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| | (-)-Sparteine sulfate pentahydrate Basic information |
| | (-)-Sparteine sulfate pentahydrate Chemical Properties |
| Melting point | 133-140 °C(lit.) | | alpha | -28 º (589nm, c=2, H2O 25 ºC) | | refractive index | -22 ° (C=5, H2O) | | storage temp. | 2-8°C | | solubility | H2O: 0.1 g/mL, clear, colorless | | form | Solid | | Merck | 8737 | | InChI | InChI=1/C15H26N2.H2O4S/c1-3-7-16-11-13-9-12(14(16)5-1)10-17-8-4-2-6-15(13)17;1-5(2,3)4/h12-15H,1-11H2;(H2,1,2,3,4)/t12-,13-,14-,15+;/s3 | | InChIKey | FCEHFCFHANDXMB-WAZVWRGFNA-N | | SMILES | [C@]12([H])CN3CCCC[C@]3([H])[C@]([H])(CN3CCCC[C@@]13[H])C2.S(O)(O)(=O)=O |&1:0,8,10,18,r| | | CAS DataBase Reference | 6160-12-9 |
| Hazard Codes | Xn | | Risk Statements | 22-20/21/22 | | Safety Statements | 36-24/25 | | WGK Germany | 3 | | RTECS | WG6430000 | | HS Code | 29399900 |
| | (-)-Sparteine sulfate pentahydrate Usage And Synthesis |
| Chemical Properties | white fine crystalline powder | | Uses | oxytocic | | Purification Methods | Recrystallise the sulfate from aqueous EtOH or H2O, although the solubility in the latter is high. The free (-)-base has b 173o/8mm and is steam volatile but resinifies in air. The dipicrate forms yellow needles from EtOH/Me2CO, m 205-206o [Clemo et al. J Chem Soc 429 1931; see also Bolnmann & Schuman The Alkaloids (Ed Manske) Vol 9 175 1967]. The free (±)-base has m 71-72.5o [van Tamelen & Foltz J Am Chem Soc 82 2400 1960]. [Beilstein 23 II 99, 23 III/IV 18.] |
| | (-)-Sparteine sulfate pentahydrate Preparation Products And Raw materials |
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