ChemicalBook >> CAS DataBase List >>2-Nitrophenylboronic acid
2-Nitrophenylboronic acid
- CAS No.
- 5570-19-4
- Chemical Name:
- 2-Nitrophenylboronic acid
- Synonyms
- 2-nitroborate;RARECHEM AH PB 0142;2-Borononitrobenzene;2-Nitrophenylboronic;Electronic materials;2-Nitrophenylboronicaci;2-NITROPHENYLBORONIC ACID;O-NITROPHENYLBORONIC ACID;2-NITROBENZENEBORONIC ACID;o-Nitrobenzeneboronic acid
- CBNumber:
- CB9689206
- Molecular Formula:
- C6H6BNO4
- Molecular Weight:
- 166.93
- MDL Number:
- MFCD00161358
- MOL File:
- 5570-19-4.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-07-08 07:26:47
| Product description | Number | Pack Size | Price |
| 2-Nitrophenylboronic acid ≥95% | 673862 | 1g | $64.4 |
| 2-Nitrophenylboronic acid ≥95% | 673862 | 5g | $260 |
| 2-Nitrophenylboronic Acid (contains varying amounts of Anhydride) | N0811 | 1g | $27 |
| 2-Nitrophenylboronic Acid (contains varying amounts of Anhydride) | N0811 | 5g | $90 |
| 2-Nitrophenylboronic acid Asreported | 285454 | 1g | $345 |
| More product size | |||
| Melting point | 155-160°C |
|---|---|
| Boiling point | 374.8±44.0 °C(Predicted) |
| Density | 1.40±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | soluble in Methanol,Ether,Ethanol |
| pka | 7.83±0.53(Predicted) |
| form | Crystalline Powder |
| color | White to off-white |
| BRN | 3032097 |
| InChI | InChI=1S/C6H6BNO4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4,9-10H |
| InChIKey | SFUIGUOONHIVLG-UHFFFAOYSA-N |
| SMILES | B(C1=CC=CC=C1[N+]([O-])=O)(O)O |
| CAS DataBase Reference | 5570-19-4(CAS DataBase Reference) |
| UNSPSC Code | 12352103 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P270-P301+P312-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22-36/37/38 | |||||||||
| Safety Statements | 26 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Harmful | |||||||||
| HS Code | 29319090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
2-Nitrophenylboronic acid price More Price(114)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 673862 | 2-Nitrophenylboronic acid ≥95% | 5570-19-4 | 1g | $64.4 | 2023-01-07 | Buy |
| Sigma-Aldrich | 673862 | 2-Nitrophenylboronic acid ≥95% | 5570-19-4 | 5g | $260 | 2022-05-15 | Buy |
| TCI Chemical | N0811 | 2-Nitrophenylboronic Acid (contains varying amounts of Anhydride) | 5570-19-4 | 1g | $27 | 2026-04-30 | Buy |
| TCI Chemical | N0811 | 2-Nitrophenylboronic Acid (contains varying amounts of Anhydride) | 5570-19-4 | 5g | $90 | 2026-04-30 | Buy |
| Usbiological | 285454 | 2-Nitrophenylboronic acid Asreported | 5570-19-4 | 1g | $345 | 2026-06-03 | Buy |
2-Nitrophenylboronic acid Chemical Properties,Uses,Production
Chemical Properties
White to orange to brown solid
Uses
Boronic acid catalyst used for:
- Mild and selective dipolar cycloadditions of unsaturated carboxylic acids with azides
- Transposition of allylic alcohols and Meyer-Schuster rearrangements
Reactant involved in:
- Suzuki-Miyaura cross-coupling reactions with aryl halides or nitroarenediazonium tetrafluoroborates
- Copper-catalyzed halogenation
- Oxidative arylation of aminopyrazolyl disulfides
Synthesis
98-80-6
5570-19-4
Using phenylboronic acid as starting material, nitric acid (126 g, 2 mol) and sodium nitrite (0.04 mol) were added dropwise to the reaction system and the reaction temperature was controlled at 45 °C. The reaction mixture was reacted with dimethylformamide (15 mol) under stirring conditions. Upon completion of the reaction, the mixture was poured completely into ice water, concentrated to a small volume, cooled and allowed to stand until a solid precipitate precipitated. The solid was separated by filtration and washed with ice water, and the final product 2-nitrophenylboronic acid 165.3 g was collected in 99.0% molar yield and >99.5% HPLC purity.
