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METHYL 4-AMINO-3-NITROBENZOATE

METHYL 4-AMINO-3-NITROBENZOATE structure

CAS No.: 3987-92-6

Chemical Name:: METHYL 4-AMINO-3-NITROBENZOATE

Synonyms: 4-AMINO-3-NITROMETHYLBENZOATE;METHYL 4-AMINO-3-NITROBENZOATE;Methyl 3-nitro-4-aminobenzoate;Methyl4-amino-3-nitrobenzoate,97%;METHYL 4-AMINO-3-NITROBENZENECARBOXYLATE;4-Amino-3-nitrobenzoic acid methyl ester;3-Nitro-4-aminobenzoic acid methyl ester;Benzoic acid, 4-amino-3-nitro-, methyl ester;methyl 4-amino-3-nitrobenzoatemethyl 4-amino-3-nitrobenzoate;2-Amino-5-(methoxycarbonyl)nitrobenzene, 4-(Methoxycarbonyl)-2-nitroaniline

CBNumber:: CB9282610

Molecular Formula:: C8H8N2O4

Molecular Weight:: 196.16

MDL Number:: MFCD00017562

MOL File:: 3987-92-6.mol

MSDS File:: SDS

Last updated:2026-01-13 11:26:43

Product description	Number	Pack Size	Price
Methyl4-amino-3-nitrobenzoate	M328673	500mg	$65
Methyl4-amino-3-nitrobenzoate	M328673	100mg	$45
Methyl4-amino-3-nitrobenzoate 99.81%	CS-W007745	25g	$62
Methyl4-amino-3-nitrobenzoate	X2837	5g	$41
Methyl 4-amino-3-nitrobenzenecarboxylate 95+%	042844	1g	$10
More product size

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METHYL 4-AMINO-3-NITROBENZOATE Properties

Melting point	204-206°C
Boiling point	392.8±22.0 °C(Predicted)
Density	1.386±0.06 g/cm3(Predicted)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
pka	-2.59±0.10(Predicted)
Appearance	Light yellow to yellow Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a

Hazard Codes

HazardClass

IRRITANT

HS Code

2922390090

NFPA 704

	0
2		0

METHYL 4-AMINO-3-NITROBENZOATE price More Price(33)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TRC	M328673	Methyl4-amino-3-nitrobenzoate	3987-92-6	500mg	$65	2021-12-16	Buy
TRC	M328673	Methyl4-amino-3-nitrobenzoate	3987-92-6	100mg	$45	2021-12-16	Buy
ChemScene	CS-W007745	Methyl4-amino-3-nitrobenzoate 99.81%	3987-92-6	25g	$62	2021-12-16	Buy
AK Scientific	X2837	Methyl4-amino-3-nitrobenzoate	3987-92-6	5g	$41	2021-12-16	Buy
Matrix Scientific	042844	Methyl 4-amino-3-nitrobenzenecarboxylate 95+%	3987-92-6	1g	$10	2021-12-16	Buy

Product number	Packaging	Price	Buy
M328673	500mg	$65	Buy
M328673	100mg	$45	Buy
CS-W007745	25g	$62	Buy
X2837	5g	$41	Buy
042844	1g	$10	Buy

METHYL 4-AMINO-3-NITROBENZOATE Chemical Properties,Uses,Production

Chemical Properties

Methyl 4-amino-3-nitrobenzoate is a synthetic compound that has been found to have a variety of uses. It has been used to prepare intramolecular hydrogen bonds in anilines, and it can be used as an intermediate to synthesize amides and anilines. This molecule also forms resonance structures with the nitro group, which allows for increased stability. The proton magnetic resonance spectra of Methyl 4-amino-3-nitrobenzoate show that the molecule has a high degree of symmetry, which is due to the presence of intramolecular hydrogen bonding.

Synthesis

67-56-1

1588-83-6

3987-92-6

4-Amino-3-nitrobenzoic acid (50 g, 270 mmol, 1 eq.) was suspended in methanol (600 mL) at room temperature. Subsequently, sulfoxide chloride (20 mL, 270 mmol, 1 eq.) was slowly added dropwise to the above suspension. The reaction mixture was heated to reflux for 16 h. After completion of the reaction, it was cooled to room temperature. The resulting yellow solid, methyl 4-amino-3-nitrobenzoate (D1) (53 g, 100% yield), was collected by filtration, and the product could be used in subsequent reactions without further purification. Mass spectrometry analysis showed [M + H]+ = 197.3, retention time (RT) = 2.42 min.

