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1-TERT-BUTYL-4-NITROBENZENE

1-TERT-BUTYL-4-NITROBENZENE Structure
1-TERT-BUTYL-4-NITROBENZENE structure
CAS No.
3282-56-2
Chemical Name:
1-TERT-BUTYL-4-NITROBENZENE
Synonyms
4-t-Butylnitrobenzene;p-t-Butylnitrobenzene;p-Nitro-t-butylbenzene;4-tert-Butylnitrobenzene;P-TERT-BUTYLNITROBENZENE;P-NITRO-TERT-BUTYLBENZENE;4-Nitro-tert-butylbenzene;1-TERT-BUTYL-4-NITROBENZENE;1-Nitro-4-tert-butylbenzene;1-tert-Butyl-4-nitrobenzene >
CBNumber:
CB9164886
Molecular Formula:
C10H13NO2
Molecular Weight:
179.22
MDL Number:
MFCD00041253
MOL File:
3282-56-2.mol
MSDS File:
SDS
Last updated:2026-01-13 11:25:15
Product description Number Pack Size Price
1-tert-Butyl-4-nitrobenzene >97.0%(GC) B2149 5g $31
1-tert-Butyl-4-nitrobenzene >97.0%(GC) B2149 25g $116
1-tert-Butyl-4-nitrobenzene B810025 100mg $60
1-(tert-Butyl)-4-nitrobenzene 95+% 120000 1g $72
1-(tert-Butyl)-4-nitrobenzene 330007 25g $75
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1-TERT-BUTYL-4-NITROBENZENE Properties

Melting point 1°C (estimate)
Boiling point 265-267°C
Density 1,0586 g/cm3
refractive index 1.5340
Flash point 265-267°C
storage temp. Store at room temperature
form clear liquid
color Light yellow to Yellow to Orange
BRN 2047337

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS06
Signal word  Warning
Hazard statements  H301-H311-H332
Precautionary statements  P261-P280h-P301+P310a-P304+P340-P405-P501a
Safety Statements  23-24/25
HS Code  2904.20.4500
NFPA 704
1
2 0

1-TERT-BUTYL-4-NITROBENZENE price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B2149 1-tert-Butyl-4-nitrobenzene >97.0%(GC) 3282-56-2 5g $31 2026-03-19 Buy
TCI Chemical B2149 1-tert-Butyl-4-nitrobenzene >97.0%(GC) 3282-56-2 25g $116 2026-03-19 Buy
TRC B810025 1-tert-Butyl-4-nitrobenzene 3282-56-2 100mg $60 2021-12-16 Buy
Matrix Scientific 120000 1-(tert-Butyl)-4-nitrobenzene 95+% 3282-56-2 1g $72 2021-12-16 Buy
Oakwood 330007 1-(tert-Butyl)-4-nitrobenzene 3282-56-2 25g $75 2021-12-16 Buy
Product number Packaging Price Buy
B2149 5g $31 Buy
B2149 25g $116 Buy
B810025 100mg $60 Buy
120000 1g $72 Buy
330007 25g $75 Buy

1-TERT-BUTYL-4-NITROBENZENE Chemical Properties,Uses,Production

Synthesis

1-tert-butyl-4-iodobenzene

35779-04-5

1-TERT-BUTYL-4-NITROBENZENE

3282-56-2

GENERAL STEPS: Add 1-tert-butyl-4-iodobenzene (0.5 mmol), copper(II) trifluoromethanesulfonate (45 mg, 0.125 mmol), potassium nitrite (KNO2, 128 mg, 1.5 mmol), and anhydrous dimethylsulfoxide (DMSO, 0.6 mL) to an oven-dried pressure tube under nitrogen atmosphere. The pressure tube was sealed with a polytetrafluoroethylene screw cap with a microvalve and purged through nitrogen for 5 min to displace the air. The mixture was stirred at room temperature for 10 minutes and then gradually warmed to 130 °C and the reaction was maintained at this temperature for 48 hours. Upon completion of the reaction, the mixture was cooled to room temperature, washed with excess ice water and extracted with ethyl acetate (3 x 10 mL). The organic phases were combined, dried with anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure to give the crude product. The crude product was purified by silica gel column chromatography (Table 2, entries 1-18) or basic alumina column chromatography (Table 2, entries 19-23) using a mixture of ethyl acetate and hexanes as eluent to give 1-tert-butyl-4-nitrobenzene in good final yield.

Purification Methods

Recrystallise it three times by partially freezing a mixture of the mono-nitro isomers, then recrystallise it twice from MeOH and dry it in vacuo [Brown J Am Chem Soc 81 3232 1959]. [Beilstein 5 H 418, 5 I 203, 5 II 321, 5 III 943, 5 IV 1052.]

