Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>2-BROMO-5-NITROANISOLE

2-BROMO-5-NITROANISOLE

2-BROMO-5-NITROANISOLE Structure
2-BROMO-5-NITROANISOLE structure
CAS No.
77337-82-7
Chemical Name:
2-BROMO-5-NITROANISOLE
Synonyms
2-Bromo-5-nitroanisoL;2-BROMO-5-NITROANISOLE;2-Bromo-5-nitroanisole >2-Bromo-5-nitroanisole,98%;2-bromo-5-nitrobenzyl ether;2-BroMo-5-nitroanisole, 97+%;4-BROMO-3-METHOXYNITROBENZENE;2-Methoxy-4-nitrobromobenzene;2-BroMo-5-nitroanisole, 98% 10GR;1-BROMO-2-METHOXY-4-NITROBENZENE
CBNumber:
CB8719656
Molecular Formula:
C7H6BrNO3
Molecular Weight:
232.03
MDL Number:
MFCD00041250
MOL File:
77337-82-7.mol
MSDS File:
SDS
Last updated:2025-08-08 17:45:00
Product description Number Pack Size Price
2-Bromo-5-nitroanisole >98.0%(GC) B3418 5g $77
2-Bromo-5-nitroanisole >98.0%(GC) B3418 25g $306
2-Bromo-5-nitroanisole B688118 5g $75
2-Bromo-5-nitroanisole CS-W014685 100g $89
2-BROMO-5-NITROANISOLE 95.00% HCH0018783 1G $127.05
More product size
Request For Quotation

2-BROMO-5-NITROANISOLE Properties

Melting point 99-103 °C
Boiling point 302.1±22.0 °C(Predicted)
Density 1.640±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
Water Solubility Insoluble in water
form Crystalline Powder
color Light brown
λmax 324nm(EtOH)(lit.)
BRN 2520496
CAS DataBase Reference 77337-82-7(CAS DataBase Reference)
FDA UNII 55S5YMP2XF

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H335-H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-22
Safety Statements  24/25-26
Hazard Note  Irritant
HS Code  29093090
NFPA 704
1
0 0

2-BROMO-5-NITROANISOLE price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B3418 2-Bromo-5-nitroanisole >98.0%(GC) 77337-82-7 5g $77 2025-07-31 Buy
TCI Chemical B3418 2-Bromo-5-nitroanisole >98.0%(GC) 77337-82-7 25g $306 2025-07-31 Buy
TRC B688118 2-Bromo-5-nitroanisole 77337-82-7 5g $75 2021-12-16 Buy
ChemScene CS-W014685 2-Bromo-5-nitroanisole 77337-82-7 100g $89 2021-12-16 Buy
American Custom Chemicals Corporation HCH0018783 2-BROMO-5-NITROANISOLE 95.00% 77337-82-7 1G $127.05 2021-12-16 Buy
Product number Packaging Price Buy
B3418 5g $77 Buy
B3418 25g $306 Buy
B688118 5g $75 Buy
CS-W014685 100g $89 Buy
HCH0018783 1G $127.05 Buy

2-BROMO-5-NITROANISOLE Chemical Properties,Uses,Production

Chemical Properties

light brown crystalline powder

Synthesis

2-Methoxy-4-nitroaniline

97-52-9

2-BROMO-5-NITROANISOLE

77337-82-7

General procedure for the synthesis of 2-bromo-5-nitroanisole from 2-methoxy-4-nitroaniline: a catalytic amount of copper bromide (1 mol%) was added to a solution of 2-methoxy-4-nitroaniline (2.5 mmol) in acetonitrile (30 ml), followed by camphorsulfonic acid (3.0 mmol), sodium nitrite or tert-butyl nitrite (3.0 mmol), and tetrabutylammonium bromide (5.0 mmol). The reaction mixture was stirred at 60°C for 24 h (Tables 1 and 2). Nitrogen release was observed immediately during the reaction. After completion of the reaction (confirmed by β-naphthol test and thin layer chromatography), the solvent was removed using a rotary evaporator. The residue was washed with water and extracted with dichloromethane. The organic phases were combined, dried with anhydrous magnesium sulfate and concentrated under reduced pressure. Finally, purification by column chromatography using a hexane/dichloromethane solvent mixture as eluent gave the pure product 2-bromo-5-nitroanisole. The physical properties and 1H NMR data of the product were consistent with the commercially available analytically pure sample.

