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2-Hydroxypropyl methacrylate

CAS No.
27813-02-1
Chemical Name:
2-Hydroxypropyl methacrylate
Synonyms
HYDROXYPROPYL METHACRYLATE;PROPYLENE GLYCOL MONOMETHACRYLATE;METHACRYLIC ACID 2-HYDROXYPROPYL ESTER;methacrylic acid, monoester with propane-1,2-diol;2HPMA;L-61040;rocryl410;Photomer 2317;2-Hydroxypropyl meth;CHLUMICRYL HPMA Monomer
CBNumber:
CB9299748
Molecular Formula:
C7H12O3
Molecular Weight:
144.17
MDL Number:
MFCD00004536
MOL File:
27813-02-1.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-07-02 22:15:05

2-Hydroxypropyl methacrylate Properties

Melting point -58°C
Boiling point 57 °C/0.5 mmHg (lit.)
Density 1.066 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
vapor pressure 0.05 mm Hg ( 20 °C)
refractive index n20/D 1.447(lit.)
Flash point 206 °F
storage temp. 2-8°C
solubility 107g/l
form Liquid
color Clear
Specific Gravity 1.066
PH 6 (50g/l, H2O, 20℃)
Viscosity 8.88mm2/s
Water Solubility Soluble in water.
BRN 1752228
Cosmetics Ingredients Functions FILM FORMING
InChIKey GNSFRPWPOGYVLO-UHFFFAOYSA-N
LogP 0.97 at 20℃
CAS DataBase Reference 27813-02-1(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances HYDROXYPROPYL METHACRYLATE
FDA 21 CFR 175.105; 177.1010
FDA UNII UKW89XAX2X
EPA Substance Registry System Hydroxypropyl methacrylate (27813-02-1)
UNSPSC Code 12162002
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
Signal word  Danger
Hazard statements  H315-H317-H319-H335-H340-H350
Precautionary statements  P201-P202-P280-P302+P352-P305+P351+P338-P308+P313
Hazard Codes  Xi,T
Risk Statements  36/37/38-43-36-46-45
Safety Statements  26-36/37-37/39-24/25-45-53
WGK Germany  1
RTECS  UD3442500
TSCA  TSCA listed
HS Code  29161490
Hazardous Substances Data 27813-02-1(Hazardous Substances Data)
Toxicity rat,LD50,oral,11200mg/kg (11200mg/kg),LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMAGASTROINTESTINAL: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: DYSPNEA,National Technical Information Service. Vol. OTS0544834,
REACH Registrations Active
NFPA 704
1
2 1

2-Hydroxypropyl methacrylate price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 268542 Hydroxypropyl methacrylate Mixture of hydroxypropyl and hydroxyisopropyl methacrylates, 97%, contains 180-220 ppm monomethyl ether hydroquinone as inhibitor 27813-02-1 1l $227 2026-04-30 Buy
Sigma-Aldrich 268542 Hydroxypropyl methacrylate Mixture of hydroxypropyl and hydroxyisopropyl methacrylates, 97%, contains 180-220 ppm monomethyl ether hydroquinone as inhibitor 27813-02-1 18l $813 2026-04-30 Buy
TCI Chemical M0512 Hydroxypropyl Methacrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Methacrylate) (stabilized with MEHQ) >97.0%(GC) 27813-02-1 25mL $17 2026-04-30 Buy
TCI Chemical M0512 Hydroxypropyl Methacrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Methacrylate) (stabilized with MEHQ) >97.0%(GC) 27813-02-1 500mL $50 2026-04-30 Buy
scipoly M-120 2-Hydroxypropyl methacrylate 27813-02-1 200g $33 2026-05-22 Buy
Product number Packaging Price Buy
268542 1l $227 Buy
268542 18l $813 Buy
M0512 25mL $17 Buy
M0512 500mL $50 Buy
M-120 200g $33 Buy

2-Hydroxypropyl methacrylate Chemical Properties, Uses, Production

Description

Hydroxypropyl methacrylate(HPMA) is a clear, colorless liquid with a pungent, sweet odor. The product contains low levels of a polymerization inhibitor along with small amounts of methacrylic acid, and propylene oxide. HPMA is used in the manufacture of acrylic polymers for adhesives, inks, and coatings for automotive, appliance and metal applications. The added hydroxyl groups improve adhesion to surfaces, incorporate cross-link sites, and impart corrosion, fogging, and abrasion resistance.