References

[1] Tetrahedron Letters, 2005, vol. 46, # 28, p. 4715 - 4717
[2] Tetrahedron Letters, 2012, vol. 53, # 12, p. 1511 - 1513

1-TERT-BUTYL-4-NITROBENZENE synthesis

769-92-6
3282-56-2
Synthesis of 1-TERT-BUTYL-4-NITROBENZENE from 4-tert-Butylaniline

1-TERT-BUTYL-4-NITROBENZENE Preparation Products And Raw materials

Raw materials

Benzene, 1,1'-methylenebis[4-(1,1-dimethylethyl)-2-nitro- 1-Butanesulfonic acid, 1,1,2,2,3,3,4,4,4-nonafluoro-, 4-(1,1-dimethylethyl)phenyl ester BIS(4-TERT-BUTYLPHENYL)IODONIUM TRIFLATE POTASSIUM NITRITE COPPER(II) TRIFLUOROMETHANESULFONATE
4,4'-DI-TERT-BUTYLDIPHENYLMETHANE Dimethyl sulfoxide 1-tert-butyl-4-iodobenzene 4-tert-Butylaniline 4-tert-Butylphenylboronic acid

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Preparation Products

1-TERT-BUTYL-3-NITROBENZENE 2,5-DI-TERT-BUTYLNITROBENZENE 1-TERT-BUTYL-2-NITROBENZENE 4-(TERT-BUTYL)-1,2-DIAMINOBENZENE

1-TERT-BUTYL-4-NITROBENZENE Suppliers

Global( 88)Suppliers
Supplier Tel Email Country ProdList Advantage
Shaanxi Dideu Medichem Co. Ltd 		+86-029-81138252 +86-173 9270 1263 1057@dideu.com China 4000 58
Wuhan Chemwish Technology Co., Ltd 		027-67849912 sales@chemwish.com CHINA 10821 58
Richest Group Ltd 		18017061086 oled@richest-group.com CHINA 5600 58
ANHUI WITOP BIOTECH CO., LTD 		+8615255079626 eric@witopchemical.com China 23541 58
Dayang Chem (Hangzhou) Co.,Ltd. 		+86-0571-88938639 +8617705817739 info@dycnchem.com China 52705 58
GIHI CHEMICALS CO.,LIMITED 		+86-571-86217390; +8618058761490 info@gihichemicals.com China 49968 58
Zhengzhou Anbu Chem Co.,Ltd 		+86-0371-88006763; +8615988602810 sales@anbuchem.com China 3014 58
HANGZHOU LEAP CHEM CO., LTD. 		+86-571-87711850 market18@leapchem.com China 43333 58
Aladdin Scientific 		tp@aladdinsci.com United States 57505 58
Suzhou ARTK Medchem Co., Ltd. 		+8618118463618 sales1@artkmedchem.com China 39020 58
Supplier Advantage
Shaanxi Dideu Medichem Co. Ltd 		58
Wuhan Chemwish Technology Co., Ltd 		58
Richest Group Ltd 		58
ANHUI WITOP BIOTECH CO., LTD 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
GIHI CHEMICALS CO.,LIMITED 		58
Zhengzhou Anbu Chem Co.,Ltd 		58
HANGZHOU LEAP CHEM CO., LTD. 		58
Aladdin Scientific 		58
Suzhou ARTK Medchem Co., Ltd. 		58

View Lastest Price from 1-TERT-BUTYL-4-NITROBENZENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-TERT-BUTYL-4-NITROBENZENE pictures 2024-07-11 1-TERT-BUTYL-4-NITROBENZENE
3282-56-2
 US $1.00 / KG 1KG 99% 20T Shaanxi Dideu Medichem Co. Ltd

1-TERT-BUTYL-4-NITROBENZENE Spectrum

1-TERT-BUTYL-4-NITROBENZENE(3282-56-2)MS1-TERT-BUTYL-4-NITROBENZENE(3282-56-2)1HNMR1-TERT-BUTYL-4-NITROBENZENE(3282-56-2)IR1

3282-56-2(1-TERT-BUTYL-4-NITROBENZENE)Related Search:

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N-T-BUTYL 3-NITROBENZENESULFONAMIDE N-tert-Butyl 4-Nitrophenylsulfonamide 4-tert-Butyl-2-nitrophenyl propyl ether 4-TERT-BUTYL-2-NITROBENZENETHIOL 1-TERT-BUTYL-2-NITROBENZENE 97%,1-TERT-BUTYL-2-NITROBENZENE
3-(4-NITROPHENYL)ADAMANTANE-1-CARBOXYLIC ACID 2,6-DINITRO-3-TERT-BUTYL-4-ISOPROPYLTOLUENE 2-DIETHYLAMINOETHYL 1-(4-NITROPHENYL)CYCLOPENTANECARBOXYLATE HYDROCHLORIDE 1-(4-NITROPHENYL)CYCLOPENTANE-1-CARBOXYLICACID 2-methyl-2-(4-nitrophenyl)propanenitrile
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4-t-Butylnitrobenzene 4-tert-Butylnitrobenzene Benzene, 1-(1,1-dimethylethyl)-4-nitro- p-Nitro-t-butylbenzene p-t-Butylnitrobenzene P-TERT-BUTYLNITROBENZENE P-NITRO-TERT-BUTYLBENZENE 1-TERT-BUTYL-4-NITROBENZENE 4-Nitro-tert-butylbenzene 1-(1,1-Dimethylethyl)-4-nitrobenzene 1-Nitro-4-tert-butylbenzene 1-tert-Butyl-4-nitrobenzene 1-tert-Butyl-4-nitrobenzene > 3282-56-2