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Perfluorobutyl iodide

CAS No.
423-39-2
Chemical Name:
Perfluorobutyl iodide
Synonyms
1,1,1,2,2,3,3,4,4-NONAFLUORO-4-IODOBUTANE;NONAFLUOROBUTYL IODIDE;Perfluoroiodobutane;NONAFLUORO-1-IODOBUTANE;C1014NH3;uorobutyL;PERFLUOROBUTYL IODODE;PERFLUOROBUTYL IODIDE;1-Iodoperfluorobutane;1-IODONONAFLUOROBUTANE
CBNumber:
CB9474482
Molecular Formula:
C4F9I
Molecular Weight:
345.93
MDL Number:
MFCD00001062
MOL File:
423-39-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 05:25:21
Product description Number Pack Size Price
Nonafluoro-1-iodobutane 98% 317845 25g $77.9
Nonafluoro-1-iodobutane 98% 317845 100g $200
Nonafluorobutyl Iodide >98.0%(GC) N0499 25g $38
Nonafluorobutyl Iodide >98.0%(GC) N0499 100g $108
Nonafluorobutyl Iodide Asreported 285918 25g $315
More product size

Perfluorobutyl iodide Properties

Melting point -88 °C
Boiling point 66-67 °C
Density 2.01 g/mL at 25 °C(lit.)
refractive index n20/D 1.3285(lit.)
Flash point None
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form Liquid
Specific Gravity 2.010
color Clear purple
Water Solubility immiscible
Sensitive Light Sensitive
BRN 1777546
Exposure limits ACGIH: TWA 0.01 ppm
Stability Stable. Incompatible with bases.
InChI 1S/C4F9I/c5-1(6,3(9,10)11)2(7,8)4(12,13)14
InChIKey PGRFXXCKHGIFSV-UHFFFAOYSA-N
SMILES FC(F)(F)C(F)(F)C(F)(F)C(F)(F)I
CAS DataBase Reference 423-39-2(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII N4357HS8BY
NIST Chemistry Reference 1-Iodononafluorobutane(423-39-2)
EPA Substance Registry System Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo- (423-39-2)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Environment (GHS09)
GHS09
Signal word  Warning
Hazard statements  H411
Precautionary statements  P273-P391-P501
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
RIDADR  2810
WGK Germany  3
RTECS  EK5360000
8
Hazard Note  Irritant/Light Sensitive
TSCA  TSCA listed
HazardClass  6.1(b)
PackingGroup  III
HS Code  29034700
Storage Class 10 - Combustible liquids
Hazard Classifications Aquatic Chronic 2
NFPA 704
1
2 1

Perfluorobutyl iodide price More Price(52)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 317845 Nonafluoro-1-iodobutane 98% 423-39-2 25g $77.9 2026-04-30 Buy
Sigma-Aldrich 317845 Nonafluoro-1-iodobutane 98% 423-39-2 100g $200 2026-04-30 Buy
TCI Chemical N0499 Nonafluorobutyl Iodide >98.0%(GC) 423-39-2 25g $38 2026-04-30 Buy
TCI Chemical N0499 Nonafluorobutyl Iodide >98.0%(GC) 423-39-2 100g $108 2026-04-30 Buy
Usbiological 285918 Nonafluorobutyl Iodide Asreported 423-39-2 25g $315 2026-06-03 Buy
Product number Packaging Price Buy
317845 25g $77.9 Buy
317845 100g $200 Buy
N0499 25g $38 Buy
N0499 100g $108 Buy
285918 25g $315 Buy

Perfluorobutyl iodide Chemical Properties,Uses,Production

Description

Perfluorobutyl iodide (PFBI) is a promising alternative to chlorofluorocarbon solvents used in aircraft ground maintenance operations and other military and commercial operations because it cleans well, has zero ozone depletion potential, and has extremely low global warming properties. Perfluorobutyl iodides also could used as gain media for a solar-pumped laser amplifier. This compound is usually utilized as perfluoroalkyl radical precursors[1–3].

Chemical Properties

clear colourless liquid with pungent odour

Uses

Perfluorobutyl Iodide is used as an organocatalyst in some polymerization reactions.

