TRIPHENYLPHOSPHINE RESIN
- CAS No.
- 39319-11-4
- Chemical Name:
- TRIPHENYLPHOSPHINE RESIN
- Synonyms
- POLYMER-BOUND TRIPHENYLPHOSPHINE;POLYMER SUPPORTED TRIPHENYLPHOSPHINE;DIPHENYLPHOSPHINO-POLYSTYRENE;TRIPHENYLPHOSPHINE POLYSTYRENE;TRIPHENYLPHOSPHINE POLYMER BOUND;TRIPHENYLPHOSPHINE POL. BOUND, 100-200 M ESH, ~1.6 MMOL/G;PL-TPP RESIN;-C6H4P(C6H5)2;PL-TPP MP-RESIN;POLYSTYRENE-PPH2
- CBNumber:
- CB9181407
- Molecular Formula:
- C18H15P
- Molecular Weight:
- 262.285461
- MDL Number:
- MFCD20489348
- MOL File:
- 39319-11-4.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| Triphenylphosphine, polymer-bound 100-200?mesh, extent of labeling: ~3.2?mmol/g loading | 14664 | 25g | $304 |
| Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked) | 15-6730 | 1g | $48 |
| Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked) | 15-6730 | 5g | $143 |
| Triphenylphosphine resin Asreported | 291142 | 2g | $333 |
| Triphenylphosphine resin Asreported | 291142 | 5g | $455 |
| More product size | |||
| storage temp. | 2-8°C |
|---|---|
| form | Beads |
| color | White to yellow |
| Sensitive | Air Sensitive |
| InChI | 1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H |
| InChIKey | RIOQSEWOXXDEQQ-UHFFFAOYSA-N |
| SMILES | c1ccc(cc1)P(c2ccccc2)c3ccccc3 |
| UNSPSC Code | 12352200 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H312-H315-H319-H332-H335-H302+H312+H332 |
| Precautionary statements | P261-P280-P305+P351+P338 |
| PPE | dust mask type N95 (US), Eyeshields, Faceshields, Gloves |
| Hazard Codes | Xn,Xi |
| Risk Statements | 22-43-20/21/22-36/37/38 |
| Safety Statements | 36/37-36-26 |
| WGK Germany | 3 |
| F | 10-23 |
| HS Code | 29310099 |
| Storage Class | 11 - Combustible Solids |
TRIPHENYLPHOSPHINE RESIN price More Price(66)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 14664 | Triphenylphosphine, polymer-bound 100-200?mesh, extent of labeling: ~3.2?mmol/g loading | 39319-11-4 | 25g | $304 | 2024-03-01 | Buy |
| Strem Chemicals | 15-6730 | Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked) | 39319-11-4 | 1g | $48 | 2021-12-16 | Buy |
| Strem Chemicals | 15-6730 | Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked) | 39319-11-4 | 5g | $143 | 2021-12-16 | Buy |
| Usbiological | 291142 | Triphenylphosphine resin Asreported | 39319-11-4 | 2g | $333 | 2026-06-03 | Buy |
| Usbiological | 291142 | Triphenylphosphine resin Asreported | 39319-11-4 | 5g | $455 | 2026-06-03 | Buy |
TRIPHENYLPHOSPHINE RESIN Chemical Properties,Uses,Production
Chemical Properties
white to yellow beads
Uses
Triphenylphosphine resin is used for the preparation of polymer bound ylids which are useful for Wittig reactions.
Uses
Polymer-bound triphenylphosphine is a solid-supported reagent that can be used as a better alternative to triphenylphosphine in the Mitsunobu reaction.
It can also be used:
- For the esterification of alkylphosphonic acids using primary alcohols in the presence of iodine and imidazole.
- To catalyze the conversion of 3-[3-(1,3-dioxolan-2-yl)-1-hydroxypropyl]pyridine to 3-[1-bromo-3-(1,3-dioxolan-2-yl)propyl]pyridine using carbon tetrabromide.
- To isomerize (Z)-nitro olefins to the (E)-isomers.
- To prepare polymer-bound ylides which are useful in Wittig reactions.
- To convert alcohols or carboxylic acids to the corresponding chlorides.
- In combination with carbon tetrachloride for the coupling N-alkoxycarbonyl α-amino acids and primary amines to form the corresponding amides.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reaction type: solution phase peptide synthesis
reagent type: ligand
TRIPHENYLPHOSPHINE RESIN Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| CONIER CHEM AND PHARMA LIMITED | sales@conier.com | China | 49906 | 58 | |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9631 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +86-18530059196 | sale04@alfachem.cn | China | 9609 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +86-17732866630 | mina@chuanghaibio.com | China | 18114 | 58 |
| SUZHOU SENFEIDA CHEMICAL CO.,LTD | +86-0512-83500002 +86-15195660023 | 3899766280@qq.com | China | 26349 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 +86-15355479329 | market18@leapchem.com | China | 43303 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +86-18621343501 | product@acmec-e.com | China | 33301 | 58 |
| SHANGHAI KEAN TECHNOLOGY CO., LTD. | +8613817748580 | cooperation@kean-chem.com | China | 40048 | 58 |
| DAYANG CHEM (HANGZHOU) CO.,LTD | +86-88938639 +86-17705817739 | info@dycnchem.com | China | 53799 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
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