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2-Chloropropene

CAS No.
557-98-2
Chemical Name:
2-Chloropropene
Synonyms
2-CHLOROPROP-1-ENE;2-CHLORO-1-PROPENE;2-chloro-propen;2-CHLOROPROPENE;2-Chlor-1-propen;propene,2-chloro-;2-chloro-1-propen;2-Chloropropene-1;β-Chloropropylene;2-CHLOROPROPYLENE
CBNumber:
CB9853829
Molecular Formula:
C3H5Cl
Molecular Weight:
76.52
MDL Number:
MFCD00000859
MOL File:
557-98-2.mol
MSDS File:
SDS
Last updated:2026-04-10 10:27:34
Product description Number Pack Size Price
2-Chloropropene 98% 254355 5g $38.2
2-Chloro-1-propene >97.0%(GC) C1112 10mL $85
2-Chloropropene 7029AF 10ml $272
2-Chloro-1-propene FC00923 5G $300
2-Chloro-1-propene FC00923 10g $400
More product size

2-Chloropropene Properties

Melting point -138 °C
Boiling point 23 °C
Density 0.91
refractive index n20/D 1.395(lit.)
Flash point -20°C
storage temp. 2-8°C
form clear liquid
color Colorless to Almost colorless
Water Solubility Not miscible or difficult to mix in water.
BRN 1361376
Henry's Law Constant 1.4×10-4 mol/(m3Pa) at 25℃, HSDB (2015)
InChI InChI=1S/C3H5Cl/c1-3(2)4/h1H2,2H3
InChIKey PNLQPWWBHXMFCA-UHFFFAOYSA-N
SMILES C=C(Cl)C
CAS DataBase Reference 557-98-2(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 50TXN55E4A
EPA Substance Registry System 2-Chloropropene (557-98-2)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Danger
Hazard statements  H319-H224
Precautionary statements  P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P303+P361+P353-P403+P235
target organs Respiratory system
PPE Eyeshields, Faceshields, Gloves
Hazard Codes  F+,Xi
Risk Statements  12-36/37
Safety Statements  16-26-36
RIDADR  UN 2456
WGK Germany  3
RTECS  UC7200000
10-23
TSCA  TSCA listed
HazardClass  3
PackingGroup  I
HS Code  2903290000
Storage Class 3 - Flammable liquids
Hazard Classifications Eye Irrit. 2
Flam. Liq. 1
STOT SE 3
Hazardous Substances Data 557-98-2(Hazardous Substances Data)
Limited Quantities 0.5 L (0.1 gallon)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (300g or 300ml)
NFPA 704
4
2 1

2-Chloropropene price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 254355 2-Chloropropene 98% 557-98-2 5g $38.2 2024-03-01 Buy
TCI Chemical C1112 2-Chloro-1-propene >97.0%(GC) 557-98-2 10mL $85 2026-04-30 Buy
AK Scientific 7029AF 2-Chloropropene 557-98-2 10ml $272 2021-12-16 Buy
Biosynth Carbosynth FC00923 2-Chloro-1-propene 557-98-2 5G $300 2021-12-16 Buy
Biosynth Carbosynth FC00923 2-Chloro-1-propene 557-98-2 10g $400 2021-12-16 Buy
Product number Packaging Price Buy
254355 5g $38.2 Buy
C1112 10mL $85 Buy
7029AF 10ml $272 Buy
FC00923 5G $300 Buy
FC00923 10g $400 Buy

2-Chloropropene Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

2-Chloropropene is used in measurement of photoionization cross sections of allyl and 2-propenyl radicals to form C3H5+ by tunable vacuum ultraviolet synchrotron radiation coupled with photofragment translational spectroscopy.

Preparation

1,2-Propadiene adds hydrogen chloride to yield 2-chloropropene. One early synthesis involves dehydrohalogenation of 1,2-dichloropropane with potassium hydroxide.

General Description

2-chloropropene appears as a clear colorless volatile liquid. Less dense than water and insoluble in water. Vapors heavier than air.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Halogenated aliphatic compounds, such as 2-Chloropropene, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Low molecular weight haloalkenes are highly flammable, peroxidizable and may polymerize violently. They may react violently with aluminum. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Mildly toxic by inhalation. Mutation data reported. Very dangerous fire hazard when exposed to heat, flame, sparks, or powerful oxidizers. To fight fire, use water, spray, mist, fog, dry chemical, alcohol foam. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORIDES.

5281-20-9
67-64-1
557-98-2
Synthesis of 2-Chloropropene from acetone hydrazone and Acetone
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View Lastest Price from 2-Chloropropene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Chloropropene pictures 2026-03-20 2-Chloropropene
557-98-2
US $10.00 / KG 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
2-Chloropropene pictures 2023-07-27 2-Chloropropene
557-98-2
US $1.10 / g 1g 99.0% Min 100 Tons Shaanxi Didu New Materials Co. Ltd
  • 2-Chloropropene pictures
  • 2-Chloropropene
    557-98-2
  • US $10.00 / KG
  • 99%
  • Hebei Chuanghai Biotechnology Co., Ltd
  • 2-Chloropropene pictures
  • 2-Chloropropene
    557-98-2
  • US $1.10 / g
  • 99.0% Min
  • Shaanxi Didu New Materials Co. Ltd
1-Methylvinylchloride 1-propene,2-chloro- 2-Chlor-1-propen 2-chloro-1-propen 2-chloro-propen 2-Chloropropene-1 beta-Chloropropene beta-Chloropropylene Propene, 2-chloro- 2-Chloroprop-1-ene99% propene,2-chloro- β-Chloropropylene 2-CHLORO-1-PROPENE 2-CHLOROPROP-1-ENE 2-CHLOROPROPENE 2-CHLOROPROPYLENE 2-Chloropropene,98% ISOPROPENYL CHLORIDE 2-Chloro-1-propene, Isopropenyl chloride 2-Chloroprop-1-ene 99% 2-Chloropropene, 99,6% 2-Chloro-1-propene > 2-Chloropropene in methanol 557-98-2 CH3CClCH2 Organic Building Blocks Alkenyl Environmental Standards Chromatography Halogenated Hydrocarbons Volatiles/ Semivolatiles Building Blocks Analytical Standards Analytical Chromatography Product Catalog Alkyl