1-ニトロピレン 化学特性,用途語,生産方法
外観
わずかにうすい黄色～橙色、結晶性粉末～粉末
説明
1-Nitropyrene (1-NP) is a nitro-polycyclic aromatic hydrocarbon
(PAH) and a byproduct of incomplete combustion
product from stationary combustion sources and in vehicle
exhaust fumes.
化学的特性
1-Nitropyrene is a synthetic, light sensitive, yellow to orange-brown crystalline solid that is practically insoluble in water and soluble in diethyl ether, acetone, ethanol, benzene and toluene. It is not used for any commercial applications and is used only for research purposes, principally as a marker for exposure to nitro-polycyclic aromatic hydrocarbons from diesel exhaust.
定義
ChEBI: 1-nitropyrene is a nitroarene that is pyrene substituted at the 1-position by a nitro group. A by-product of combustion, it is the predominant nitrated polycyclic aromatic hydrocarbon emitted in a diesel engine. It has a role as a carcinogenic agent. It derives from a hydride of a pyrene.
製造方法
The synthesis of 1-nitropyrene by heating pyrene with nitric acid in acetic acid at 50 °C (Boit, 1965). 1-Nitropyrene was also produced in a mixture with dinitropyrenes following the addition of potassium nitrite to pyrene in diethyl ether (Prager & Jacobson, 1922).
主な応用
1-Nitropyrene has been reported to use as a chemical photosensitizer in photocopy toners. It is available for research purposes as a reference material with different purities.
一般的な説明
Yellow needles or prisms (from ethanol).
空気と水の反応
Insoluble in water.
反応プロフィール
1-Nitropyrene may be sensitive to prolonged exposure to light. Reacts with ethanolic potassium hydroxide. Also reacts with zinc powder and ethanol with catalytic amounts of ammonium chloride or ammonia .
健康ハザード
ACUTE/CHRONIC HAZARDS: When heated to decomposition 1-Nitropyrene emits toxic fumes of NOx.
火災危険
Flash point data for 1-Nitropyrene are not available; however, 1-Nitropyrene is probably combustible.
発がん性
1-Nitropyrene is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.
環境運命予測
1-NP creates yellow needles in ethanol, and it has a melting
point of 155 ℃. It is partially insoluble in water (0.02 mg l
-1,
25 ℃); very soluble in diethyl ether; and soluble in acetone,
ethanol, benzene, toluene, and tetrahydrofluorenone.
1-NP upon an estimated Koc value (soil adsorption coefficient
normalized to the content of organic carbon) of 13 500 is
immobile in soil and adsorb to sediment and solids from
water. According to Henry’s law constant of 2.5× 10
-8 atmcum
mol1 and vapor pressure (8.3 ×10
-8 mmHg at 25℃)
volatilization from moist soil surfaces and water is not an
important fate process. It is expected to exist solely in the
particulate phase in the ambient atmosphere. Adsorptions to
the particulate phase cause occurring photolysis in lower rate
and decompose by wet and dry deposition. An estimated bioconcentration
factor of 4100 suggests that its concentration in
aquatic organisms is very high.
1-ニトロピレン 上流と下流の製品情報
原材料
準備製品