References

[1] Tetrahedron, 2013, vol. 69, # 16, p. 3511 - 3517
[2] Tetrahedron, 2010, vol. 66, # 37, p. 7418 - 7422
[3] Tetrahedron Letters, 2010, vol. 51, # 51, p. 6769 - 6771
[4] Chemical and Pharmaceutical Bulletin, 2014, vol. 62, # 10, p. 979 - 988
[5] Journal of the American Chemical Society, 1935, vol. 57, p. 1592,1594

2-BROMO-5-NITROANISOLE Preparation Products And Raw materials

Raw materials

2-Methoxy-4-nitroaniline 2-Bromo-4-nitrophenol Dimethyl sulfate (1S)-(+)-Camphor-10-sulphonic acid Cuprous bromide
tert-Butyl nitrite TETRABUTYLAMMOMIUM BROMIDE

1of2

Preparation Products

2,5-DIBROMOANISOLE

2-BROMO-5-NITROANISOLE Suppliers

Global( 215)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20130 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718; +8613336195806 sales@capot.com China 29735 60
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
Nanjing Dolon Biotechnology Co.,Ltd. 		18905173768 52513593@qq.com CHINA 2972 58
Alchem Pharmtech,Inc. 		8485655694 sales@alchempharmtech.com United States 63687 58
Wuhan Chemwish Technology Co., Ltd 		027-67849912 sales@chemwish.com CHINA 10821 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49977 58
career henan chemical co 		+86-0371-86658258 +8613203830695 factory@coreychem.com China 29796 58
Richest Group Ltd 		18017061086 oled@richest-group.com CHINA 5600 58
Fuxin Pharmaceutical 		+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 9999 58
Supplier Advantage
Henan Fengda Chemical Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
ATK CHEMICAL COMPANY LIMITED 		60
Nanjing Dolon Biotechnology Co.,Ltd. 		58
Alchem Pharmtech,Inc. 		58
Wuhan Chemwish Technology Co., Ltd 		58
CONIER CHEM AND PHARMA LIMITED 		58
career henan chemical co 		58
Richest Group Ltd 		58
Fuxin Pharmaceutical 		58

View Lastest Price from 2-BROMO-5-NITROANISOLE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-BROMO-5-NITROANISOLE pictures 2025-09-25 2-BROMO-5-NITROANISOLE
77337-82-7
 US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
2-BROMO-5-NITROANISOLE pictures 2022-01-15 2-BROMO-5-NITROANISOLE
77337-82-7
 US $0.00 / KG 1KG 97.8% 100 tons Honest Joy Holdings Limited
2-Bromo-5-nitroanisole pictures 2020-02-26 2-Bromo-5-nitroanisole
77337-82-7
 US $0.00-0.00 / Kg 1KG 99.0% 100 tons Shaanxi Dideu Medichem Co. Ltd

2-BROMO-5-NITROANISOLE Spectrum

2-BROMO-5-NITROANISOLE(77337-82-7)1HNMR

77337-82-7(2-BROMO-5-NITROANISOLE)Related Search:

2-bromo-5-nitrobenzaldehyde 1-CYANO-2-BROMO-5-NITROBENZENE 4-BROMO-3-NITROANISOLE 2-BROMO-5-NITROETHOXYBENZENE 1-Bromo-4-nitrobenzene
2-Bromoanisole 4-BROMO-3-METHOXYANILINE 2-BROMO-5-NITROANISOLE 3-BROMO-5-NITROANISOLE 2-BROMO-4-NITROANISOLE 95%,2-BROMO-4-NITROANISOLE
2-Bromo-3-nitroanisole 99%,2-BROMO-3-NITROANISOLE 4-BROMO-2-NITROANISOLE 3-BROMO-4-NITROANISOLE 3-Bromo-2-nitroanisole 5-amino-2-bromophenol
1-bromo-2,5-dimethoxy-4-nitrobenzene 2-Bromo-4-nitrophenol 3-BROMO-4-NITROANISOLE 95%

1of4

4-BROMO-3-METHOXYNITROBENZENE 1-BROMO-2-METHOXY-4-NITROBENZENE 2-BroMo-5-nitroanisole, 98% 10GR 2-BroMo-5-nitroanisole, 97+% 2-BROMO-5-NITROANISOLE 2-Bromo-5-nitroanisole,98% 2-Methoxy-4-nitrobroMobenzene[2-BroMo-5-nitroanisole] 2-Bromo-5-nitroanisoL 2-Bromo-5-nitroanisole > Benzene, 1-bromo-2-methoxy-4-nitro- 2-BROMO-5-NITROANISOLE ISO 9001：2015 REACH 2-Bromo-5-nitroanisole[2-Methoxy-4-nitrobromobenzene 2-bromo-5-nitrobenzyl ether 2-Methoxy-4-nitrobromobenzene 77337-82-7 Alcohols Building Blocks C7 to C8 Chemical Synthesis New Products for Chemical Synthesis Nitrogen Compounds Organic Building Blocks Oxygen Compounds Aromatic Halides (substituted) Phenyls & Phenyl-Het Anisole Miscellaneous Anisoles, Alkyloxy Compounds & Phenylacetates Bromine Compounds Nitro Compounds Phenyls & Phenyl-Het