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N,N-Diethylaniline

CAS No.
91-66-7
Chemical Name:
N,N-Diethylaniline
Synonyms
DEA;DIETHYLANILINE;Diaethylanilin;N,N-Diethylanilin;Phenyldiethylamine;N-PHENYLDIETHYLAMINE;N,N-diethylbenzenamine;N, ≥99%(GC);N.N-Diethylani;diaethylaniline
CBNumber:
CB8854632
Molecular Formula:
C10H15N
Molecular Weight:
149.23
MDL Number:
MFCD00009042
MOL File:
91-66-7.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-10 10:27:31
Product description Number Pack Size Price
N,N-Diethylaniline ≥99% 185868 50ml $18.8
N,N-Diethylaniline ≥99% 185868 1l $81
N,N-Diethylaniline >99.0%(GC)(T) D0475 25mL $20
N,N-Diethylaniline >99.0%(GC)(T) D0475 500mL $46
N,N-Diethylaniline ≥99% 185868 250ml $57.3
More product size

N,N-Diethylaniline Properties

Melting point -38 °C
Boiling point 217 °C(lit.)
Density 0.938 g/mL at 25 °C(lit.)
vapor density 5.2 (vs air)
vapor pressure 1 mm Hg ( 49.7 °C)
refractive index n20/D 1.542(lit.)
Flash point 208 °F
storage temp. Store below +30°C.
solubility water: soluble1g in 70ml at 12°C
pka 6.61(at 22℃)
form Liquid
color Clear yellow
PH 8 (0.1g/l, H2O, 20℃)
explosive limit 1.1-5.3%(V)
Water Solubility 14 g/L (12 ºC)
Merck 14,3114
BRN 742483
Henry's Law Constant 6.7×10-2 mol/(m3Pa) at 25℃, Brockbank (2013)
Dielectric constant 5.5(19℃)
Stability Stable. Combustible. Incompatible with strong oxidizing agents, strong acids.
InChI 1S/C10H15N/c1-3-11(4-2)10-8-6-5-7-9-10/h5-9H,3-4H2,1-2H3
InChIKey GGSUCNLOZRCGPQ-UHFFFAOYSA-N
SMILES CCN(CC)c1ccccc1
LogP 3.904 at 25℃
Indirect Additives used in Food Contact Substances N,N-DIETHYLANILINE
CAS DataBase Reference 91-66-7(CAS DataBase Reference)
FDA 21 CFR 177.2420
EWG's Food Scores 2
FDA UNII 1WR1HJ2PGW
NIST Chemistry Reference Benzenamine, N,N-diethyl-(91-66-7)
EPA Substance Registry System N,N-Diethylaniline (91-66-7)
UNSPSC Code 12352116
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301+H311+H331-H315-H373-H411
Precautionary statements  P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P314
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  T,N
Risk Statements  23/24/25-33-51/53
Safety Statements  28-37-45-61-28A
RIDADR  UN 2432
WGK Germany  2
RTECS  BX3400000
8
Autoignition Temperature 500 °C
Hazard Note  Toxic
TSCA  TSCA listed
HS Code  2921 42 00
HazardClass  6.1
PackingGroup  III
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Aquatic Chronic 2
Skin Irrit. 2
STOT RE 2 Oral
Hazardous Substances Data 91-66-7(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 610 mg/kg LD50 dermal Rat > 5000 mg/kg
Limited Quantities 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
2
2 0

N,N-Diethylaniline price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 185868 N,N-Diethylaniline ≥99% 91-66-7 50ml $18.8 2026-03-19 Buy
Sigma-Aldrich 185868 N,N-Diethylaniline ≥99% 91-66-7 1l $81 2026-03-19 Buy
TCI Chemical D0475 N,N-Diethylaniline >99.0%(GC)(T) 91-66-7 25mL $20 2026-03-19 Buy
TCI Chemical D0475 N,N-Diethylaniline >99.0%(GC)(T) 91-66-7 500mL $46 2026-03-19 Buy
Sigma-Aldrich 185868 N,N-Diethylaniline ≥99% 91-66-7 250ml $57.3 2026-03-19 Buy
Product number Packaging Price Buy
185868 50ml $18.8 Buy
185868 1l $81 Buy
D0475 25mL $20 Buy
D0475 500mL $46 Buy
185868 250ml $57.3 Buy

N,N-Diethylaniline Chemical Properties,Uses,Production

Description

Diethyl aniline is a colorless to yellow liquid.Molecular weight=149.26; Boiling point=216℃; Flashpoint=85℃; Autoignition temperature=630℃. HazardIdentification (based on NFPA-704 M Rating System): Health3, Flammability 2, Reactivity 0. Slightly soluble in water.

Chemical Properties

N,N-Diethylaniline is a pale yellow liquid. It is slightly soluble in water (1.40 g/L at 12°C), and soluble in alcohol and ether.

Chemical Properties

light yellow liquid

Uses

As dyestuff intermediate, in organic syntheses.

Uses

DEA (diethanolamine) is an organic alkali used in formulations to neutralize organic acids and thus adjust pH. It is usually listed on ingredient labels preceding the compound that it is neutralizing. oleth-3 phosphate, for example, is a powerful emulsifier, but it is very acidic when it is made, so manufacturers use DeA to neutralize it and improve the nature of a formulation.

Uses

N,N-Diethylaniline is used in dyestuffs and in the synthesis of other intermediates and pharmaceuticals.

