5-(DIMETHYLAMINOMETHYLENE)-1,3-CYCLOPENTADIENE manufacturers
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| | 5-(DIMETHYLAMINOMETHYLENE)-1,3-CYCLOPENTADIENE Basic information |
| Product Name: | 5-(DIMETHYLAMINOMETHYLENE)-1,3-CYCLOPENTADIENE | | Synonyms: | N-CYCLOPENTA-2,4-DIENYLIDENMETHYL-N,N-DIMETHYLAMINE;SPECS AO-840/40768031;5-(DIMETHYLAMINOMETHYLENE)-1,3-CYCLOPENTADIENE;6-(DIMETHYLAMINO)FULVENE;2,4-Cyclopentadiene-delta1,alpha-methylamine, N,N-dimethyl-;Methanamine, 1-(2,4-cyclopentadien-1-ylidene)-N,N-dimethyl-;N-(2,4-Cyclopentadien-1-ylidenemethyl)-N,N-dimethylamine;AIDS051095 | | CAS: | 696-68-4 | | MF: | C8H11N | | MW: | 121.18 | | EINECS: | | | Product Categories: | | | Mol File: | 696-68-4.mol |  |
| | 5-(DIMETHYLAMINOMETHYLENE)-1,3-CYCLOPENTADIENE Chemical Properties |
| Melting point | 64-66 °C (lit.) | | Boiling point | 205.3±9.0 °C(Predicted) | | density | 1.042±0.06 g/cm3(Predicted) | | storage temp. | 2-8°C | | pka | 6.25±0.20(Predicted) | | form | powder to crystal | | color | Light yellow to Brown to Dark green | | InChI | 1S/C8H11N/c1-9(2)7-8-5-3-4-6-8/h3-7H,1-2H3 | | InChIKey | UJXXVGXQTXQALL-UHFFFAOYSA-N | | SMILES | CN(C)\C=C1/C=CC=C1 | | CAS DataBase Reference | 696-68-4 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | WGK Germany | 3 | | HS Code | 2921199990 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | 5-(DIMETHYLAMINOMETHYLENE)-1,3-CYCLOPENTADIENE Usage And Synthesis |
| Uses | 6-(Dimethylamino)fulvene was used in the synthesis of chiral cyclopentadienyllithiums substituted with an N,N-dimethylamino(aryl)methyl group. | | Preparation | 6-(Dimethylamino)fulvene may be conveniently prepared by the reaction of cyclopentadienylsodium with N,N-Dimethylformamide-Dimethyl Sulfate. Alternatively, cyclopentadiene has been condensed with N,N-Dimethylformamide Diethyl Acetal. | | Synthesis Reference(s) | Journal of the American Chemical Society, 97, p. 1615, 1975 DOI: 10.1021/ja00839a078 | | storage | 6-(Dimethylamino)fulvene should be protected from light during storage. |
| | 5-(DIMETHYLAMINOMETHYLENE)-1,3-CYCLOPENTADIENE Preparation Products And Raw materials |
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