2-Bromo-5-fluorobenzyl alcohol
- CAS No.
- 202865-66-5
- Chemical Name:
- 2-Bromo-5-fluorobenzyl alcohol
- Synonyms
- CAS:202865-66-5;BUTTPARK 87\01-69;RARECHEM AL BD 0749;Tavaborole Intermediate;Tavaborole Alcohol impurity;2-Ethoxy-4-fluorobromobenzene;2-BROMO-5-FLUOROBENZYL ALCOHOL;2-Bromo-5-fluorobenzenemethanol;(2-Bromo-5-fluorophenyl)methanol;Benzenemethanol,2-bromo-5-fluoro-
- CBNumber:
- CB9670255
- Molecular Formula:
- C7H6BrFO
- Molecular Weight:
- 205.02
- MDL Number:
- MFCD00142876
- MOL File:
- 202865-66-5.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2-Bromo-5-fluorobenzyl alcohol 97% | 665827 | 5g | $184 |
| 2-Bromo-5-fluorobenzyl alcohol | B692103 | 250mg | $55 |
| 2-Bromo-5-fluorobenzyl alcohol | B692103 | 1g | $75 |
| (2-Bromo-5-fluorophenyl)methanol 95+% | 074527 | 5g | $82 |
| 2-Bromo-5-fluorobenzyl alcohol | J54027 | 25g | $40 |
| More product size | |||
| Melting point | 91-94 °C |
|---|---|
| Boiling point | 252.5±25.0 °C(Predicted) |
| Density | 1.658±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| pka | 13.67±0.10(Predicted) |
| form | Solid |
| color | Yellow |
| Water Solubility | Slightly soluble in water. |
| InChI | InChI=1S/C7H6BrFO/c8-7-2-1-6(9)3-5(7)4-10/h1-3,10H,4H2 |
| InChIKey | HXGZPMHPSBJMKB-UHFFFAOYSA-N |
| SMILES | C1(CO)=CC(F)=CC=C1Br |
| CAS DataBase Reference | 202865-66-5(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H335-H302-H319 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P405-P501a-P305+P351+P338 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi,Xn | |||||||||
| Risk Statements | 36/37/38-36-22 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| HS Code | 2906290090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Eye Irrit. 2 |
|||||||||
| NFPA 704 |
|
2-Bromo-5-fluorobenzyl alcohol price More Price(42)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 665827 | 2-Bromo-5-fluorobenzyl alcohol 97% | 202865-66-5 | 5g | $184 | 2023-06-20 | Buy |
| TRC | B692103 | 2-Bromo-5-fluorobenzyl alcohol | 202865-66-5 | 250mg | $55 | 2021-12-16 | Buy |
| TRC | B692103 | 2-Bromo-5-fluorobenzyl alcohol | 202865-66-5 | 1g | $75 | 2021-12-16 | Buy |
| Matrix Scientific | 074527 | (2-Bromo-5-fluorophenyl)methanol 95+% | 202865-66-5 | 5g | $82 | 2021-12-16 | Buy |
| AK Scientific | J54027 | 2-Bromo-5-fluorobenzyl alcohol | 202865-66-5 | 25g | $40 | 2021-12-16 | Buy |
2-Bromo-5-fluorobenzyl alcohol Chemical Properties,Uses,Production
Chemical Properties
Colorless liquid
Uses
2-Bromo-5-fluorobenzyl alcohol is used as intermediates in pharmaceutical and organic synthesis.
Synthesis
94569-84-3
202865-66-5
General procedure for the synthesis of 2-bromo-5-fluorobenzyl alcohol from 2-bromo-5-fluorobenzaldehyde: To a solution of 2-bromo-5-fluorobenzaldehyde (75.0 g, 369 mmol) in ethanol (375 mL) was slowly added a solution of sodium borohydride (4.47 g, 118 mmol) in water (9 mL) at 0 °C. The reaction mixture was kept stirred at 0°C for 1 hour. Upon completion of the reaction, the mixture was treated with water and ethyl acetate and extracted with ethyl acetate. The combined organic extracts were washed with saturated brine and dried over anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure to give 75.6 g of 2-bromo-5-fluorobenzyl alcohol (yield = 99.8%) as a colorless solid.1H NMR (CDCl3) δ 7.50-7.46 (1H, m), 7.29-7.25 (1H, m), 6.92-6.85 (1H, m), 4.72 (2H, s).
References
[1] Journal of Organic Chemistry, 2005, vol. 70, # 2, p. 756 - 759
[2] Patent: WO2007/19098, 2007, A2. Location in patent: Page/Page column 44
[3] Tetrahedron, 2007, vol. 63, # 38, p. 9401 - 9405
[4] Patent: CN108358961, 2018, A. Location in patent: Paragraph 0016; 0057; 0058-0060; 0062; 0069; 0071; 0078
[5] CrystEngComm, 2014, vol. 16, # 23, p. 4999 - 5011
2-Bromo-5-fluorobenzyl alcohol Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Blocksynth Pharmaceutical Technology Co.,Ltd | 0086-19817745290; +8619817745290 | bd@blocksynth.com | China | 5661 | 58 |
| Qi-Chem Co., Ltd. | +86-15633578820 +86-13591335396 | chris.wang@qi-chem.com | China | 133 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20128 | 58 |
| Capot Chemical Co.,Ltd. | +86-(0)57185586718; +8613336195806 | sales@capot.com | China | 29735 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13800 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21595 | 55 |
| Fluoropharm Co., Ltd. | +86-0571-85586753 +86-13336034509 | sales@fluoropharm.com | China | 1445 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29831 | 58 |
| Win-Win Chemical CO., Limited | 0086-577-64498589 | sales@win-winchemical.com | CHINA | 998 | 58 |
View Lastest Price from 2-Bromo-5-fluorobenzyl alcohol manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-02-05 | 2-Bromo-5-fluorobenzyl alcohol
202865-66-5
|
US $0.00 / KG Ton | 1KG Ton | 98%+ | 2 tons/month | ZHUHAI HRD PHARMACEUTICAL CO., LTD.
|
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2025-09-25 | 2-Bromo-5-fluorobenzyl alcohol
202865-66-5
|
US $5.00-0.10 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
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2025-04-04 | 2-Bromo-5-fluorobenzyl alcohol
202865-66-5
|
US $0.00-0.00 / KG | 1KG | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd.
|
-

- 2-Bromo-5-fluorobenzyl alcohol
202865-66-5
- US $0.00 / KG Ton
- 98%+
- ZHUHAI HRD PHARMACEUTICAL CO., LTD.
-

- 2-Bromo-5-fluorobenzyl alcohol
202865-66-5
- US $5.00-0.10 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-

- 2-Bromo-5-fluorobenzyl alcohol
202865-66-5
- US $0.00-0.00 / KG
- 98%
- Henan Aochuang Chemical Co.,Ltd.
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