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| | 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Basic information |
| Product Name: | 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE | | Synonyms: | 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE;TETRAKIS(2,2-DIMETHYLPROPANOATE)-A-D-GLUCOPYRANOSYL BROMIDE;2,3,4,6-Tetra-O-pivaloyl-a-D-glucopyranosyl bromide (stabilised with CaCO3);[(2S,3S,4S,5R,6S)-6-broMo-3,4,5-tris(2,2-diMethylpropanoyloxy)tetrahydropyran-2-yl]Methyl2,2-diMethylpropanoate;2,3,4,6-Tetra-O-pivaloyl-a-D-glucopyranosylbromide;(2R,3R,4S,5R,6R)-2-BroMo-6-((pivaloyloxy)Methyl)tetrahydro-2H-pyran-3,4,5-triyl tris(2,2-diMethylpropanoate);Canagliflozin Intermediate3;α-D-glucopyranosyl bromide, 2,3,4,6-tetra-O-pivaloyl | | CAS: | 81058-27-7 | | MF: | C26H43BrO9 | | MW: | 579.53 | | EINECS: | 686-241-8 | | Product Categories: | SGLT2;substrate;Canagliflozin intermediate | | Mol File: | 81058-27-7.mol |  |
| | 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Chemical Properties |
| Melting point | 147-148°C | | Boiling point | 530.5±50.0 °C(Predicted) | | density | 1.22±0.1 g/cm3(Predicted) | | vapor pressure | 0-0Pa at 20-25℃ | | storage temp. | Inert atmosphere,2-8°C | | solubility | Chloroform (Sparingly) | | form | Solid | | color | White to Off-White | | Optical Rotation | [α]/D 152.0±3.0°, c =3 in chloroform | | Stability: | Light Sensitive, Moisture Sensitive | | InChIKey | BSDBCYHGMPHOAL-WPECYLAMNA-N | | SMILES | O([C@@H]1[C@H](O[C@H](Br)[C@H](OC(=O)C(C)(C)C)[C@H]1OC(=O)C(C)(C)C)COC(=O)C(C)(C)C)C(=O)C(C)(C)C |&1:1,2,4,6,14,r| | | LogP | 7.2 at pH7 | | CAS DataBase Reference | 81058-27-7 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | WGK 3 | | HS Code | 2932990090 | | Storage Class | 11 - Combustible Solids |
| | 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Usage And Synthesis |
| Uses | 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE was used in the preparation of glucosylated monoterpenoids rhodiolosides A and D. | | Uses | Tetra-O-pivaloyl-α-D-glucopyranosyl Bromide was used in the preparation of glucosylated monoterpenoids rhodiolosides A and D. | | Uses | Knigs-Knorr glycosyl donor with considerably lower tendency to form orthoester side products during glycosylation than the traditional acetobromoglucose |
| | 2,3,4,6-TETRA-O-PIVALOYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE Preparation Products And Raw materials |
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