References
[1] Patent: CN104788484, 2017, B. Location in patent: Paragraph 0026-0039
[2] Patent: CN103214489, 2016, B. Location in patent: Paragraph 0061-0062
[3] Patent: US2005/192310, 2005, A1. Location in patent: Page/Page column 46
[4] Synlett, 2002, # 3, p. 477 - 479
[5] Journal of Organometallic Chemistry, 2003, vol. 680, # 1-2, p. 263 - 270
2-Nitrophenylboronic acid Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
Global( 355)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hainan Bonsen New Technology Co., LTD | +86-17384938934 +86-15310476930 | sales@newbs.com.cn | China | 45 | 58 |
| Hebei Xinsheng New Material Technology Co., LTD. | +86-16632316109 | xinshengkeji@xsmaterial.com | China | 1085 | 58 |
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-15225627621 +86-13213167925 | jiuyitime@fdachem.com | China | 16512 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21585 | 55 |
| Chembon Pharmaceutical Co., Ltd. | +86-28-8425-2981 | CHINA | 722 | 55 | |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29812 | 58 |
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10403 | 58 |
View Lastest Price from 2-Nitrophenylboronic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-07-20 | 2-Nitrophenylboronic acid
5570-19-4
|
0.99 | RongNa Biotechnology Co.,Ltd | ||||
 |
2026-07-10 | 2-Nitrophenylboronic acid
5570-19-4
|
1KG | 98% | 100KG | Hainan Bonsen New Technology Co., LTD | ||
 |
2026-07-02 | (2-Nitrophenyl)boronic acid
5570-19-4
|
$3.00-9.00 | 99% | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD |
-
- 2-Nitrophenylboronic acid
5570-19-4
- 0.99
- RongNa Biotechnology Co.,Ltd
-
- 2-Nitrophenylboronic acid
5570-19-4
- 98%
- Hainan Bonsen New Technology Co., LTD
-
- (2-Nitrophenyl)boronic acid
5570-19-4
- $3.00-9.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
5570-19-4(2-Nitrophenylboronic acid)Related Search:
RARECHEM AH PB 0142
O-NITROPHENYLBORONIC ACID
2-NITROPHENYLBORONIC ACID
2-NITROBENZENEBORONIC ACID
2-Borononitrobenzene
2-Nitrophenylboronic acid O2NC6H4B(OH)2
2-Borononitrobenzene~2-Nitrophenylboronic acid
2-Nitrophenylboronic Acid (contains varying amounts of Anhydride)
Boronic acid, B-(2-nitrophenyl)-
o-Nitrobenzeneboronic acid
2-Nitrophenylboronicacid(2NPBA)
2-nitroborate
2-Nitrophenylboronicaci
2-Nitrophenylboronic
2-Nitrophenylboronic acid diaminohexane
Electronic materials
2-Nitrophenylboronic acid, 98%
2-Nitrophenylboronic acid, 98%min
(2-Nitrophenyl)boronic acid - [N4760]
5570-19-4
135510-14-5
O2NC6H4BOH2
Aryl
Boronic Acids and Derivatives
Boronic Acids
Organometallic Reagents
Substituted Boronic Acids
Boronic acids
B (Classes of Boron Compounds)
Aryl
Boronic Acids
Boronic Acids and Derivatives
blocks
BoronicAcids
NitroCompounds
OLED
