2-Morpholinoethyl isocyanide
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2-Morpholinoethyl isocyanide 속성
- 끓는 점
- 72-73 °C0.7 mm Hg(lit.)
- 밀도
- 1.017 g/mL at 20 °C(lit.)
- 굴절률
- n
20/D 1.469
- 인화점
- 110 ºC
- 저장 조건
- -20°C
- 물리적 상태
- liquid
- BRN
- 4666990
- InChI
- InChI=1S/C7H12N2O/c1-8-2-3-9-4-6-10-7-5-9/h2-7H2
- InChIKey
- MFRZPLYKVDHOSN-UHFFFAOYSA-N
- SMILES
- C(N1CCOCC1)C[N+]#[C-]
- CAS 데이터베이스
- 78375-48-1(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | T | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 23/24/25-36/37/38 | ||
| 안전지침서 | 26-36/37-45 | ||
| 유엔번호(UN No.) | UN 2810 6.1/PG 3 | ||
| WGK 독일 | 3 | ||
| F 고인화성물질 | 10-21 | ||
| 위험 등급 | 6.1(b) | ||
| 포장분류 | III | ||
| 스토리지 클래스 | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
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| Hazard Classifications | Acute Tox. 3 Dermal Acute Tox. 3 Inhalation Acute Tox. 3 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
| 그림문자(GHS): |
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| 신호 어: | Danger | ||||||||||||||||||||||||||||
| 유해·위험 문구: |
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| 예방조치문구: |
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2-Morpholinoethyl isocyanide C화학적 특성, 용도, 생산
용도
2-Morpholinoethyl isocyanide can be used for the synthesis of:- Nitrogen acyclic carbene (NAC) complexes to be used as catalysts for the synthesis of phenol and hydration of alkynes.
- Variety of imidazo[1,2-a]pyridines and α-acylaminoamides by Ugi condensation reaction.
- 2-Aminobenzoxazoles and 3-aminobenzoxazines having important therapeutic activities.
It can also be used as a ligand in bis-cyclometalated iridium complexes for the organic light emitting diodes (OLEDs).
Synthesis
2-Morpholinoethyl isocyanide is prepared by the reaction of 2-morpholinoethylamine with Formic Acid in boiling toluene with a water separator, to yield the formamide which is treated either with Phosgene and Triethylamine in CH2Cl2 or with Phosphorus Oxychloride and Diisopropylamine. The use of diisopropylamine as base is favored as yields are improved, typically to 68%. Trichloroacetic Anhydride has also been used as an alternative for COCl2, giving a yield of 74%.2-Morpholinoethyl isocyanide 준비 용품 및 원자재
원자재
준비 용품
2-Morpholinoethyl isocyanide 공급 업체
글로벌( 76)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49979 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 |
info@dycnchem.com | China | 52705 | 58 |
| Henan Alfa Chemical Co., Ltd | +8615838112936 |
sale03@alfachem.cn | China | 9796 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178; |
peter68@ptchemgroup.com | China | 35425 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 |
market18@leapchem.com | China | 43333 | 58 |
| Aladdin Scientific | |
tp@aladdinsci.com | United States | 57505 | 58 |
| Amadis Chemical Company Limited | 571-89925085 |
sales@amadischem.com | China | 131957 | 58 |
| Mainchem Co., Ltd. | +86-0592-6210733 |
sale@mainchem.com | China | 32343 | 55 |
| Chemwill Asia Co.,Ltd. | 86-21-51086038 |
chemwill_asia@126.com | CHINA | 23912 | 58 |
| Wuhan EEChem Technologies Co., Ltd | 0711-3617768 13308685235 |
lihongcai4360@sina.com | China | 1542 | 55 |
2-Morpholinoethyl isocyanide 관련 검색:
아일이소시아네이트 클로로설포닐이소시아네이트 삼차-뷰틸 아이소시아네이트 트리알릴 이소시아누르산염 에틸이소시아네이트 메틸리다인트라이-P-페닐린트라이아이소사이안산 4-(2-아미노에틸)모르폴린 페닐이소시안산 메틸이소시아나이드 에틸이소시아나이드 N-MORPHOLINO-2-ISOCYANO-아세트아미드 2-이소시아노-3-페닐-프로피온산모르폴리나아미드
Isocyanic acid 3,4-dichlorophenyl ester
Propyl isocyanate
4-Fluorophenyl isocyanate
Phenethyl isocyanate
METHYL ISOCYANATE
morpholine