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| | (Pentamethylcyclopentadienyl)iridium(III) chloride dimer Basic information | | Reaction |
| | (Pentamethylcyclopentadienyl)iridium(III) chloride dimer Chemical Properties |
| Melting point | 245 °C (decomp)(Solv: chloroform (67-66-3); hexane (110-54-3)) | | storage temp. | Inert atmosphere,Room Temperature | | solubility | Chloroform (Sparingly), Methanol (Slightly) | | form | crystal | | color | orange | | Stability: | Moisture Sensitive | | InChI | InChI=1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4 | | InChIKey | JDOHSXHCQARCAW-UHFFFAOYSA-J | | SMILES | [C]1(C)[C](C)[C](C)[C](C)[C]1C.[C]1(C)[C](C)[C](C)[C](C)[C]1C.[Ir](Cl)Cl.[Ir](Cl)Cl |^1:0,2,4,6,8,10,12,14,16,18| | | CAS DataBase Reference | 12354-84-6 |
| | (Pentamethylcyclopentadienyl)iridium(III) chloride dimer Usage And Synthesis |
| Reaction |
- Iridium-catalyzed C-3 alkylation of oxindole with alcohols.
- Precursor to N-heterocyclic carbene catalyst effective for hydrogenation and alkylation of amines and alcohols.
- Precursor to efficient phosphine free catalyst for enantioselective hydrogenation of quinoline derivatives.
- Catalyst for oxidative C–H activation.
- Precursor to an effective water oxidation catalyst.
| | Chemical Properties | orange fine crystalline powder | | Uses | Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is used as a precursor to catalysts for the asymmetric transfer hydrogenation of ketones. It is a catalyst for greener amine synthesis. | | General Description | This product has been enhanced for catalytic efficiency. | | reaction suitability | core: iridium
reagent type: catalyst |
| | (Pentamethylcyclopentadienyl)iridium(III) chloride dimer Preparation Products And Raw materials |
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