Sodium 4-chlorobenzene sulfinate
- CAS No.
- 14752-66-0
- Chemical Name:
- Sodium 4-chlorobenzene sulfinate
- Synonyms
- SODIUM 4-CHLOROBENZENESULFINATE;Sodium p-chlorobenzenesulfinate;sodium p-chlorobenzenesulphinate;Sodium 4-chlorobenzenesulphinate;Sodium p-chlorophenyl sulfinylate;Sodium 4-Chlorobenzenesulfinate >SODIUM 4-CHLOROBENZENE SULFINIC ACID;4-ChloroBenzene sulfinic acid sodium;Benzenesulfinicacid,4-chloro-,sodiumsalt;P-CHLOROBENZENESULFINIC ACID SODIUM SALT
- CBNumber:
- CB9246641
- Molecular Formula:
- C6H4ClNaO2S
- Molecular Weight:
- 198.6
- MDL Number:
- MFCD00035602
- MOL File:
- 14752-66-0.mol
- MSDS File:
- SDS
| Melting point | 300 °C |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| form | powder to crystal |
| color | White to Light yellow |
| Water Solubility | almost transparency |
| BRN | 3575604 |
| CAS DataBase Reference | 14752-66-0(CAS DataBase Reference) |
| FDA UNII | X2U129FZ4N |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H319 | |||||||||
| Precautionary statements | P264-P270-P301+P312-P330-P501-P264-P280-P305+P351+P338-P337+P313P | |||||||||
| Safety Statements | 24/25-22 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29309090 | |||||||||
| NFPA 704 |
|
Sodium 4-chlorobenzene sulfinate price More Price(42)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | S614394 | 4-CHLOROBENZENESULFINIC ACID SODIUM SALT AldrichCPR | 14752-66-0 | 1 unit | $197 | 2026-04-30 | Buy |
| Sigma-Aldrich | S614394 | 4-CHLOROBENZENESULFINIC ACID SODIUM SALT AldrichCPR | 14752-66-0 | 250MG | $179 | 2024-03-01 | Buy |
| TCI Chemical | C1559 | Sodium 4-Chlorobenzenesulfinate >98.0%(T) | 14752-66-0 | 5g | $36 | 2026-04-30 | Buy |
| TCI Chemical | C1559 | Sodium 4-Chlorobenzenesulfinate >98.0%(T) | 14752-66-0 | 25g | $98 | 2026-04-30 | Buy |
| Usbiological | 267348 | 4-Chloro-benzene-sulfinic acid sodium salt Asreported | 14752-66-0 | 2g | $302 | 2026-06-03 | Buy |
Sodium 4-chlorobenzene sulfinate Chemical Properties, Uses, Production
Chemical Properties
white crystalline powder
Synthesis
98-60-2
14752-66-0
The general procedure for the synthesis of sodium 4-chlorobenzenesulfinate from 4-chlorobenzenesulfonyl chloride: chlorobenzene (3.23 g, 28 mmol) was added dropwise to chlorosulfonic acid (10 g, 86 mmol) at a strictly controlled temperature not exceeding 20°C. The reaction was carried out by stirring for 1 hour. After completion of the reaction, the reaction solution was stirred at room temperature for 1 h, followed by slow pouring into ice (50 g) for quenching. The precipitate was collected by filtration, washed with water and added in batches to a solution of sodium bisulfite (7.5 g, 60 mmol) in water (28 mL). The mixture was heated to 90 °C and stirred for 1 h, during which a 50% sodium hydroxide solution was added slowly and dropwise to maintain the pH of the reaction system between 8-9. At the end of the reaction, the reaction mixture was filtered and the filtrate was allowed to stand at room temperature for 10 hours to crystallize. Filtration gave a white crystalline 4-chlorobenzenesulfinic acid sodium salt product, which was washed with cold water and dried at room temperature. The final product 3 was obtained in 75% yield (4.3 g). The characteristic absorption peaks (cm-1 ) of the IR spectrum of the product were as follows: 1575 (aromatic C-H stretching vibration); 1340, 1130 (SO2 symmetric and asymmetric stretching vibration); 1004, 981 (C-H in-plane bending vibration); 832, 740 (C-Cl stretching vibration).
References
[1] Tetrahedron Letters, 2014, vol. 55, # 29, p. 3851 - 3855
[2] Chemistry - An Asian Journal, 2016, vol. 11, # 15, p. 2121 - 2125
[3] Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry, 1976, vol. A30, # 8, p. 579 - 585
[4] European Journal of Medicinal Chemistry, 2007, vol. 42, # 6, p. 880 - 884
[5] Patent: WO2007/66844, 2007, A1. Location in patent: Page/Page column 14-15
Sodium 4-chlorobenzene sulfinate Preparation Products And Raw materials
Raw materials
Preparation Products
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| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Shanghai Sinch Parmaceuticals Tech. Co. Ltd. | +86-21-54098501 | sales@sinch.com.cn | China | 11592 | 64 |
| Nanjing Chemlin Chemical Co., Ltd | 025-83697070 13770331960 | info@chemlin.com.cn | China | 16305 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Sinopharm Chemical Reagent Co,Ltd. | 86-21-63210123 | sj_scrc@sinopharm.com | China | 9791 | 79 |
View Latest Price from Sodium 4-chlorobenzene sulfinate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-09-05 | Sodium 4-chlorobenzene sulfinate
14752-66-0
|
$1.00 | 1KG | 98% | 1000KG | Career Henan Chemical Co |
-
- Sodium 4-chlorobenzene sulfinate
14752-66-0
- $1.00
- 98%
- Career Henan Chemical Co
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