 g of calcium oxide, and the temperature was raised to 85 ° C, and the mixture was stirred for 3 hours. The reaction pressure was controlled by continuously feeding the trifluoromethane sulfonyl fluoride gas. The reaction time is 3.5 hours, then the reaction is kept for 3 hours, and then the temperature is lowered to 25 ℃. The reaction liquid is filtered to obtain the product lithium trifluoromethanesulfonate aqueous solution. Lithium trifluoromethanesulfonate

References

[1] Patent: CN105693561, 2016, A. Location in patent: Paragraph 0030

335-05-7
33454-82-9
Synthesis of Lithium trifluoromethanesulfonate from TRIFLUOROMETHANESULFONYL FLUORIDE
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View Lastest Price from Lithium trifluoromethanesulfonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Lithium triflate pictures 2026-02-25 Lithium triflate
33454-82-9
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
lithium triflate pictures 2025-10-13 lithium triflate
33454-82-9
US $88.00-10.00 / kg 1kg 99% 1000kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Lithium trifluoromethanesulfonate pictures 2025-09-25 Lithium trifluoromethanesulfonate
33454-82-9
US $8.00-6.00 / kg 1kg 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
  • lithium triflate pictures
  • lithium triflate
    33454-82-9
  • US $88.00-10.00 / kg
  • 99%
  • ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
ithium trifL Lithiumtrifluoromethanesulphonate97% LITHIUM TRIFLUOROMETHANESULFONATE, 99.99 5% Lithium Trifluoro Methylsulphate Lithium triflate~Trifluoromethanesulphonic acid lithium salt Lithiumtrifluoromethanesulfonate,99%(Lithiumtriflate) Lithium trifluoromethanesulphonate 97% Methanesulfonic acid,1,1,1-trifluoro-, lithiuM salt (1:1) LithiuM trifluoroMethanesulfonate 99.995% trace Metals basis LithiuM trifluoroMethanesulfonate, 99.995% METALS BASIS LiTf PFM-LI TRIFLUOROMETHANESULFONIC ACID LITHIUM SALT LITHIUM TRIFLATE LITHIUM TRIFLUOROMETHANESULPHONATE LITHIUM TRIFLUOROMETHYL SULFONATE LITHIUM TRIFLUOROMETHANESULFONATE Methanesulfonicacid,trifluoro-,lithiumsalt trifluoro-methanesulfonicacilithiumsalt Lithium triflate, Trifluoromethanesulfonic acid lithium salt Lithium trifluoromethanesulfonate ,97% Lithium trifluoromethanesulfonate,Lithium triflate, Trifluoromethanesulfonic acid lithium salt TrifluoroMethyl sulfonic acid lithiuM LithiuM trifluoroMethanesulfonat LITHIUM TRIFLUOROMETHANESULFONATE (LITHIUM TRIFLATE) LITHIUM TRIFLUOROMETHENESULFONATE Lithium trifluoromethanesulfonate, 99.5% Lithiumtrifluoromethanesulfonate (LiTFS) Lithium trifluorome Lithium trifluoromethanesulfonate, 98+% Lithium trifluoromethanesulfonate, 30% aqueous solution LITHIUM TRIFLUOROMETHANESULFONATELITHIUM TRIFLUOROMETHANESULFONATELITHIUM TRIFLUOROMETHANESULFONATELITHIUM TRIFLUOROMETHANESULFONATE Lithium Trifluoromethanesulfonate (LiTf) lithium(1+) trifluoromethanesulfonate High purity CAS 33454-82-9 Lithium triflate in stock LiTFS Trifluoromethanesulfonate (lithium) LiCF3SO Lithium trifluoro methane sulfonate 95% / Lithium triflate LiOTf 33454-82-9 33455-82-9 333454-82-9 CF3LiO3S CF3SO3Li CF3O3SLi CLiF3SO3 LiCF3SO3 LiSO3CF3 Li (Lithium) Compounds Metal Triflates Homogeneous Catalysts Catalysts for Organic Synthesis Typical Metal Compounds Classes of Metal Compounds Lithium Inorganic Salts Synthetic Reagents