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2-Chlorobenzoyl chloride

2-Chlorobenzoyl chloride structure

CAS No.: 609-65-4

Chemical Name:: 2-Chlorobenzoyl chloride

Synonyms: O-CHLOROBENZOYL CHLORIDE;OCOC;o-ChL;SKL750;orobenzoyL;o-Chlorobenzoylchlor;chlorobenzoylchloride;o-Chlorbenzoylchlorid;o-Chlorobenzoylchlorid;LABOTEST-BB LTBB000568

CBNumber:: CB9721544

Molecular Formula:: C7H4Cl2O

Molecular Weight:: 175.01

MDL Number:: MFCD00000660

MOL File:: 609-65-4.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 05:53:37

Product description	Number	Pack Size	Price
2-Chlorobenzoyl chloride 95%	103918	5g	$102
2-Chlorobenzoyl chloride 95%	103918	100g	$118
2-Chlorobenzoyl chloride for synthesis	8.21989	250ML	$56.1
2-Chlorobenzoyl Chloride >98.0%(GC)(T)	C0140	25mL	$24
2-Chlorobenzoyl Chloride >98.0%(GC)(T)	C0140	100mL	$37
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2-Chlorobenzoyl chloride Properties

Melting point	-4--3 °C (lit.)
Boiling point	238 °C (lit.)
Density	1.382 g/mL at 25 °C (lit.)
vapor pressure	0.1 hPa (20 °C)
refractive index	n20/D 1.572(lit.)
Flash point	>230 °F
storage temp.	Store below +30°C.
form	Liquid
color	Clear colorless to very slightly yellow
explosive limit	1.5-9.4%(V)
Water Solubility	Soluble in acetone, ether, and alcohol. Solubility in water it decomposes.
Sensitive	Moisture Sensitive
BRN	386435
InChI	1S/C7H4Cl2O/c8-6-4-2-1-3-5(6)7(9)10/h1-4H
InChIKey	ONIKNECPXCLUHT-UHFFFAOYSA-N
SMILES	ClC(=O)c1ccccc1Cl
CAS DataBase Reference	609-65-4(CAS DataBase Reference)
FDA UNII	JR29A4N74X
NIST Chemistry Reference	Benzoyl chloride, 2-chloro-(609-65-4)
EPA Substance Registry System	Benzoyl chloride, 2-chloro- (609-65-4)
UNSPSC Code	12352106
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS08

Signal word

Danger

Hazard statements

H314-H341-H290

Precautionary statements

P501-P202-P234-P201-P264-P280-P390-P308+P313-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P406-P405

PPE

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Codes

Risk Statements

Safety Statements

26-36/37/39-45-28A

RIDADR

UN 3265 8/PG 2

WGK Germany

19-21

Autoignition Temperature

600 °C

Hazard Note

Corrosive/Moisture Sensitive

TSCA

TSCA listed

HazardClass

PackingGroup

HS Code

29163900

Storage Class

8A - Combustible corrosive hazardous materials

Hazard Classifications

Eye Dam. 1
Skin Corr. 1B

Toxicity

LD50 orally in Rabbit: 3250 mg/kg

REACH Registrations

Active

NFPA 704

	1
3		0

2-Chlorobenzoyl chloride price More Price(26)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	103918	2-Chlorobenzoyl chloride 95%	609-65-4	5g	$102	2026-04-30	Buy
Sigma-Aldrich	103918	2-Chlorobenzoyl chloride 95%	609-65-4	100g	$118	2026-04-30	Buy
Sigma-Aldrich	8.21989	2-Chlorobenzoyl chloride for synthesis	609-65-4	250ML	$56.1	2026-04-30	Buy
TCI Chemical	C0140	2-Chlorobenzoyl Chloride >98.0%(GC)(T)	609-65-4	25mL	$24	2026-04-30	Buy
TCI Chemical	C0140	2-Chlorobenzoyl Chloride >98.0%(GC)(T)	609-65-4	100mL	$37	2026-04-30	Buy

Product number	Packaging	Price	Buy
103918	5g	$102	Buy
103918	100g	$118	Buy
8.21989	250ML	$56.1	Buy
C0140	25mL	$24	Buy
C0140	100mL	$37	Buy

2-Chlorobenzoyl chloride Chemical Properties,Uses,Production

Chemical Properties

clear colourless to very slightly yellow liquid

Uses

2-Chlorobenzoyl chloride, is used in organic synthesis. It is used as a pharmaceutical intermediate for eg as an intermediate of clotrimazolc, preparation of p-chlorobenzoic acid and production of trichloro-acaricide.

