Butyltriphenylphosphonium bromide
- CAS No.
- 1779-51-7
- Chemical Name:
- Butyltriphenylphosphonium bromide
- Synonyms
- BTPPB;BuTPPBr;Triphenylbutylphosphonium bromide;BTPPBR;NSC 59684;(o-Boric Acid);(1-BUTYL)TRIPHEN;Butyl triphenyl pho;Butyltriphenylphosph;Butyltriphenylbromophosphine
- CBNumber:
- CB9260892
- Molecular Formula:
- C22H24BrP
- Molecular Weight:
- 399.3
- MDL Number:
- MFCD00011855
- MOL File:
- 1779-51-7.mol
| Product description | Number | Pack Size | Price |
| Butyltriphenylphosphonium bromide 99% | B102806 | 100g | $162 |
| Butyltriphenylphosphonium Bromide >98.0%(HPLC)(T) | B0970 | 25g | $40 |
| Butyltriphenylphosphonium Bromide >98.0%(HPLC)(T) | B0970 | 250g | $287 |
| n-ButyltriphenylphosphoniumBromide | B693805 | 10g | $130 |
| n-Butyltriphenylphosphoniumbromide | J51765 | 250g | $140 |
| More product size | |||
| Melting point | 240-243 °C(lit.) |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform, Methanol |
| form | Crystalline Powder |
| color | White |
| Water Solubility | soluble |
| Sensitive | Hygroscopic |
| BRN | 3580224 |
| InChI | InChI=1S/C22H24P.BrH/c1-2-3-19-23(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-18H,2-3,19H2,1H3;1H/q+1;/p-1 |
| InChIKey | IKWKJIWDLVYZIY-UHFFFAOYSA-M |
| SMILES | [P+](CCCC)(C1C=CC=CC=1)(C1C=CC=CC=1)C1=CC=CC=C1.[Br-] |
| CAS DataBase Reference | 1779-51-7(CAS DataBase Reference) |
| FDA UNII | 97KU95HRS8 |
| EPA Substance Registry System | Phosphonium, butyltriphenyl-, bromide (1779-51-7) |
| UNSPSC Code | 12352002 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H335-H301-H315-H319-H302-H312 | |||||||||
| Precautionary statements | P264-P270-P301+P310+P330-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P405-P501-P261-P280a-P301+P310a-P305+P351+P338-P501a-P280 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 21/22-36/37/38 | |||||||||
| Safety Statements | 36/37-36/37/39-26 | |||||||||
| RIDADR | 3464 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | TA1855200 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
Butyltriphenylphosphonium bromide price More Price(29)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | B102806 | Butyltriphenylphosphonium bromide 99% | 1779-51-7 | 100g | $162 | 2023-06-20 | Buy |
| TCI Chemical | B0970 | Butyltriphenylphosphonium Bromide >98.0%(HPLC)(T) | 1779-51-7 | 25g | $40 | 2025-07-31 | Buy |
| TCI Chemical | B0970 | Butyltriphenylphosphonium Bromide >98.0%(HPLC)(T) | 1779-51-7 | 250g | $287 | 2025-07-31 | Buy |
| TRC | B693805 | n-ButyltriphenylphosphoniumBromide | 1779-51-7 | 10g | $130 | 2021-12-16 | Buy |
| AK Scientific | J51765 | n-Butyltriphenylphosphoniumbromide | 1779-51-7 | 250g | $140 | 2021-12-16 | Buy |
Butyltriphenylphosphonium bromide Chemical Properties,Uses,Production
Chemical Properties
white crystalline powder
Uses
suzuki reaction
Uses
PTC catalyst
Uses
Reactant for: Free radical 5-exo-dig cyclization Intramolecular hydroacylalkoxylation Wittig reactions for stereoselective synthesis of alkenes Dimerization of α-olefins Alkylidenation of hydrazides for synthesis of indoles Tandem cyclization and 1,2-thiolate shift of nitrogen ylides
Uses
n-Butyltriphenylphosphonium Bromide is used in the synthesis of inhibitors of tubulin polymerization thus expressing antimitotic and antitubulin properties. Also used in the synthesis of 3-phenylpropanoic acids as peroxisome proliferator-activated receptor dual agonists affecting the mitochondrial carnitine system.
reaction suitability
reaction type: C-C Bond Formation
Synthesis
109-65-9
603-35-0
1779-51-7
Under nitrogen protection, 280 g of bromobutane and 696 g of triphenylphosphine were added to a 2 L four-neck flask dissolved in 500 mL of xylene. The reaction mixture was heated to reflux temperature with continuous stirring for 6 hours. After completion of the reaction, the system was cooled to room temperature, the precipitated white crystals were collected by filtration and washed with xylene. After drying, 797 g of butyltriphenylphosphonium bromide was obtained as a white solid in 97.7% yield.
References
[1] Patent: JP6136589, 2017, B2. Location in patent: Paragraph 0102-0104
[2] Acta Chimica Hungarica, 1987, vol. 124, # 5, p. 737 - 748
[3] Journal of Fluorine Chemistry, 2002, vol. 113, # 2, p. 177 - 183
[4] Pharmazie, 1999, vol. 54, # 1, p. 26 - 30
[5] Synthetic Communications, 1981, vol. 11, # 2, p. 125 - 132
Butyltriphenylphosphonium bromide Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shandong Promise New Material Co.,Ltd. | +86-18678104048 +86-15305334460 | johnwang@promisechemical.com | China | 88 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615350571055 | Sibel@chuanghaibio.com | China | 8772 | 58 |
| Dideu Industries Group Limited | +86-29-89586680 +86-15129568250 | 1026@dideu.com | China | 20363 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5251 | 58 |
| Anhui Ruihan Technology Co., Ltd | +8617756083858 | daisy@anhuiruihan.com | China | 973 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20183 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29734 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21620 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2988 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29852 | 58 |
View Lastest Price from Butyltriphenylphosphonium bromide manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-10-14 | Butyltriphenylphosphonium bromide
1779-51-7
|
US $0.00 / KG | 1KG | 99%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | |
 |
2025-10-11 | Butyltriphenylphosphonium bromide
1779-51-7
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2025-09-25 | Butyltriphenylphosphonium bromide
1779-51-7
|
US $5.00-0.50 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd |
-
- Butyltriphenylphosphonium bromide
1779-51-7
- US $0.00 / KG
- 99%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- Butyltriphenylphosphonium bromide
1779-51-7
- US $10.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- Butyltriphenylphosphonium bromide
1779-51-7
- US $5.00-0.50 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
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