Synthesis

Add 10 mol of triphenylphosphine chloride and 50 mol of N-methylimidazole hydrochloride to methanol and stir to dissolve. Heat to 50°C, add 65 moles of aluminum chloride, stir and dissolve, continue the reaction for 2 hours, raise the temperature to 80°C, evaporate the solvent, and filter to remove the insoluble matter to obtain quaternary ammonium salt and N-alkyl imidazole salt composite aluminum acid. Salt ionic liquid. Add 2 kg of the aluminate ionic liquid prepared in step S1 to the reaction kettle equipped with a reflux device, then add 264 g of perfluoropentanoic acid and raise the temperature to 80°C. Slowly add 2.5 mol of iodine ethanol solution dropwise within 5 hours. After the dropwise addition is completed, heat to 100°C for 8 hours. The reaction solution was allowed to stand and separated into layers to separate the aluminate ionic liquid and product layers. The product layer was purified by distillation to obtain 336g of Perfluorobutyl iodide.

References

[1] Darol Dodd, Colin Hardy, Gary Hoffman. "Perfluoro-n-butyl iodide: acute toxicity, subchronic toxicity and genotoxicity evaluations. " International Journal of Toxicology 23 4 (2004): 249–58.
[2] J. Lee, B. Tabibi, W. Weaver. "Perfluorobutyl iodides as gain media for a solar-pumped laser amplifier." Optics Communications 67 1 (1988): 435–440.
[3] Zhang, Juan et al. "Perfluorobutyl iodide-assisted direct cyanomethylation of azoles and phenols with acetonitrile." RSC Advances 26 (2015): 20562–20565.

2706-90-3
423-39-2
Synthesis of Perfluorobutyl iodide from Perfluoropentanoic acid
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 Perfluorobutyl iodide pictures 2026-05-28 Perfluorobutyl iodide
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$49.60 1KG 99% 5000kg Hebei Chuanghai Biotechnology Co,.LTD
Perfluorobutyl iodide pictures 2025-12-24 Perfluorobutyl iodide
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1KG 99.0% 1000 tons Shaanxi Dideu Medichem Co. Ltd
Perfluorobutyl iodide pictures 2025-12-01 Perfluorobutyl iodide
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1KG 98 10000KGS Shaanxi Dideu New Materials Co. Ltd
PERFLUOROBUTYL IODODE Nonafluoro-1-iodobutane,1-Iodoperfluorobutane, Perfluorobutyl iodide 1-Iodoperfluorobutane, 1,1,1,2,2,3,3,4,4-Nonafluoro-4-iodobutane 1-Iodoperfluorobutane, Perfluorobutyl iodide Perfluorobutyl iodide,99% PERFLUOROBUTYL IODIDE (STABILISED WITH S Nonafluoro-1-iodobutane 98% Perfluorobutyl iodide (stabilised with silver platelets) for synthesis C1014NH3 uorobutyL 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo-butan Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo- m-Nonafluorobutyl iodide 1-IODONONAFLUOROBUTANE PERFLUOROBUTYL IODIDE PERFLUORO-N-BUTYL IODIDE N-NONAFLUOROBUTYLIODIDE NONAFLUOROBUTYL IODIDE NONAFLUORO-1-IODOBUTANE NONAFLUORO-N-BUTYL IODIDE 1,1,2,2,3,3,4,4,4-Nonafluoro-1-iodobutane NONAFLUORO-1-IODOBUTANE, STAB. PERFLUOROBUTYL IODIDE 95% 1-Iodoperfluorobutane 1-Iodononafluorobutane,97% n-Nonafluorobutyliodide,98% 1-Iodononafluorobutane 98% 1-Iodononafluorobutane98% Nonafluorobutyl Iodide > Nonafluoro-1-iodobutane, 99%, for synthesis CHLUMOFIUOR CH-4 Perfluorobutyl iodide 1,1,1,2,2,3,3,4,4-NONAFLUORO-4-IODOBUTANE Perfluoroiodobutane 423-39-2 CF3CF23I C4F9I Organic Building Blocks Halogenated Hydrocarbons Fluorous Compounds Fluorous Chemistry Alkyl Building Blocks Alkyl Building Blocks Chemical Synthesis Fluorinated Building Blocks F-Tagged Halogenated Hydrocarbons Organic Building Blocks Organic Fluorinated Building Blocks Organic Fluorides Fluorous Chemistry Fluorous Compounds Synthetic Organic Chemistry