Synthesis Reference(s)

Chemistry Letters, 15, p. 293, 1986
Journal of the American Chemical Society, 95, p. 3038, 1973 DOI: 10.1021/ja00790a064

General Description

A colorless to yellow liquid with a fishlike odor, that is strongly corrosive. Irritating to skin, eyes and mucous membranes and moderately toxic by inhalation, absorption and ingestion. Flash point 185°F. Used in dyes and in the production of organic chemicals.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

N,N-Diethylaniline neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

May be fatal if inhaled, swallowed or absorbed through the skin. Vapor or mist is irritant to the eyes, mucous membranes, upper respiratory tract; causes skin irritation. Absorption into the body leads to the formation of methemoglobin which, in sufficient concentration, may cause cyanosis. Onset may be delayed 2-4 hours or longer. Exposure can cause nausea, dizziness, headache, damage to the eyes, and blood effects.

Fire Hazard

Special Hazards of Combustion Products: Emits toxic fumes under fire conditions.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic fumes of NOx. See also ANILINE DYES.

Potential Exposure

Diethyl aniline is used in organic synthesis and as a diestuff intermediate.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Note to physician: Treat for methemoglobinemia.Spectrophotometry may be required for precise determination of levels of methemoglobinemia in urine.

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with DEA youshould be trained on its proper handling and storage.Diethyl aniline must be stored to avoid contact with strongoxidizers (such as chlorine, bromine, and fluorine) andstrong acids since violent reactions occur. Store in tightlyclosed containers in a cool, well-ventilated area away fromstrong acids (such as hydrochloric, sulfuric, and nitric) anddirect sunlight.

Shipping

N,N-Diethylaniline must be labeled:“POISONOUS/TOXIC MATERIALS.” It falls in HazardClass 6.1 and Packing Group III.

Purification Methods

Reflux the base for 4hours with half its weight of acetic anhydride, then fractionally distil it under reduced pressure (b 92o/10mm). [Beilstein 12 IV 252.]

Incompatibilities

Forms explosive mixture with air.Violent reaction with strong oxidizers, halogens.Incompatible with acids, organic anhydrides, isocyanates,aldehydes.

Global( 376)Suppliers
Supplier Tel Email Country ProdList Advantage
Changde Changlian Chemical Co., Ltd.
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View Lastest Price from N,N-Diethylaniline manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
N,N-Diethylaniline pictures 2026-04-24 N,N-Diethylaniline
91-66-7
US $0.00 / kg 1000kg 99 20mt Yancheng Green Chemicals Co.,Ltd
N,N-Diethylaniline pictures 2026-03-20 N,N-Diethylaniline
91-66-7
US $10.00 / KG 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
N,N-Diethylaniline pictures 2025-05-26 N,N-Diethylaniline
91-66-7
US $10.00 / KG 1KG 95% 10 ton Hebei Chuanghai Biotechnology Co,.LTD
N,N-DIETHYLANILINE, 98%N,N-DIETHYLANILINE, 98%N,N-DIETHYLANILINE, 98% N,N-DiethylbenzeneaMine Pregna-1,4-diene-3,20-dione, 17,21-bis(acetyloxy)-2-bromo-6,9-difluoro-11-hydroxy-, (6b,11b)- coMpound with borane N,N-Diethylaniline, 99% 250ML N,N-Diethylaniline, 99% 5ML N,N-Diethylaniline puriss. p.a., >=99.5% N, ≥99%(GC) N,N-Diethylaniline, >=99%(GC) N.N-Diethylani DEA, N-Phenyldiethylamine Cefepime Impurity 11 N,N-Diethylanilin n,n-diethyl-anilin n,n-diethylanilin(czech) n,n-diethylaniline,[combustibleliquid] n,n-diethyl-benzenamin N,N-Diethyl-N-phenylamine Aniline, N,N-diethyl- Benzenamine,N,N-diethyl- Diethylaminobenzene Diethylphenylamine N,N-Diathylanilin N,N-diethylbenzenamine N,N'-DIETHYLANILINE N,N-DIETHYLANILINE N,N-DIETHYLAMINOBENZENE N,N-Diethylphenylamine N-PHENYLDIETHYLAMINE Diethylaniline (DEA) N,N-DIETHYLANILINE, FREE OF MONO-COMPOUN DS N,N-DIETHYLANILINE, 99+% N,N-Diethylaniline Phosphate N,N-DiethylanilineGr(ReagentForZinc) N,N,DiethylanilineForSynthesis N,N-DIETHYLBENZAMINE diaethylaniline Diethylaniline, n,n- N,N-DIETHYLANILINE extrapure AR N,N-DIETHYLANILINE pure 17,21-Bis(acetyloxy)-2-bromo-6b,9-difluoro-11b-hydroxypregna-1,4-dien-3,20-dione Halopredone diacetate N,N-Diethylaniline> Cefepime Impurity 11(Cefepime EP Impurity G) N,N-Diethylaniline ISO 9001:2015 REACH N N-DIETHYL?ANILINE (DIETHYL?ANILINE) N,N-Diethylaniline, GR N,N-DIETHYLANILINE AR Cefepime impurity 6 (N, N-diethylaniline) N,N-Diethylaniline 98.5% For Synthesis C12604800 N,N-Diethylaniline N,N-Diethylanilin 100 μg/ml Methanol N,N-Diethylaniline N,N-Diethylaniline, 98% Phenyldiethylamine Diaethylanilin DIETHYLANILINE DEA