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CIS-1,3-DICHLOROPROPENE

CAS No.
10061-01-5
Chemical Name:
CIS-1,3-DICHLOROPROPENE
Synonyms
(z)-1,3-dichloro-1-propene;cis-dcp;CIS-1,3-CHLOROPROPENE;3-dichloro-(z)-propen;CIS-1,3-DICHLOROPROPENE;1,3-CIS-DICHLOROPROPENE;(Z)-1,3-Dichloropropene;3-dichloro-(z)-1-propen;1,3-DICHLOROPROPENE(CIS);(1Z)-1,3-Dichloropropene
CBNumber:
CB9680157
Molecular Formula:
C3H4Cl2
Molecular Weight:
110.97
MDL Number:
MFCD00062949
MOL File:
10061-01-5.mol
MSDS File:
SDS
Last updated:2026-05-28 05:40:43
Product description Number Pack Size Price
cis-1,3-Dichloropropene 97% 377414 1ml $82.5
cis-1,3-Dichloropropene >98.0%(GC) D2792 25g $127
cis-1,3-Dichloropropene >95%(GC) TRC-C269680-5G 5g $218
cis-1,3-Dichloropropene >95%(GC) TRC-C269680-25G 25g $716
cis-1,3-Dichloropropene >95%(GC) TRC-C269680-10G 10g $349
More product size

CIS-1,3-DICHLOROPROPENE Properties

Melting point -50 °C
Boiling point 104 °C(lit.)
Density 1.225 g/mL at 25 °C(lit.)
vapor pressure 111.6 at 50 °C, 687.8 at 100 °C (Wilding et al., 2002)
refractive index n20/D 1.4675(lit.)
Flash point 75 °F
storage temp. 0-6°C
solubility Chloroform (Soluble), Methanol (Slightly)
form Oil
color Colourless
Water Solubility 1.071g/L(30 ºC)
Merck 14,3075
Henry's Law Constant 1.23 x 10-3 atmm3/molat 20 °C, 2.77 at 40 °C (static headspace-GC, Kim et al., 2003)
Exposure limits ACGIH TLV: TWA 1 ppm for cis and trans isomers (adopted).
Stability Stable. Flammable. Incompatible with strong oxidizing agents, aluminium and its alloys, active metals, halogens, some metal salts. May be light sensitive.
InChI 1S/C3H4Cl2/c4-2-1-3-5/h1-2H,3H2/b2-1-
InChIKey UOORRWUZONOOLO-UPHRSURJSA-N
SMILES ClC\C=C/Cl
LogP 1.82 at 20℃ and pH5.83-7.78
Surface tension 69.6mN/m at 976.8mg/L and 20.2℃
CAS DataBase Reference 10061-01-5(CAS DataBase Reference)
FDA UNII 411B9UAH6H
NIST Chemistry Reference 1-Propene, 1,3-dichloro-, (Z)-(10061-01-5)
EPA Substance Registry System cis-1,3-Dichloropropene (10061-01-5)
UNSPSC Code 12162002
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Skull and Crossbones (GHS06)Health Hazard (GHS08)Environment (GHS09)
GHS02,GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H226-H301+H311+H331-H304-H315-H317-H319-H335-H410
Precautionary statements  P210-P273-P280-P301+P310-P303+P361+P353-P331
target organs Respiratory system
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  T,N,F
Risk Statements  10-20/21-25-36/37/38-43-50/53-52/53-39/23/24/25-23/24/25-11-65-24/25-20
Safety Statements  36/37-45-60-61-16-7
RIDADR  UN 2047 3/PG 2
WGK Germany  3
RTECS  UC8325000
HazardClass  3.2
PackingGroup  III
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Asp. Tox. 1
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
Skin Sens. 1
STOT SE 3
Hazardous Substances Data 10061-01-5(Hazardous Substances Data)
Toxicity LC50 (96-hour) for bluegill sunfish 7.1 mg/L and rainbow trout 7.1 mg/L (Worthing and Hance, 1991); acute oral LD50 of the isomeric mixture for male and female rats is 713 and 470 mg/kg, respectively (Verschueren, 1983).
REACH Registrations Active

CIS-1,3-DICHLOROPROPENE price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 377414 cis-1,3-Dichloropropene 97% 10061-01-5 1ml $82.5 2026-04-30 Buy
TCI Chemical D2792 cis-1,3-Dichloropropene >98.0%(GC) 10061-01-5 25g $127 2023-01-07 Buy
TRC TRC-C269680-5G cis-1,3-Dichloropropene >95%(GC) 10061-01-5 5g $218 2026-06-03 Buy
TRC TRC-C269680-25G cis-1,3-Dichloropropene >95%(GC) 10061-01-5 25g $716 2026-06-03 Buy
TRC TRC-C269680-10G cis-1,3-Dichloropropene >95%(GC) 10061-01-5 10g $349 2026-06-03 Buy
Product number Packaging Price Buy
377414 1ml $82.5 Buy
D2792 25g $127 Buy
TRC-C269680-5G 5g $218 Buy
TRC-C269680-25G 25g $716 Buy
TRC-C269680-10G 10g $349 Buy

CIS-1,3-DICHLOROPROPENE Chemical Properties,Uses,Production

Chemical Properties

colourless to amber liquid

Chemical Properties

1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.

