4-CHLOROISATIN

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CAS:6344-05-4
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CAS:6344-05-4
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CAS:6344-05-4
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CAS:6344-05-4
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4-CHLOROISATIN manufacturers

  • 4-Chloroisatin
  •  4-Chloroisatin pictures
  • $2.20
  • 2026-04-17
  • CAS:6344-05-4
  • Min. Order: 1kg
  • Purity: 99%min
  • Supply Ability: 100kg
  • 4-CHLOROISATIN
  • 4-CHLOROISATIN pictures
  • $15.00
  • 2021-08-12
  • CAS:6344-05-4
  • Min. Order: 1KG
  • Purity: 99%+ HPLC
4-CHLOROISATIN Basic information
Product Name:4-CHLOROISATIN
Synonyms:4-CHLORO-2,3-INDOLINEDIONE;4-CHLOROISATIN;4-CHLOROINDOLE-2,3-DIONE;4-Chloro-(1H)-indole-2,3-dione;BUTTPARK 50\07-90;4-Chloro-2,3-dihydro-1H-indole-2,3-dione;4-chloro-1H-indole-2,3-dione(SALTDATA: FREE);4-Chloroindole-2,3-dione 4-Chloro-2,3-indolinedione
CAS:6344-05-4
MF:C8H4ClNO2
MW:181.58
EINECS:1533716-785-6
Product Categories:Indane/Indanone and Derivatives;Indoles;Simple Indoles
Mol File:6344-05-4.mol
4-CHLOROISATIN Structure
4-CHLOROISATIN Chemical Properties
Melting point 258 °C
density 1.519±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility soluble in Dimethylformamide
form powder to crystal
pka9.44±0.20(Predicted)
color Light yellow to Brown
CAS DataBase Reference6344-05-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
HazardClass IRRITANT
HS Code 2933998090
MSDS Information
4-CHLOROISATIN Usage And Synthesis
Chemical PropertiesOrange powder
Uses4-Chloroisatin is an isatic acid derivative that performs a plant growth-regulating activity. Isatin compounds also performs selective inhibitory functions against carboxylesterases.
Synthesis
Chloral hydrate

302-17-0

3-Chloroaniline

108-42-9

4-CHLOROISATIN

6344-05-4

Chloral hydrate (8.93 g, 0.054 mol), anhydrous sodium sulfate (130 g, 0.40 mol), m-chloroaniline (0.05 mol), hydroxylammonium chloride (10.98 g, 0.158 mol), and concentrated hydrochloric acid (43 mL) were added to 120 mL of water in sequence. The resulting suspension was heated to 90 °C, maintained for 5 minutes and cooled to room temperature. The reaction mixture was filtered and washed with water (2 x 20 mL) to obtain the crude product. The crude product was added in batches to a 250 mL three-necked flask pre-filled with concentrated sulfuric acid (32.6 mL) and preheated to 65 °C, after which the mixture was heated to 80 °C and maintained for 20 minutes. After completion of the reaction, the solution was cooled to room temperature and slowly poured into 500 g of ice water with vigorous stirring for 4 hours. The intermediate 4-chloroindoline-2,3-dione was isolated by filtration, washed with water and recrystallized from ethanol in a final yield of 25.7% to 73.2%.

References[1] Chinese Chemical Letters, 2013, vol. 24, # 10, p. 929 - 933
Tag:4-CHLOROISATIN(6344-05-4) Related Product Information
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