Diethyl ketomalonate
|
|
Diethyl ketomalonate 속성
- 녹는점
- -70°C
- 끓는 점
- 208-210 °C (lit.)
- 밀도
- 1.142 g/mL at 25 °C (lit.)
- 굴절률
- n
20/D 1.415
- 인화점
- >230 °F
- 저장 조건
- Inert atmosphere,Room Temperature
- 용해도
- 클로로포름(약간 용해됨), 메탄올
- 물리적 상태
- 액체
- 색상
- 녹색-노란색
- Specific Gravity
- 1.142
- 수용성
- 물과 완전히 섞입니다.
- 감도
- Moisture Sensitive
- Merck
- 14,5913
- BRN
- 971873
- InChI
- 1S/C7H10O5/c1-3-11-6(9)5(8)7(10)12-4-2/h3-4H2,1-2H3
- InChIKey
- DBKKFIIYQGGHJO-UHFFFAOYSA-N
- SMILES
- CCOC(=O)C(=O)C(=O)OCC
- CAS 데이터베이스
- 609-09-6(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | Xi | ||
|---|---|---|---|
| 안전지침서 | 24/25 | ||
| WGK 독일 | 3 | ||
| F 고인화성물질 | 21 | ||
| 위험 참고 사항 | Irritant | ||
| TSCA | TSCA listed | ||
| 위험 등급 | IRRITANT, MOISTURE SENSITIVE | ||
| HS 번호 | 29183000 | ||
| 스토리지 클래스 | 10 - Combustible liquids | ||
| 기존화학 물질 | KE-27648 |
Diethyl ketomalonate C화학적 특성, 용도, 생산
화학적 성질
Clear yellow liquid용도
Diethyl ketomalonate, reagent employed in Wittig and Aza-Wittig reactions for synthesis of triazoles, and 2-azadienes, respectively.주요 응용
Diethyl ketomalonate can be used in electron-deficient heterodienophile; Diels-Alder reaction; heterodipolarophile; [3 + 2] cycloaddition; 1,3-diyl trapping agent; 1,4-dipolar cycloaddition; [2 + 2] cycloaddition; enophile; ene reaction; electrophilic addition; Wittig reactions; condensation with amines; Pictet-Spengler reactions.Synthesis Reference(s)
Synthetic Communications, 24, p. 695, 1994 DOI: 10.1080/00397919408012648The Journal of Organic Chemistry, 46, p. 2598, 1981 DOI: 10.1021/jo00325a039
저장
Diethyl ketomalonate is stable for at least 6 months if stored in the refrigerator.Diethyl ketomalonate 준비 용품 및 원자재
원자재
준비 용품
Diethyl isopropylidenemalonate
에틸6,7-디클로로-3,4-디히드로-3-옥소-2-퀴녹살린카르복실레이트
4-ethoxy-3-(ethoxycarbonyl)-4-oxobut-2-enoic acid
ETHYL 3-(4-CHLOROPHENYL)-5-HYDROXY-1,2,4-TRIAZINE-6-CARBOXYLATE
ethyl 5-oxo-3-phenyl-2H-1,2,4-triazine-6-carboxylate
6-Phenylisatin
ethyl 6-bromo-3-hydroxy-5-methylpyrazine-2-carboxylate
2-(2,5-디메틸페닐)-2-수산화아세트산
Diethyl ketomalonate 공급 업체
글로벌( 350)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 |
sales@capot.com | China | 29626 | 60 |
| CONIER CHEM AND PHARMA LIMITED | |
sales@conier.com | China | 49906 | 58 |
| career henan chemical co | +86-0371-86658258 |
factory@coreychem.com | China | 29780 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 |
sale@simagchem.com | China | 17339 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +86-189 4982 3763 |
sales@tnjchem.com | China | 34526 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 |
sales@win-winchemical.com | China | 14301 | 58 |
| Shanghai UCHEM Inc. | +86-18930848214 +86-021-56762820 |
sales@myuchem.com | China | 8898 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-81139210 +86-17392587031 |
1059@dideu.com | China | 9984 | 58 |
| AFINE CHEMICALS LIMITED | +86-571-85134551 +86-18958018566 |
info@afinechem.com | China | 15052 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 17705817739 |
info@dycnchem.com | China | 52693 | 58 |