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2-Bromo-3-methylaniline

2-Bromo-3-methylaniline structure

CAS No.: 54879-20-8

Chemical Name:: 2-Bromo-3-methylaniline

Synonyms: 3-Amino-2-bromotoluene;2-BROMO-3-METHYLANILIN;2-BROMO-3-METHYLANILINE;2-broMo-3-MethylbenzenaMine;2-BROMO-3-METHYLANILINE 98;2-BroMo-3-Methylaniline, 97+%;BenzenaMine, 2-broMo-3-Methyl-;2-Bromo-3-methylaniline 95%min;methyl 2-((2-aminophenyl)thio)acetate;2-Bromo-3-methylaniline, 98%, for synthesis

CBNumber:: CB9498840

Molecular Formula:: C7H8BrN

Molecular Weight:: 186.05

MDL Number:: MFCD06411367

MOL File:: 54879-20-8.mol

MSDS File:: SDS

Last updated:2025-08-08 17:45:00

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2-Bromo-3-methylaniline Properties

Boiling point	48 °C/0.03 mmHg (lit.)
Density	1.489 g/mL at 25 °C (lit.)
refractive index	n20/D 1.605(lit.)
Flash point	>230 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	Liquid
pka	2.66±0.10(Predicted)
color	Pale brown
InChI	InChI=1S/C7H8BrN/c1-5-3-2-4-6(9)7(5)8/h2-4H,9H2,1H3
InChIKey	VJNUZLYTGSGDHR-UHFFFAOYSA-N
SMILES	C1(N)=CC=CC(C)=C1Br
UNSPSC Code	12352100

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302-H317

Precautionary statements

P280-P301+P312+P330-P302+P352

Hazard Codes

Risk Statements

22-43-36/37/38-20/21/22

Safety Statements

36/37-60-26-23-9

RIDADR

2810

WGK Germany

HazardClass

6.1

HS Code

29214300

NFPA 704

	0
2		0

2-Bromo-3-methylaniline price More Price(38)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	645621	2-Bromo-3-methylaniline 98%	54879-20-8	5g	$388	2023-06-20	Buy
TRC	B814223	2-bromo-3-methylaniline	54879-20-8	1g	$45	2021-12-16	Buy
TRC	B814223	2-bromo-3-methylaniline	54879-20-8	5g	$110	2021-12-16	Buy
Matrix Scientific	076557	2-Bromo-3-methylaniline 95+%	54879-20-8	25g	$118	2021-12-16	Buy
Biosynth Carbosynth	FB55595	2-Bromo-3-methylaniline	54879-20-8	5G	$120	2021-12-16	Buy

Product number	Packaging	Price	Buy
645621	5g	$388	Buy
B814223	1g	$45	Buy
B814223	5g	$110	Buy
076557	25g	$118	Buy
FB55595	5G	$120	Buy

2-Bromo-3-methylaniline Chemical Properties,Uses,Production

Synthesis

Add iron powder (3.86 g, 69 mmol), water (5 mL) and concentrated HCL (0.5 mL) sequentially to a solution of commercially available 2-bromo-3-nitrotoluene (5 g, 23 mmol) in methanol (100 mL) at room temperature and heat the mixture at reflux for 125 h. Remove the solvents under reduced pressure, suspend the residue in water (400 mL) and extract with chloroform (3 x 250 mL). Dry the combined organic extracts over MGS04 and remove the solvents under reduced pressure to afford 2-bromo-3-methylphenylamine as an amber oil (4.45 g, 100percent): 1H NMR (CDC13) 5 2.30 (s, 3H), 4.00 (br s, 2H), 7.60 (m, 2H), 7.00 (t, 1H).

References

[1] Patent: WO2004/63155, 2004, A1. Location in patent: Page 120-121
[2] Journal of Organic Chemistry, 1988, vol. 53, # 6, p. 1170 - 1176
[3] Angewandte Chemie - International Edition, 2018, vol. 57, # 34, p. 11040 - 11044
[4] Angew. Chem., 2018, vol. 130, # 34, p. 11206 - 11210,5
[5] Angewandte Chemie - International Edition, 2010, vol. 49, # 40, p. 7257 - 7260

2-Bromo-3-methylaniline Preparation Products And Raw materials

Raw materials

2-Bromo-3-nitrotoluene Benzene, 2-bromo-5-(bromomethyl)-1,3-dimethyl- Iron Water Methanol

Hydrochloric acid

1of2

Preparation Products

2-Bromo-3-nitrotoluene N-(3-Bromo-2-methylphenyl)acetamide 3-METHYL-2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL) BENZENAMINE

2-Bromo-3-methylaniline Suppliers

Global( 176)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	+8613336195806	sales@capot.com	China	29734	60
Fluoropharm Co., Ltd.	+86-0571-85586753 +86-13336034509	sales@fluoropharm.com	China	1445	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4241	58
Nanjing Dolon Biotechnology Co.,Ltd.	18905173768	52513593@qq.com	CHINA	2972	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	21193	58
Shanghai Worldyang Chemical Co.,Ltd.	+86-021-56795779 +8613651600618	sales@worldyachem.com	China	1382	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22963	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49917	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
Fluoropharm Co., Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
Changzhou Ansciep Chemical Co., Ltd.	58
Nanjing Dolon Biotechnology Co.,Ltd.	58
Accela ChemBio Inc.	58
Shanghai Worldyang Chemical Co.,Ltd.	58
Hubei xin bonus chemical co. LTD	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58

View Lastest Price from 2-Bromo-3-methylaniline manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2022-08-12	2-BROMO-3-METHYLANILINE 98 54879-20-8	US $1.10 / g	1g	99.00%	100 Tons Min	Dideu Industries Group Limited
	2020-01-09	2-BROMO-3-METHYLANILINE 98 54879-20-8	US $1.00 / KG	1KG	98% HPLC	10 tons/month	Career Henan Chemical Co

2-BROMO-3-METHYLANILINE 98
54879-20-8
US $1.10 / g
99.00%
Dideu Industries Group Limited

2-BROMO-3-METHYLANILINE 98
54879-20-8
US $1.00 / KG
98% HPLC
Career Henan Chemical Co

2-Bromo-3-methylaniline Spectrum

2-Bromo-3-methylaniline(54879-20-8)¹HNMR

54879-20-8(2-Bromo-3-methylaniline)Related Search:

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1of4

3-Amino-2-bromotoluene 2-broMo-3-MethylbenzenaMine BenzenaMine, 2-broMo-3-Methyl- 2-BROMO-3-METHYLANILINE 98 2-BroMo-3-Methylaniline, 97+% 2-BROMO-3-METHYLANILIN 2-Bromo-3-methylaniline, 98%, for synthesis 2-BROMO-3-METHYLANILINE 98 ISO 9001：2015 REACH 2-BROMO-3-METHYLANILINE methyl 2-((2-aminophenyl)thio)acetate 2-Bromo-3-methylaniline 95%min 54879-20-8 BrCH3C6H3NH2 Anilines, Amides & Amines Bromine Compounds Amines C7 Nitrogen Compounds