Methyl 5-nitro-2-methylbenzoate
- CAS No.
- 77324-87-9
- Chemical Name:
- Methyl 5-nitro-2-methylbenzoate
- Synonyms
- Methyl 2-methyl-5-nitrobenzoate;Methyl 5-nitro-2-met;Methyl 5-Nitro-o-toluate;Lenalidomide Impurity 57;Methyl 5-nitro-2-methylbenzoate;Methyl2-Methyl-5-nitrobenzoate>5-Nitro-o-toluic acid methyl ester;o-Toluic acid, 5-nitro-, methyl ester;Methyl 2-methyl-5-nitrobenzoate, 98%,;5-Nitro-o-toluicacidmethylester(COOCH3=1)
- CBNumber:
- CB9855131
- Molecular Formula:
- C9H9NO4
- Molecular Weight:
- 195.17
- MDL Number:
- MFCD00230865
- MOL File:
- 77324-87-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| Methyl 2-Methyl-5-nitrobenzoate >98.0%(GC) | M2220 | 5g | $22 |
| Methyl 2-Methyl-5-nitrobenzoate >98.0%(GC) | M2220 | 25g | $71 |
| Methyl 5-nitro-2-methylbenzoate Asreported | 283490 | 10g | $368 |
| Methyl 5-nitro-2-methylbenzoate Asreported | 283490 | 25g | $509 |
| Methyl 5-nitro-2-methylbenzoate Asreported | 283490 | 50g | $694 |
| More product size | |||
| Melting point | 67.0 to 71.0 °C |
|---|---|
| Boiling point | 305.4±22.0 °C(Predicted) |
| Density | 1+-.0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | soluble in Methanol |
| form | powder to crystal |
| color | Light orange to Yellow to Green |
| CAS DataBase Reference | 77324-87-9(CAS DataBase Reference) |
Methyl 5-nitro-2-methylbenzoate price More Price(69)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | M2220 | Methyl 2-Methyl-5-nitrobenzoate >98.0%(GC) | 77324-87-9 | 5g | $22 | 2026-04-30 | Buy |
| TCI Chemical | M2220 | Methyl 2-Methyl-5-nitrobenzoate >98.0%(GC) | 77324-87-9 | 25g | $71 | 2026-04-30 | Buy |
| Usbiological | 283490 | Methyl 5-nitro-2-methylbenzoate Asreported | 77324-87-9 | 10g | $368 | 2026-06-03 | Buy |
| Usbiological | 283490 | Methyl 5-nitro-2-methylbenzoate Asreported | 77324-87-9 | 25g | $509 | 2026-06-03 | Buy |
| Usbiological | 283490 | Methyl 5-nitro-2-methylbenzoate Asreported | 77324-87-9 | 50g | $694 | 2026-06-03 | Buy |
Methyl 5-nitro-2-methylbenzoate Chemical Properties,Uses,Production
Chemical Properties
White crystalline powder
Synthesis
1975-52-6
74-88-4
77324-87-9
4.2.1 Synthesis of methyl 2-methyl-5-nitrobenzoate (2): 2-methyl-5-nitrobenzoic acid (15 g, 82.8 mmol) and potassium carbonate (K2CO3, 17.2 g, 124.2 mmol) were suspended in N,N-dimethylformamide (DMF, 75 mL) in a dry round-bottom flask. To this suspension, iodomethane (6.7 mL) was slowly added dropwise at room temperature. The reaction mixture was stirred at room temperature overnight (~12 hours). After completion of the reaction, the mixture was poured into water (500 mL) and the aqueous phase was extracted three times with ethyl acetate (EA). The organic phases were combined, dried with anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure to give methyl 2-methyl-5-nitrobenzoate (15.3 g, 94% yield) as a yellow solid. The product was confirmed by 1H NMR (400 MHz, CDCl3): δ 8.52 (s, 1H), 8.05 (s, 1H), 7.30 (s, 1H), 3.83 (s, 3H), 2.56 (s, 3H). ESI-MS analysis showed m/z 196 [M + H]+.
References
[1] Journal of the American Chemical Society, 2003, vol. 125, # 40, p. 12074 - 12075
[2] Patent: US6344465, 2002, B1. Location in patent: Page column 32
[3] Bioorganic and Medicinal Chemistry, 2015, vol. 23, # 17, p. 5881 - 5890
[4] Patent: US2005/43385, 2005, A1. Location in patent: Page/Page column 14
[5] Patent: US2001/34343, 2001, A1
Methyl 5-nitro-2-methylbenzoate Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20111 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29626 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29766 | 58 |
| CONIER CHEM AND PHARMA LIMITED | sales@conier.com | China | 49906 | 58 | |
| Fuxin Pharmaceutical | +86-021-021-50872116 | contact@fuxinpharm.com | China | 9976 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17339 | 58 |
| Jinan Qinmu Fine Chemical Co.,Ltd. | 18660799346 | sales@qinmuchem.com | China | 1006 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14301 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-81139210 +86-17392587031 | 1059@dideu.com | China | 9984 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 17705817739 | info@dycnchem.com | China | 52693 | 58 |
View Lastest Price from Methyl 5-nitro-2-methylbenzoate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-26 | Methyl 5-nitro-2-methylbenzoate
77324-87-9
|
$1.00-100.00 | 1KG | 99% | Henan Fengda Chemical Co., Ltd | ||
 |
2026-06-30 | Methyl 5-nitro-2-methylbenzoate
77324-87-9
|
1KG | 99.0% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd | ||
 |
2020-02-26 | Methyl 2-Methyl-5-nitrobenzoate
77324-87-9
|
1KG | 99.0% | 100 tons | Shaanxi Dideu Medichem Co. Ltd |
-
- Methyl 5-nitro-2-methylbenzoate
77324-87-9
- $1.00-100.00
- 99%
- Henan Fengda Chemical Co., Ltd
-
- Methyl 5-nitro-2-methylbenzoate
77324-87-9
- 99.0%
- Shaanxi Dideu New Materials Co. Ltd
-
- Methyl 2-Methyl-5-nitrobenzoate
77324-87-9
- 99.0%
- Shaanxi Dideu Medichem Co. Ltd
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