| | 141556-45-8 Basic information More.. |
| Product Name: | 1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride | | Synonyms: | 1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLIUM CHLORIDE;1,3-(2,4,6-TRIMETHYLPHENYL)IMIDAZOLIUM CHLORIDE;N,N'-(2,4,6-TRIMETHYLPHENYL)DIHYDROIMADAZOLIUM CHLORIDE;1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOLI&;1,3-Bis(2,4,6-trimethylphenyl)imidazoliumchloride,min.95%;1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-1H-IMIDAZOLIUM CHLORIDE;1,3-Bisimidazolium chloride;1,3-Bis-(2,4,6-trimethyl-phenyl)-3H-imidazol-1-ium chloride | | CAS: | 141556-45-8 | | MF: | C21H25ClN2 | | MW: | 340.89 | | EINECS: | | | Mol File: | 141556-45-8.mol |  |
Use
1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride is used as a phosphine-free ligand in various metal-catalyzed coupling reactions, often with advantageous results in difficult cases. For use in the Pd-catalyzed cross-coupling of aryl Grignards with aryl chlorides (Kumada reaction). Many examples have been recorded of the use of NHC ligands in the Suzuki coupling reaction, for examples utilizing 1,3-dimesitylimidazol-2-ylidene, in the coupling of arylboronic acids with relatively unreactive aryl chlorides.
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141556-45-8
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