エチルアルミニウムジクロリド 化学特性,用途語,生産方法
外観
無色～うすい黄色～うすい黄赤色透明液体
溶解性
水, アルコールにより分解。炭化水素, エーテルに易溶。ヘキサン及びベンゼンと任意の割合で混和するが、水及びエタノールには分解する。
解説
ジクロロエチルアルミニウム．塩化エチル，アルミニウム，三塩化アルミニウムの混合物を加熱すると得られる．あるいはトリクロロトリエチルジアルミニウムと三塩化アルミニウムとをヨウ化エチルの存在下に加熱しても合成することができる．無色の結晶性固体．融点32 ℃，沸点100 ℃(4 kPa)．d250 1.232．粘度3.18 cP．有機溶媒に可溶．空気と水で分解する．液相では二量化している．オレフィンの重合や芳香族化合物の水素化の触媒として用いられる．
用途
有機合成用試薬。
使用上の注意
本品を採取する場合は、よく乾燥して窒素を充填した注射器等を用いること。不活性ガス封入
化学的特性
The aluminum alkyl halides are flammable, reactive, and may be spontaneously combustible in air. They are colorless to yellow liquids. Ethylaluminum dichloride:(563-43-9):
使用
Ethylaluminum dichloride is used as a catalyst component in the polyolefin industry, for the synthesis of synthetic rubbers and for the dimerisation of olefins. It is also employed as a catalyst for Friedel-Crafts acylations.
一般的な説明
A colorless to light-yellow heated liquid. Freezing point 90°F.
空気と水の反応
Highly flammable. Ignites when exposed to air. Reacts violently with water or moisture in air forming hydrogen chloride fumes and flammable ethane gas (Rose 1961).
反応プロフィール
Organometallics, such as ETHYLALUMINUM DICHLORIDE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Organometallics containing halogens (fluorine, chlorine, bromine, iodine) bonded to the metal typically with generate gaseous hydrohalic acids (HF, HCl, HBr, HI) with water.
危険性
Ignites on contact with air, dangerous fire
risk, reacts violently with water. Skin irritant.
健康ハザード
Inhalation of smoke from fire causes metal-fume fever (flu-like symptoms); acid fumes irritate nose and throat. Contact with liquid (which is spontaneously flammable) causes severe burns of eyes and skin.
職業ばく露
These materials are used as components of olefin polymerization catalysts. The reader is referred to the entry on “Aluminum alkyls” for additional information on this entry. The aluminum alkyl halides parallel very closely the aluminum alkyls
輸送方法
UN3052 Spontaneously combustible. Water reactive releasing large quantities of toxic and deadly hydrogen gas. (Note: this number does not appear in the 49/CFR HazMat tables)
不和合性
The aluminum alkyl halides are strong reducing agents; they react—possibly violently—with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. These chemicals react violently with nitromethaneEthylaluminum sesquichloride reacts explosively with carbon tetrachloride at room temperature. This chemical reacts violently with water, forming corrosive hydrogen chloride and flammable ethane gas. Diethylaluminum chloride may form an explosive product with chlorine azide.
エチルアルミニウムジクロリド 上流と下流の製品情報
原材料
準備製品