9-Methoxy-9-borabicyclo[3.3.1]nonane

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9-Methoxy-9-borabicyclo[3.3.1]nonane manufacturers

9-Methoxy-9-borabicyclo[3.3.1]nonane Basic information
Product Name:9-Methoxy-9-borabicyclo[3.3.1]nonane
Synonyms:9-Borabicyclo[3.3.1]nonane,9-methoxy-;9-Methoxy-9-borabicycL;B-METHOXY-9-BBN, 1.0M SOLUTION IN HEXANE S;b-methoxy-9-bbn solution;8-Methoxy-9-borabicyclo[3,3,1]nonane;9- methoxy-9-borabicyclo[3.3.1]nonane 1.0M in hexanes;B-Methoxy-9-BBN solution,9-Methoxy-9-borabicyclo[3.3.1]nonane;B-Methoxy-9-borabicyclo[3.3.1]nonane
CAS:38050-71-4
MF:C9H17BO
MW:152.04
EINECS:253-758-1
Product Categories:
Mol File:38050-71-4.mol
9-Methoxy-9-borabicyclo[3.3.1]nonane Structure
9-Methoxy-9-borabicyclo[3.3.1]nonane Chemical Properties
Boiling point 57-58 °C(Press: 7 Torr)
density 0.716 g/mL at 25 °C
Fp −9 °F
form liquid
InChIInChI=1S/C9H17BO/c1-11-10-8-4-2-5-9(10)7-3-6-8/h8-9H,2-7H2,1H3
InChIKeyUNGDGQYONLTNJZ-UHFFFAOYSA-N
SMILESC12B(OC)C(CCC1)CCC2
Safety Information
Hazard Codes F,Xn,N
Risk Statements 11-20/21/22-67-65-62-51/53-48/20-38
Safety Statements 16-23-36/37/39-45-62-61-36/37
RIDADR UN 1993 3/PG 2
WGK Germany 3
Storage Class3 - Flammable liquids
Hazard ClassificationsAquatic Chronic 2
Asp. Tox. 1
Flam. Liq. 2
Repr. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
9-Methoxy-9-borabicyclo[3.3.1]nonane Usage And Synthesis
UsesPro-nucleophile and co-catalyst for indium-catalyzed allylations of methyl ethers and carbohydrate derivatives. Catalyst for preparation of linear allenes from other allenes 2 Reactant for: Stereoconvergent Suzuki cross-coupling reactions 3 B-alkyl Suzuki-Miyaura cross-coupling reactions 4 Preparation of borabicyclononanyl amino acid complexes for selective treatment of malignant melanoma 5 Asymmetric synthesis of isomerically pure allenyl boranes through insertion and borotropic rearrangement.
Uses9-Methoxy-9-borabicyclo[3.3.1]nonane is a coupling reagent used in reactions like the synthesis of (-)-brevenal a polycyclic ether.
Uses
  • Pro-nucleophile and co-catalyst for indium-catalyzed allylations of methyl ethers and carbohydrate derivatives
  • Catalyst for preparation of linear allenes from other allenes

Reactant for:
  • Stereoconvergent Suzuki cross-coupling reactions
  • B-alkyl Suzuki-Miyaura cross-coupling reactions
  • Preparation of borabicyclononanyl amino acid complexes for selective treatment of malignant melanoma
  • Asymmetric synthesis of isomerically pure allenyl boranes through insertion and borotropic rearrangement
reaction suitabilityreaction type: C-C Bond Formation
9-Methoxy-9-borabicyclo[3.3.1]nonane Preparation Products And Raw materials
Preparation Products9-BBN dimer-->beta-Benzyl-9-BBN
Tag:9-Methoxy-9-borabicyclo[3.3.1]nonane(38050-71-4) Related Product Information
9-BBN triflate 9-Bromo-9-borabicyclo[3.3.1]nonane Potassium 9-(2,3-dimethyl-2-butoxy)-9-boratabicyclo[3.3.l]nonane LITHIUM 9-BBN HYDRIDE 9-(1,1,2-Trimethylpropoxy)-9-borabicyclo[3.3.1]nonane BETA-BENZYL-9-BBN Methoxydiethylborane 9-METHOXY-9-BORABICYCLO[3.3.1]NONANE 9-Borabicyclo[3.3.1]nonane