Physical properties

Clear, colorless to amber-colored liquid with a pungent and irritating, chloroform-like odor. Evaporates quickly when spilled. The average least detectable odor threshold concentration in water at 60 °C for mixed isomers of 1,3-dichloropropylene was 0.12 mg/L (Alexander et al., 1982).

Uses

The isomeric mixture is used as a soil fumigant and a nematocide.

Definition

ChEBI: The (Z)-isomer of 1,3-dichloropropene.

General Description

Colorless to amber liquid with a sweetish odor.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

CIS-1,3-DICHLOROPROPENE may be sensitive to light. Reacts with aluminum, aluminum alloys, other active metals and some metal salts and halogens. Can react vigorously with oxidizing materials.

Fire Hazard

Flash point data for CIS-1,3-DICHLOROPROPENE are not available, however literature sources indicate that CIS-1,3-DICHLOROPROPENE is flammable.

Safety Profile

Confirmed carcinogen with experimental neoplastigenic data. Human mutation data reported. A dangerous fire hazard when exposed to heat, flame, or oxidzers. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS , ALIPHATIC .

Potential Exposure

Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.

Environmental Fate

Biological. cis-1,3-Dichloropropylene was reported to hydrolyze to 3-chloro-2-propen- 1-ol and can be biologically oxidized to 3-chloropropenoic acid, which is further oxidized to formylacetic acid. Decarboxylation of this compound yields carbon dioxide (Connors et al., 1990). The isomeric mixture showed significant degradation with gradual adaptation in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was lost due to volatilization (Tabak et al., 1981).
Soil. Hydrolyzes in wet soil forming cis-3-chloroallyl alcohol (Castro and Belser, 1966).
Chemical/Physical. Hydrolyzes in distilled water at 25°C forming 2-chloro-3-propenol and hydrochloric acid. The half-life was 1 day (Milano et al., 1988; Kollig, 1993). Chloroacetaldehyde, formyl chloride and chloroacetic acid were formed from the ozonation of dichloropropylene at about 23°C and 730 mmHg. Chloroacetaldehyde and formyl chloride also formed from the reaction of dichloropropylene with hydroxyl radicals (Tuazon et al., 1984).
The evaporation half-life of cis-1,3-dichloropropylene (1 mg/L) from water at 25°C using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 29.6 minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic phosgene (Sittig, 1985).

Solubility in organics

Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene, and trichloroethylene.

Solubility in water

Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene, and trichloroethylene.

Shipping

UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.

Incompatibilities

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.

Waste Disposal

Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

107-05-1
10061-01-5
10061-02-6
Synthesis of CIS-1,3-DICHLOROPROPENE from Allyl chloride

CIS-1,3-DICHLOROPROPENE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from CIS-1,3-DICHLOROPROPENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(Z)-1,3-Dichloro-1-propene pictures 2020-02-07 (Z)-1,3-Dichloro-1-propene
10061-01-5
$9.80 1KG >98%HPLC 20 tons Career Henan Chemical Co

CIS-1,3-DICHLOROPROPENE Spectrum

cis-dcp Propene, 1,3-dichloro-, (Z)- CIS-3-CHLOROALLYL CHLORIDE CIS-1,3-DICHLORO-1-PROPENE CIS-1,3-DICHLOROPROPENE cis-1,3-Dichloropropene (1mg/ml in methanol) 1 3-DICHLOROPROPENE (ISOMERIC) 2000MG & 1,3-DICHLOROPROPENE,(ISOMERIC), 2000MG, NEAT CIS-1 3-DICHLOROPROPENE NEAT STANDARD & CIS-1,3-DICHLOROPROPENE, 100MG, NEAT cis-1,3-dichloropropene (technical) 1,3-CIS-DICHLOROPROPENE 1,3-DICHLOROPROPENE(CIS) CIS-1,3-CHLOROPROPENE 1,3-Dichlorpropen (cis u. trans) cis-1,3-dichloropropenesingle*componentstandard cis-1,3-Dichloropropylene cis-1,3-Dichloropropene  cis-1,3-Dichloropropene Standard cis-1,3-Dichloropropene (1mg/ml in Methanol) [for Water Analysis] Dichloropropene, cis-1,3- cis-1,3-Dichloropropene solution (1Z)-1,3-Dichloropropene (Z)-1,3-Dichloropropylene (Z)-3-Chloroallyl chloride (Z)-γ-Chloroallyl chloride (1Z)-1,3-Dichloro-1-propene (z)-1,3-dichloro-1-propene (Z)-1,3-Dichloropropene 3-dichloro-(z)-1-propen 3-dichloro-(z)-propen 1-Propene,1,3-dichloro-, (1Z)- cis-1,3-DichloropropyleneSolution,2,000mg/L,1ml cis-1,3-Dichloropropene> cis-1,3-Dichloropropene 10061-01-5 10061015 ClCH2CHCHCl Standard Solution of Volatile Organic Compounds for Water & Soil Analysis Standard Solutions (VOC) Alphabetic D DIA - DIC Monomers Polymer Science Vinyl Halides, Amines, Amides, and Other Vinyl Monomers Alpha Sort DAlphabetic Volatiles/ Semivolatiles Analytical Chemistry Standard Solution of Volatile Organic Compounds for Water & Soil Analysis Standard Solutions (VOC)