ニオブ(III)トリクロリド 化学特性,用途語,生産方法
製造方法
High-surface Nb metal (e.g., foil) and a slight excess of NbCl5 are placed in an evacuated reactor tube which is then sealed. The sealed horizontal reactor is heated for three days in a temperature gradient such that the end of the tube containing Nb is at 390℃, while the remainder of the tube is at 355℃. The contents are thus converted to NbCl3, which, as a result of the reversible equilibrium NbCl3 (solid) + NbCl5 (gas) = 2NbCl4 (gas), is transported into the 355℃ zone where it deposits as crystals. It can then be resublimed by reversing the temperature gradient. At the end of the procedure, only the part of the tube containing the NbCl3 is heated for a few minutes to 390°C while keeping the other end at 20℃, thus driving the NbCl5 to the cold end. The tube is allowed to cool and is then opened under anhydrous conditions.
ニオブ(III)トリクロリド 上流と下流の製品情報
原材料
準備製品