110-71-4 Basic information More..
Product Name:1,2-Dimethoxyethane
Synonyms:1,2-dimethoxy-ethan;1,2-Ethanediol dimethyl ether;DME;1,2-DIMETHOXYETHANE, 99%1,2-DIMETHOXYETHANE, 99%1,2-DIMETHOXYETHANE, 99%;1,2-Dimethoxyethane( 99.5%, HyDry, with molecular sieves, Water≤50 ppm (by K.F.));1,2-Dimethoxyethane(99%, HyDry, Water≤50 ppm (by K.F.));1,2-Dimethoxyethane Factory;1,2-Dimethoxyethane, stab. with 0.01% BHT
CAS:110-71-4
MF:C4H10O2
MW:90.12
EINECS:203-794-9
Mol File:110-71-4.mol
110-71-4

Use

Traces of water and acidic materials have been removed from it by refluxing with Na, K or CaH2, decanting and distilling from Na, K, CaH2 or LiAlH4. The reaction has been speeded up by using vigorous high-speed stirring with molten potassium. For virtually complete elimination of water, 1,2-dimethoxyethane has been dried with Na-K alloy until a characteristic blue colour is formed in the solvent at Dry-ice/cellosolve temperatures: the solvent is kept with the alloy until distilled for use [Ward J Am Chem Soc 83 1296 1961]. Alternatively, glyme, refluxed with benzophenone and Na-K, is dry enough if, on distillation, it gives a blue colour of the ketyl immediately on addition to benzophenone and sodium [Ayscough & Wilson J Chem Soc 5412 1963]. It has also been purified by distillation under N2 from sodium benzophenone ketyl (see above). [Beilstein 1 IV 2376.]

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