(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
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(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL 속성
- 녹는점
- 252-256 °C
- 알파
- -160° (c 0.5, C6H6)
- 끓는 점
- 754.4±60.0 °C(Predicted)
- 저장 조건
- Inert atmosphere,Room Temperature
- 물리적 상태
- 가루
- 색상
- 하얀색
- 광학 활성
- [α]20/D -156°, c = 0.5 in benzene
- 수용성
- 물에 불용성.
- InChIKey
- IOPQYDKQISFMJI-UHFFFAOYSA-N
- SMILES
- P(C1C=CC(C)=CC=1)(C1C=CC(C)=CC=1)C1C=CC2=CC=CC=C2C=1C1C2=CC=CC=C2C=CC=1P(C1C=CC(C)=CC=1)C1C=CC(C)=CC=1
- CAS 데이터베이스
- 100165-88-6(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험 카페고리 넘버 | 36/37/38 | ||
|---|---|---|---|
| 안전지침서 | 26-36/37/39 | ||
| WGK 독일 | 3 | ||
| TSCA | No | ||
| HS 번호 | 29333990 | ||
| 스토리지 클래스 | 11 - Combustible Solids |
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL C화학적 특성, 용도, 생산
화학적 성질
White powder용도
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl is chiral ligand widely used in asymmetric synthesis. It also used as excellent catalysts for asymmetric hydrogenation of alkenes and some cyclic anhydrides. BINAP is used in organic synthesis for enantioselective transformations catalyzed by its complexes of ruthenium, rhodium, and palladium(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL 준비 용품 및 원자재
원자재
염화니켈 헥사히드레이트
에틸알코올
N,N-다이메틸폼아마이드
(R)-1,1'-비-2-나프톨
톨루엔
트리클로로실란
나트륨
트리플루오로메탄술폰산무수물
트리에틸아민
(S)-1,1'-비-2-나프톨
4-브로모톨루엔
테트라하이드로푸란
초산에틸
1,2-디클로로에탄
디에틸포스파이트
트리페닐포스핀
피리딘
트리에틸렌디아민
마그네슘
준비 용품
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL 공급 업체
글로벌( 170)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +86-16627710726 |
sales@runvmat.com | China | 462 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +86-15350571055 |
Sibel@chuanghaibio.com | China | 8738 | 58 |
| Shenzhen Nexcon Pharmatechs Ltd. | +86-0755-89396905 +86-18025329037 |
admin@nexconn.com | China | 5935 | 58 |
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-15225627621 +86-13213167925 |
jiuyitime@fdachem.com | China | 16511 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 |
info@dakenam.com | China | 14026 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21585 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29812 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 +86-18019713315 |
info@accelachem.com | United States | 21193 | 58 |
| Wuhan Pengo Technology.,Ltd. | +86-27-81330736 +86-13628634921 |
sunny.w@boronicgroup.com | CHINA | 171 | 58 |
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL 관련 검색:
클로로[(S)-(-)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸](p-시멘)루테늄(II)클로라이드 (S)-(-)-2,2'-비스[디(3,5-자일릴)포스피노]-1,1'-비나프틸 디아세토[(R)-(+)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸]루테늄(II) 디아세토[(S)-(-)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸]루테늄(II) 디메틸암모늄디클로로트리(뮤-클로로)비스[(R)-(+)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸]디루테네이트(II) 클로로[(R)-(+)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸](p-시멘)루테늄(II)클로라이드 디메틸암모늄디클로로트리(뮤클로로)비스[(S)-(-)-2,2'-비스(디-p-톨릴포스피노)-1,1'-비나프틸]디루테네이트(II) 디아세타토{(S)-(-)-2,2'-비스[디(3,5-자일릴)포스피노]-1,1'-비나프틸}루테늄(II)
(R)-(+)-TolBINAP
Bis(diphenylphosphino)methane
1,1'-BINAPHTHYL
2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL,rac-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II)chloride