4-エチル安息香酸 化学特性,用途語,生産方法
外観
白色～うすい黄褐色、結晶性粉末～粉末
化学的特性
It is a white to beige powder with a melting point of 112-113℃. It is not soluble in water, but can be dissolved in benzene and toluene.
使用
4-Ethylbenzoic acid was used in the synthesis of ethyl 4-vinyl-α-cyano-β-phenylcinnamate. It was also used to functionalize the edge of “pristine” graphite in the presence of polyphosphoric acid/phosphorus pentoxide.
主な応用
4-Ethylbenzoic acid has various applications such as being used as an intermediate in the production of pesticide insecticides, including tebufenozide and methoxyfenozide, as well as an initiator of carbon nanotube materials. Additionally, it can also use as an intermediate in the production of liquid crystals.
製造方法
The preparation of 4-ethylbenzoic acid can be done in the following steps:
1. Add ethylbenzene and trichloroacetaldehyde in the reaction kettle.
2. Add anhydrous aluminum trichloride in batches at 0 °C.
3. Stir and react at -10 ~ 0 °C for 2 hours after the addition.
4. Add dilute hydrochloric acid to the mixed solution to decompose the remaining aluminum trichloride.
5. Wash with NaHCO3 and water.
6. Distill the organic layer to recover ethylbenzene.
7. Distill to obtain p-ethylbenzene-2,2,2-trichloroethanol.
8. Dissolve the trichloroethanol in methanol.
9. Add NaOH solution and stir.
10. Add dropwise 30% hydrogen peroxide aqueous solution to the mixture.
11. Stir until the trichloroethanol disappears.
12. Acidify with HCl to obtain crystalline 4-ethylbenzoic acid.
一般的な説明
4-Ethylbenzoic acid reacts with lanthanum nitrate in aqueous solution to yield the polymer c
atena-poly[[aqua(4-ethylbenzoic acid-
κO)lanthanum(III)]-tri-μ-4-ethylbenzoato].
4-エチル安息香酸 上流と下流の製品情報
原材料
準備製品