References

[1] Patent: WO2004/94430, 2004, A1. Location in patent: Page 16
[2] Patent: WO2006/40148, 2006, A1. Location in patent: Page/Page column 19-20
[3] Patent: WO2015/57938, 2015, A1. Location in patent: Page/Page column 102
[4] Patent: CN106146416, 2016, A. Location in patent: Paragraph 0046; 0047; 0048; 0049; 0050
[5] European Journal of Medicinal Chemistry, 2018, vol. 143, p. 8 - 20

METHYL 4-AMINO-3-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Methanol 4-Amino-3-nitrobenzoic acid

Preparation Products

4-Acetamido-3-hydroxybenzoic acid

METHYL 4-AMINO-3-NITROBENZOATE Suppliers

Global( 147)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29735	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29831	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4241	58
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	8497	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	21193	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58
Jinan Liheng Biotechnology Co., Ltd.	15865262812	info@lihengpharm.com	CHINA	938	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10000	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Changzhou Ansciep Chemical Co., Ltd.	58
Jinan Carbotang Biotech Co.,Ltd.	58
Accela ChemBio Inc.	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Jinan Liheng Biotechnology Co., Ltd.	58
Fuxin Pharmaceutical	58

View Lastest Price from METHYL 4-AMINO-3-NITROBENZOATE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2026-02-26	Methyl 4-amino-3-nitrobenzoate 3987-92-6	US $100.00 / kg	1kg	98.0%min	20tons/month	Asia Chem I and E (Jiangsu) Co Ltd
	2019-07-06	Methyl 4-amino-3-nitrobenzoate 3987-92-6	US $7.00 / kg	1kg	99%	100kg	Career Henan Chemical Co

Methyl 4-amino-3-nitrobenzoate
3987-92-6
US $100.00 / kg
98.0%min
Asia Chem I and E (Jiangsu) Co Ltd

Methyl 4-amino-3-nitrobenzoate
3987-92-6
US $7.00 / kg
99%
Career Henan Chemical Co

METHYL 4-AMINO-3-NITROBENZOATE Spectrum

METHYL 4-AMINO-3-NITROBENZOATE(3987-92-6)¹HNMR

3987-92-6(METHYL 4-AMINO-3-NITROBENZOATE)Related Search:

Methyl 4-aMino-2,6-diMethylbenzoate Methyl 4-amino-3-bromobenzoate Methyl 2,6-dichloro-4-aminobenzoate Methyl 4-amino-3-(trifluoromethoxy)benzoate METHYL 4-AMINO-3-CHLOROBENZOATE

METHYL 4-AMINO-2,3-DIFLUORO-5-NITROBENZOATE METHYL 4-AMINO-2,3-DIFLUOROBENZOATE METHYL 4-AMINO-3-CHLORO-5-METHYLBENZOATE Methyl-4-amino-3-fluorobenzoate Methyl 4-amino-2-chlorobenzoate

Methyl 4-aMino-3,5-difluorobenzoate Methyl 4-amino-2-cyanobenzoate Methyl 4-amino-2-methoxybenzoate METHYL 4-AMINO-3,5-DICHLOROBENZOATE methyl 4-amino-2-chloro-5-iodobenzoate

methyl 4-amino-2-bromo-3-fluorobenzoate Methyl-4-amino-3-bromo-5-methylbenzoate Methyl 4-amino-3-methoxybenzoate

1of4

4-AMINO-3-NITROMETHYLBENZOATE 3-Nitro-4-aminobenzoic acid methyl ester 4-Amino-3-nitrobenzoic acid methyl ester METHYL 4-AMINO-3-NITROBENZENECARBOXYLATE METHYL 4-AMINO-3-NITROBENZOATE methyl 4-amino-3-nitrobenzoatemethyl 4-amino-3-nitrobenzoate Methyl 3-nitro-4-aminobenzoate 2-Amino-5-(methoxycarbonyl)nitrobenzene, 4-(Methoxycarbonyl)-2-nitroaniline Benzoic acid, 4-amino-3-nitro-, methyl ester Methyl4-amino-3-nitrobenzoate,97% 3987-92-6 Aromatic Esters