Chemical Properties

Clear colorless liquid

Uses

Monomer for acrylic resins, nonwoven fabric binders, detergent lubricating-oil additives.

Uses

Hydroxypropyl methacrylate is a functional monomer for the preparation of hot solid acrylic coatings, styrene-butadiene latex modifiers, acrylic modified polyurethane coating ,water-soluble plating coatings , adhesives ,textile finishing agent ,paper coating , photosensitive paint and polyurethane vinyl resin modified agent. Mainly used in the manufacture are active groups of hydroxyl acrylic resin. Used in reactive diluent and cross-linking agent in the UV curing system.

Definition

ChEBI: 2-hydroxypropyl methacrylate is an enoate ester that is the 1-methacryloyl derivative of propane-1,2-diol. It has a role as a polymerisation monomer. It is functionally related to a propane-1,2-diol and a methacrylic acid.

Application

2-Hydroxypropyl Methacrylate (HPMA) used in the preparation of solid and emulsion polymers, acrylic dispersions in combination with other (meth) acrylates, which are used in various industries, especially for textile coatings and dressings. HPMA is widely used in the production of acrylic polyols for automotive components, refurbishment coatings, and industrial coatings. HPMA is also used as a comonomer in styrene-based unsaturated polyesters, PMMA-based acrylic resins, and vinyl ester formulations in anchor bolts and chemical anchors.HPMA is particularly useful as a hydrophobic hydroxy monomer in the manufacture of sealants for vacuum impregnation of cast aluminum components. HPMA is also widely used in the production of flexible UV-curable photopolymer printing plates.

General Description

White liquid with a light unpleasant odor. May float or sink in water.

Reactivity Profile

2-Hydroxypropyl methacrylate polymerization: May polymerize when hot or when exposed to ultraviolet light and free-radical catalysts [USCG, 1999].

Health Hazard

Inhalation causes coughing and irritation of nose and throat; lung injury may occur. Ingestion causes irritation and burning of mouth and stomach. Contact of vapor with eyes causes irritation. Liquid may cause severe eye burns and irritation of skin.

Fire Hazard

Behavior in Fire: Compound may polymerize when hot and burst container.

Safety

2-Hydroxypropyl Methacrylate (2-HPMA) is a combustible substance. With intense healing, it forms explosive vapors with air. Vapors are heavier than air and may spread along with floors. In the case of fire, the formation of harmful gaseous products is possible. Contact with skin may cause an allergic reaction. When working with 2-Hydroxypropyl Methacrylate (2-HPMA), sanitary rules for organizing technological processes and hygienic requirements for production equipment must be strictly observed.

2-Hydroxypropyl methacrylate Preparation Products And Raw materials

Global Suppliers ( 487)
Supplier Tel Email Country ProdList Advantage
QINGDAO CHENXI NEW ENERGYCO.LTD 19357188251 1605755801@qq.com China 26 58
Guangzhou Yuanda New Material Co., Ltd. 19849939632; 19849939632 2470479589@qq.com China 4273 58
JIANGSU BSECHEM CHEMICAL TECHNOLOGY Co., Ltd 87161895 15651337098 15651337098@163.com China 4995 58
Shandong Yaoming Chemical Co., Ltd. 15550028560 472498067@qq.com China 356 58
IGM RESINS 021-52080993 13917193189 selene.wu@igmresins.com China 89 57
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55

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