Bismuth(III) trifluoromethanesulfonate
- CAS No.
- 88189-03-1
- Chemical Name:
- Bismuth(III) trifluoromethanesulfonate
- Synonyms
- Bi(OTf)3;BISMUTH TRIFLATE;Bismuth trifluoromethanesulfonate;BISMUTH(III)TRIFLATE;BISMUTH(III)TRIFLUOROMETHANESULPHONATE;BisMuth(Ⅲ) trifluoroMethanesulfonate;Bismuth(III) trifluoromethanesulfonat;BISMUTH(III) TRIFLUOROMETHANESULFONATE;Bismuth tris(trifluoromethanesulfonate);Trifluoromethanesulfonicacidbismuthsalt
- CBNumber:
- CB9854538
- Molecular Formula:
- 3CF3O3S.Bi
- Molecular Weight:
- 656.18
- MDL Number:
- MFCD08272314
- MOL File:
- 88189-03-1.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 300 °C |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide. |
| form | Liquid |
| color | Clear colorless |
| Sensitive | Hygroscopic |
| Hydrolytic Sensitivity | 5: forms reversible hydrate |
| Stability | hygroscopic |
| InChI | InChI=1S/3CHF3O3S.Bi/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3 |
| InChIKey | HIYUMYXSGIKHHE-UHFFFAOYSA-M |
| SMILES | C(F)(S([O-])(=O)=O)(F)F.C(F)(F)(F)S([O-])(=O)=O.C(F)(F)(F)S([O-])(=O)=O.[Bi+3] |
| FDA UNII | 51KD8E1741 |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335-H314-H318 | |||||||||
| Precautionary statements | P280-P303+P361+P353-P310-P261-P305+P351+P338 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-24/25 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | No | |||||||||
| HazardClass | 8 | |||||||||
| HS Code | 29049090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| NFPA 704 |
|
Bismuth(III) trifluoromethanesulfonate price More Price(45)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 633305 | Bismuth(III) trifluoromethanesulfonate | 88189-03-1 | 5g | $107 | 2026-04-30 | Buy |
| Sigma-Aldrich | 633305 | Bismuth(III) trifluoromethanesulfonate | 88189-03-1 | 25g | $183 | 2026-04-30 | Buy |
| Strem Chemicals | 83-8000 | Bismuth(III) trifluoromethanesulfonate, min. 98% (Bismuth triflate) min.98% | 88189-03-1 | 1g | $32 | 2026-04-30 | Buy |
| Strem Chemicals | 83-8000 | Bismuth(III) trifluoromethanesulfonate, min. 98% (Bismuth triflate) min.98% | 88189-03-1 | 5g | $59 | 2026-04-30 | Buy |
| Strem Chemicals | 83-8000 | Bismuth(III) trifluoromethanesulfonate, min. 98% (Bismuth triflate) min.98% | 88189-03-1 | 25g | $233 | 2026-04-30 | Buy |
Bismuth(III) trifluoromethanesulfonate Chemical Properties, Uses, Production
Uses
Bismuth(III) trifluoromethanesulfonate is powerful Lewis acid useful in a number of catalytic reactions.
Chemical Properties
White powder
Uses
Catalyst for organic syntheses.
Uses
Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.
Uses
Catalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides.
reaction suitability
core: bismuth
reagent type: catalyst
Bismuth(III) trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Chang-Gen Chemical Technology Co., Ltd. | 021-69106814 13917161715 | 3007500651@qq.com | China | 80 | 60 |
| Shanghai Jiahua Herong Biotechnology Co., Ltd | 18916155073 | market@trustwe.com | China | 203 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Pure Chemistry Scientific Inc. | 001-857-928-2050 or 1-888-588-9418 | sales@chemreagents.com | United States | 10174 | 62 |
| Nanjing Chemlin Chemical Co., Ltd | 025-83697070 13770331960 | info@chemlin.com.cn | China | 16305 | 64 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Sichuan Kulinan Technology Co., Ltd | 400-1166-196 18981987031 | cdhxsj@163.com | China | 11674 | 57 |
View Latest Price from Bismuth(III) trifluoromethanesulfonate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-03-20 | Bismuth(III) trifluoromethanesulfonate
88189-03-1
|
$10.00 | 1KG | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd |
-
- Bismuth(III) trifluoromethanesulfonate
88189-03-1
- $10.00
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