Definition

ChEBI: An acyl chloride consisting of benzoyl chloride having a chloro substituent in the ortho-position.

General Description

2-Chlorobenzoyl chloride reacts with aromatic amines and ammonium thiocyanate using polyethylene glycol-400 as the catalyst under the condition of solid-liquid phase-transfer catalysis to form N-aryl-N′(2-chlorobenzoyl) thioureas. 2-Chlorobenzoyl chloride causes the acylation of polystyrene during the preparation and regeneration of the polystyrene-based resin.

Synthesis

A process for preparing 2-chlorobenzoyl chloride which comprises reacting 2-chlorobenzaldehyde with chlorine in the presence of phosphorus pentachloride at a temperature of from 50° to 200° C. and wherein the 2-chlorobenzaldehyde: phosphorus pentachloride ratio is from 1:0.05 to 1:0.2. Phosphorus pentachloride (41.5 g, 0.2 mole) was added to 2-chlorobenzaldehyde (289.7 g, 2.0 mole, 97%). After the ensuing exotherm had subsided, the resulting red solution was heated to 160° C. A stream of chlorine was introduced through a sparge tube into the solution for six hours. (Gas chromatography indicated 96.5% conversion.) The solution was then cooled and distilled under reduced pressure, giving 325.4 grams of 2-chlorobenzoyl chloride, which boiled at 135° to 140° C. at 16 millimeters of mercury. The yield of 2-Chlorobenzoyl chloride was 93% (98.5% pure).

2-Chlorobenzoyl chloride synthesis

Synthesis of 2-Chlorobenzoyl chloride from 2-Chlorobenzoic acid

2-Chlorobenzoyl chloride Preparation Products And Raw materials

Raw materials

Benzyl chloride 2-Chlorobenzoic acid 1-Chloro-2-iodobenzene 1,2-DICHLOROTETRAMETHYLDISILANE 2-Chlorobenzhydrazide

4-Chlorobenzylamine

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Preparation Products

Clonazepam Clofentezine 2-Chlorobenzamide 3-(o-chlorophenyl)-3-hydroxy-3-phenylpropiononitrile 2-Chlorophenyl cyclopentyl ketone

2-Chloro-4'-fluorobenzophenone (2-Chlorophenyl)phenyl-methanone metaclazepam 2-Chlorobenzoic acid KETAMINE RELATED COMPOUND A (50 MG) (1 -[(2-CHLOROPHENYL)(METHYLIMINO)METHYL]CYLCOPENTA-NOL)

2'-Chloroacetophenone Clotrimazole chlorbenzuron Fenarimol 2-Chlorobenzyl alcohol

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2-Chlorobenzoyl chloride Suppliers

Global( 415)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	+8615350571055	Sibel@chuanghaibio.com	China	8738	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-86-13131129325 +8613131129325	sales1@chuanghaibio.com	China	5231	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21588	55
Shanxi Naipu Import and Export Co.,Ltd	+86-13734021967 +8613734021967	kaia@neputrading.com	China	1001	58
Xiamen AmoyChem Co., Ltd	+86-86-5926051114 +8615060885618	sales@amoychem.com	China	6366	58
HubeiwidelychemicaltechnologyCo.,Ltd	18627774460	faith@widelychemical.com	CHINA	742	58
Shanghai Longyu Biotechnology Co., Ltd.	+8619521488211	info@longyupharma.com	China	2501	58
Hebei shuoxi biotechnology co. LTD	+8613081092107		CHINA	964	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49979	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569262 +86-15003564040	1056@dideu.com	China	3971	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	58
Hebei Chuanghai Biotechnology Co,.LTD	58
Henan Tianfu Chemical Co.,Ltd.	55
Shanxi Naipu Import and Export Co.,Ltd	58
Xiamen AmoyChem Co., Ltd	58
HubeiwidelychemicaltechnologyCo.,Ltd	58
Shanghai Longyu Biotechnology Co., Ltd.	58
Hebei shuoxi biotechnology co. LTD	58
CONIER CHEM AND PHARMA LIMITED	58
Shaanxi Dideu Medichem Co. Ltd	58

