ChemicalBook >> CAS DataBase List >>2-Bromo-5-fluorobenzyl alcohol

2-Bromo-5-fluorobenzyl alcohol

CAS No.
202865-66-5
Chemical Name:
2-Bromo-5-fluorobenzyl alcohol
Synonyms
CAS:202865-66-5;BUTTPARK 87\01-69;RARECHEM AL BD 0749;Tavaborole Intermediate;Tavaborole Alcohol impurity;2-Ethoxy-4-fluorobromobenzene;2-BROMO-5-FLUOROBENZYL ALCOHOL;2-Bromo-5-fluorobenzenemethanol;(2-Bromo-5-fluorophenyl)methanol;Benzenemethanol,2-bromo-5-fluoro-
CBNumber:
CB9670255
Molecular Formula:
C7H6BrFO
Molecular Weight:
205.02
MDL Number:
MFCD00142876
MOL File:
202865-66-5.mol
MSDS File:
SDS
Last updated:2026-01-13 11:27:07
Product description Number Pack Size Price
2-Bromo-5-fluorobenzyl alcohol 97% 665827 5g $184
2-Bromo-5-fluorobenzyl alcohol B692103 250mg $55
2-Bromo-5-fluorobenzyl alcohol B692103 1g $75
(2-Bromo-5-fluorophenyl)methanol 95+% 074527 5g $82
2-Bromo-5-fluorobenzyl alcohol J54027 25g $40
More product size

2-Bromo-5-fluorobenzyl alcohol Properties

Melting point 91-94 °C
Boiling point 252.5±25.0 °C(Predicted)
Density 1.658±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
pka 13.67±0.10(Predicted)
form Solid
color Yellow
Water Solubility Slightly soluble in water.
InChI InChI=1S/C7H6BrFO/c8-7-2-1-6(9)3-5(7)4-10/h1-3,10H,4H2
InChIKey HXGZPMHPSBJMKB-UHFFFAOYSA-N
SMILES C1(CO)=CC(F)=CC=C1Br
CAS DataBase Reference 202865-66-5(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H335-H302-H319
Precautionary statements  P261-P280a-P304+P340-P405-P501a-P305+P351+P338
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-36-22
Safety Statements  26-36
WGK Germany  3
Hazard Note  Irritant
HS Code  2906290090
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Eye Irrit. 2
NFPA 704
1
2 0

2-Bromo-5-fluorobenzyl alcohol price More Price(42)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 665827 2-Bromo-5-fluorobenzyl alcohol 97% 202865-66-5 5g $184 2023-06-20 Buy
TRC B692103 2-Bromo-5-fluorobenzyl alcohol 202865-66-5 250mg $55 2021-12-16 Buy
TRC B692103 2-Bromo-5-fluorobenzyl alcohol 202865-66-5 1g $75 2021-12-16 Buy
Matrix Scientific 074527 (2-Bromo-5-fluorophenyl)methanol 95+% 202865-66-5 5g $82 2021-12-16 Buy
AK Scientific J54027 2-Bromo-5-fluorobenzyl alcohol 202865-66-5 25g $40 2021-12-16 Buy
Product number Packaging Price Buy
665827 5g $184 Buy
B692103 250mg $55 Buy
B692103 1g $75 Buy
074527 5g $82 Buy
J54027 25g $40 Buy

2-Bromo-5-fluorobenzyl alcohol Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

Uses

2-Bromo-5-fluorobenzyl alcohol is used as intermediates in pharmaceutical and organic synthesis.

Synthesis

2-Bromo-5-fluorobenzaldehyde

94569-84-3

2-Bromo-5-fluorobenzyl alcohol

202865-66-5

General procedure for the synthesis of 2-bromo-5-fluorobenzyl alcohol from 2-bromo-5-fluorobenzaldehyde: To a solution of 2-bromo-5-fluorobenzaldehyde (75.0 g, 369 mmol) in ethanol (375 mL) was slowly added a solution of sodium borohydride (4.47 g, 118 mmol) in water (9 mL) at 0 °C. The reaction mixture was kept stirred at 0°C for 1 hour. Upon completion of the reaction, the mixture was treated with water and ethyl acetate and extracted with ethyl acetate. The combined organic extracts were washed with saturated brine and dried over anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure to give 75.6 g of 2-bromo-5-fluorobenzyl alcohol (yield = 99.8%) as a colorless solid.1H NMR (CDCl3) δ 7.50-7.46 (1H, m), 7.29-7.25 (1H, m), 6.92-6.85 (1H, m), 4.72 (2H, s).

References

[1] Journal of Organic Chemistry, 2005, vol. 70, # 2, p. 756 - 759
[2] Patent: WO2007/19098, 2007, A2. Location in patent: Page/Page column 44
[3] Tetrahedron, 2007, vol. 63, # 38, p. 9401 - 9405
[4] Patent: CN108358961, 2018, A. Location in patent: Paragraph 0016; 0057; 0058-0060; 0062; 0069; 0071; 0078
[5] CrystEngComm, 2014, vol. 16, # 23, p. 4999 - 5011

94569-84-3
202865-66-5
Synthesis of 2-Bromo-5-fluorobenzyl alcohol from 2-Bromo-5-fluorobenzaldehyde
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View Lastest Price from 2-Bromo-5-fluorobenzyl alcohol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromo-5-fluorobenzyl alcohol pictures 2026-02-05 2-Bromo-5-fluorobenzyl alcohol
202865-66-5
US $0.00 / KG Ton 1KG Ton 98%+ 2 tons/month ZHUHAI HRD PHARMACEUTICAL CO., LTD.
	2-Bromo-5-fluorobenzyl alcohol pictures 2025-09-25 2-Bromo-5-fluorobenzyl alcohol
202865-66-5
US $5.00-0.10 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
 2-Bromo-5-fluorobenzyl alcohol pictures 2025-04-04 2-Bromo-5-fluorobenzyl alcohol
202865-66-5
US $0.00-0.00 / KG 1KG 98% 1Ton Henan Aochuang Chemical Co.,Ltd.

2-Bromo-5-fluorobenzyl alcohol Spectrum

RARECHEM AL BD 0749 2-BROMO-5-FLUOROBENZYL ALCOHOL BUTTPARK 87\01-69 2-Ethoxy-4-fluorobromobenzene (2-Bromo-5-fluorophenyl)methanol 2-Ethoxy-4-fluorobroMobenzene[2-broMo-5-fluorophenetole] Benzenemethanol,2-bromo-5-fluoro- 2-Bromine-5-Fluoride Benzyl Alcohol Tavaborole Alcohol impurity 2-Bromo-5-fluorobenzyl alcohol ISO 9001:2015 REACH Tavaborole Intermediate 2-Bromo-5-fluorobenzenemethanol CAS:202865-66-5 202865-66-5 202865-66-9 202865-66-6 202865-66-7 202865-66-8 FC6H3BrCH2OH Alcohols Building Blocks C7 to C8 Oxygen Compounds Organic Building Blocks Fluorine series Alcohol Miscellaneous Alcohols Bromine Compounds Fluorine Compounds C7 to C8 Oxygen Compounds