View Lastest Price from 2-Chlorobenzoyl chloride manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-05-28	Chlorobenzoyl Chlorid Orobenzoyl 609-65-4	$19.00	1KG	99.%	10 ton	Hebei Chuanghai Biotechnology Co,.LTD
2026-03-20	2-Chlorobenzoyl chloride 609-65-4	$1.00	1KG	99%	10 mt	Hebei Chuanghai Biotechnology Co., Ltd
2023-09-11	2-Chlorobenzoyl chloride 609-65-4	$100.00	1drum	99	5000	Hebei Fengqiang Trading Co., LTD

Chlorobenzoyl Chlorid Orobenzoyl
609-65-4
$19.00
99.%
Hebei Chuanghai Biotechnology Co,.LTD

2-Chlorobenzoyl chloride
609-65-4
$1.00
99%
Hebei Chuanghai Biotechnology Co., Ltd

2-Chlorobenzoyl chloride
609-65-4
$100.00
99
Hebei Fengqiang Trading Co., LTD

2-Chlorobenzoyl chloride Spectrum

2-Chlorobenzoyl chloride(609-65-4)MS 2-Chlorobenzoyl chloride(609-65-4)¹HNMR 2-Chlorobenzoyl chloride(609-65-4)¹³CNMR 2-Chlorobenzoyl chloride(609-65-4)IR1 2-Chlorobenzoyl chloride(609-65-4)IR2 2-Chlorobenzoyl chloride(609-65-4)Raman

609-65-4(2-Chlorobenzoyl chloride)Related Search:

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2-Chlorobenzoic acid 3,5-Dichlorobenzoyl chloride Choline chloride Sodium chloride Ferric chloride

Potassium chloride Polyvinyl chloride 4-tert-Butylbenzoyl chloride

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2-Chlorobenzoyl chloride,98% 2-Chlorobenzoyl chloride ,99% o-Chlorobenzoylchlor o-Chlorobenzoylchlorid o-ChL orobenzoyL 2-chloro-benzoylchlorid Benzoyl chloride, o-chloro- Benzoylchloride,2-chloro- chlorobenzoylchloride OCOC o-Chlorobenzonyl chloride O-CHLOROBENZOYL CHLORIDE 2-CHLOROBENZOIC ACID CHLORIDE 2-CHLOROBENZOYL CHLORIDE LABOTEST-BB LTBB000568 2-Chlorobenzoyl Chloride o-Chlorobenzoyl Chloride Benzoyl chloride, 2-chloro- (9CI) 2-Chlorobenzoylchloride,97% 47) ORTHO CHLORO BENZOYL CHLORIDE o-Chlorbenzoylchlorid 2-Chlorobenzoyl Chloride > 2-CHLOROBENZOYL CHLORIDE FOR SYNTHESIS 2-Chlorobenzoyl chloride ISO 9001：2015 REACH 2-Chlorobenzoly chloride SKL750 Chlorobenzoyl Chlorid Orobenzoyl TIANFUCHEM--High purity 2-Chlorobenzoyl chloride factory price 609-65-4 609-65-43 ClC6H4COCl ACID CHLORIDE Organic Building Blocks Acid Halides Building Blocks Carbonyl Compounds Pyridines ,Halogenated Heterocycles Organic Building Blocks Acid Halides Carbonyl Compounds Aromatic Halides (substituted) ACIDHALIDE 609-65-4 YP00036